Macropolyhedral boron-containing cluster chemistry: Two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(η5-C5Me5)HIrB18H 19(PHPh2)] and [(η5-C5Me 5)IrB18H18(PH2Ph)]

Inorganica Chimica Acta

Volumn 357, Issue 10, 2004, Pages 3119-3123

  Shea, Suzanne L ^a   Jelínek, Tomáš ^b   Perera, Sarath D ^a,c   Štíbr, Bohumil ^b   Thornton Pett, Mark ^a   Kennedy, John D ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b INSTITUTE OF INORGANIC CHEMISTRY   (Czech Republic)

^c Nugegoda   (Sri Lanka)

Author keywords

Borane cluster; Iridium borane cluster compound; Macropolyhedral opening and closure; Metallaborane; NMR spectroscopy; Redox changes in intercluster intimacy; X ray structure

Indexed keywords

ATOMS; BORON; IRIDIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

BORANE CLUSTER; INTER CLUSTERS; MACROPOLYHEDRAL OPENING AND CLOSURE; METALLABORANE; X-RAY STRUCTURE;

CHEMICAL BONDS;

BORON; HYDROGEN; IRIDIUM;

ARTICLE; ATOMIC PARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CHEMISTRY; ELECTRON; NUCLEAR ENERGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY DIFFRACTION;

EID: 3242712144     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2004.03.041     Document Type: Article

References (39)

1. Kennedy J.D. Prog. Inorg. Chem. 32:1984;519
2. Kennedy J.D. Prog. Inorg. Chem. 34:1986;211
3. Barton L., Srivastava D.K. Wilkinson G., Abel E.W., Stone F.G.A. Comprehensive Organometallic Chemistry II. vol. 1:1995;275-373 Pergamon. (Chapter 8)
4. Ditzel E.J., Fontaine X.L.R., Fowkes H., Greenwood N.N., Kennedy J.D., MacKinnon P., Sisan Zhu, Thornton-Pett M. J. Chem. Soc., Chem. Commun. 1990;1692
5. Ditzel E.J., Fontaine X.L.R., Greenwood N.N., Kennedy J.D., Sisan Zhu, Stibr B., Thornton-Pett M. J. Chem. Soc., Chem. Commun. 1990;1741
6. Bould J., Brint P., Kennedy J.D., Thornton-Pett M. J. Chem. Soc. Dalton Trans. 1993;2335
7. Shea S.L., McGrath T.D., Jelínek T., Štíbr B., Thornton-Pett M., Kennedy J.D. Inorg. Chem. Commun. 1:1998;97
8. Bould J., Clegg W., Spalding T.R., Kennedy J.D. Inorg. Chem. Commun. 2:1999;315
9. Hawthorne M.F. Liebman J.F., Greenberg A., Williams R.E. Advances in Boron and the Boranes. 1988;225-233 VCH, Weinheim
10. Yan H., Beatty A.M., Fehlner T.P. J. Organomet. Chem. 680:2003;66
11. Long J.A., Marder T.B., Hawthorne M.F. J. Am. Chem. Soc. 106:1984;3004
12. Fontaine X.L.R., Kennedy J.D., Thornton-Pett M. Collect. Czech. Chem. Commun. 58:1993;1555
13. Bould J., Crook J.E., Greenwood N.N., Kennedy J.D., McDonald W.S. J. Chem. Soc., Chem. Commun. 1982;346
14. Nestor K., Fontaine X.L.R., Greenwood N.N., Kennedy J.D., Plešek J., Štíbr B., Thornton-Pett M. Inorg. Chem. 28:1989;2219
15. Bould J., Kennedy J.D., Thornton-Pett M. J. Chem. Soc., Dalton Trans. 1992;563
16. Štíbr B., Kennedy J.D., Drdáková E., Thornton-Pett M. J. Chem. Soc., Dalton Trans. 1994;229
17. See, for example, Burke A., Ellis D., Giles B.T., Hodson B.E., Macgregor S.A., Rosiar G.M., Welch A.J. Angew. Chem., Int. Ed. 42:2003;225. and references cited therein.
18. Cheung M.-S., Chan H.-S., Xie Z. Organometallics. 23:2004;517
19. Kennedy J.D. Siebert W. Advances in Boron Chemistry. 1997;451-462 Royal Society of Chemistry, Cambridge
20. Bould J., Clegg W., Teat S.J., Barton L., Rath N.P., Thornton-Pett M., Kennedy J.D. Boron chemistry at the millennium. Inorg. Chim. Acta. 289:1999;95. (special edition)
21. Bould J., Ormsby D.L., Yao H.-J., Hu C.-H., Sun J., Jin R.-S., Shea S.L., Clegg W., Jelínek T., Rath N.P., Thornton-Pett M., Greatrex R., Zheng P.-J., Barton L., Štíbr B., Kennedy J.D. Davidson M., Hughes A.K., Marder T.B., Wade K. Contemporary Boron Chemistry. 2000;171-174 Royal Society of Chemistry, Cambridge, England
22. Shea S.L., Bould J., Londesborough M.G.S., Perera S.D., Franken A., Ormsby D.L., Jelínek T., Štíbr B., Holub J., Kilner C.A., Thornton-Pett M., Kennedy J.D. Pure Appl. Chem. 75:2003;1239
23. Kennedy J.D. Heřmánek S. Boron Chemistry (IMEBORON VI). 1987/1988;207-243 World Scientific, Singapore
24. Sneath R.L., Todd L.J. Inorg. Chem. 12:1973;44
25. Fontaine X.L.R., Greenwood N.N., Kennedy J.D., MacKinnon P.I., Thornton-Pett M. J. Chem. Soc., Chem. Commun. 1986;1111
26. Kaur P., Kennedy J.D., Thornton-Pett M., Jelínek T., Štíbr B. J. Chem. Soc., Dalton Trans. 1996;1775
27. Barton L., Bould J., Kennedy J.D., Rath N.P. J. Chem. Soc., Dalton Trans. 1996;3145
28. Bould J., Clegg W., Kennedy J.D., Teat S.J., Thornton-Pett M. J. Chem. Soc., Dalton Trans. 1997;2005
29. Bould J., Kennedy J.D., Barton L., Rath N.P. J. Chem. Soc., Chem. Commun. 1997;2405
30. Shea S.L., Jelínek T., Štíbr B., Thornton-Pett M., Kennedy J.D. Inorg. Chem. Commun. 3:2000;169
31. Williams R.E. Inorg. Chem. 1:1971;210
32. Williams R.E. Adv. Inorg. Chem. Radiochem. 18:1976;67
33. Wade K. Chem. Commun. 1971;792
34. Wade K. Adv. Inorg. Chem. Radiochem. 18:1976;1
35. Shore S.G. Muetterties E.L. Boron Hydride Chemistry. 1975;79-174 Wiley, New York
36. S.L. Shea, T. Jelínek, S.D. Perera, B. Štíbr, M. Thornton-Pett, J.D. Kennedy, J. Chem. Soc., Dalton Trans. (2004, in press)
37. McArdle P. ORTEP, version 5. J. Appl. Crystallogr. 28:1995;65
38. Sheldrick G.M. SHELXS86, Program for Crystal Structure Solution. 1986;University of Göttingen
39. Sheldrick G.M. SHELXL93, Program for Crystal Structure Refinement. 1993;University of Göttingen