Characterization and catalytic activity of trans-[Pd(COCH 2CH3)(TsO)(PPh3)2], isolated from the hydro-methoxycarbonylation of ethene catalyzed by [Pd(TsO) 2(PPh3)2]

Journal of Molecular Catalysis A: Chemical

Volumn 219, Issue 2, 2004, Pages 233-240

  Cavinato, Gianni ^a   Toniolo, Luigi ^b   Vavasori, Andrea ^b  

^a UNIVERSITY OF PADOVA   (Italy)

^b CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

Author keywords

Carbon monoxide; Ethene; Methoxycarbonylation; Methylpropanoate; Palladium catalyst

Indexed keywords

CATALYSIS; COMPLEXATION; HYDRIDES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STOICHIOMETRY; SYNTHESIS (CHEMICAL);

PRECURSORS; SPECIES;

ORGANOMETALLICS;

ALKENE DERIVATIVE; CARBON DIOXIDE; CARBON MONOXIDE; CARBOXYLIC ACID DERIVATIVE; CHEMICAL COMPOUND; ESTER DERIVATIVE; ETHYLENE; LEAD;

ARTICLE; CARBONYLATION; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); HYDROGEN BOND; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; STOICHIOMETRY;

EID: 3242703487     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2004.04.014     Document Type: Article

References (41)

1. J. Falbe, New Syntheses with Carbon Monoxide, Springer, Berlin, 1980.
2. H.M. Colquhoun, D.J.Thompson, M.V. Twigg, Carbonylation, Direct Synthesis of Carbonyl Compounds, Plenum Press, New York, 1991.
3. Beller M., Cornils B., Frohning C.D., Kohlpainter C.W. J. Mol. Catal. 104:1995;17
4. Kiss G. Chem. Rev. 101:2001;3435
5. E. Drent, (Shell) EP 0,106,379 (1988).
6. Drent E., Budzelaar P.H.M. Chem. Rev. 96:1996;663
7. Knight J.G., Doherty S., Harriman A., Robbins E.G., Betham M.B., Eastham G.R., Tooze R.P., Elsegood M.R.J., Champkim P., Clegg W. Organometallics. 19:2000;4957
8. Doherty S., Robbins G., Knight J.G., Newman C.R., Rhodes B., Champkin P.A., Clegg W. J. Organomet. Chem. 640:2001;182
9. E.G. Chepaikin, A.P. Bezruchenko, A.A. Leshcheva, G.N. Baiko, Izv. Akad. Nauk SSSR, Ser. Khim. (1998) 743.
10. Tilloy S., Monflier E., Bertoux F., Castanet Y., Montreux A. New J. Chem. 21:1997;529
11. Verspui G., Papadogianakis G., Maat L., Sheldon R.A. Catal. Lett. 47:1997;43
12. Knifton J. J. Org. Chem. 41:1976;2885
13. Cavinato G., Toniolo L. J. Organomet. Chem. 398:1990;187
14. Otsuka S., Nakamura A., Yoshida T., Naruto M., Ataka K. J. Am. Chem. Soc. 95:1973;3180
15. Fenton D.M. J. Org. Chem. 38:1973;3192
16. Milstein D. Ace. Chem. Res. 21:1988;428
17. Bittler K., Kutepow N., Neubauer D., Reis H. Angew. Chem. Int. Ed. 7:1968;329
18. Morandini F., Consiglio G., Wenzinger F. Helv. Chim. Acta. 62:1979;59
19. Petrov E.S., Noskov Yu.G. Ross. Khim. Zh. 42:1998;149
20. G. Benedek, A. Szalontai, S. Gomory, B. Toros, J. Heil, Organomet. Chem. 579 (1999) 147.
21. Benedek C., Toros S., Heil B. J. Organomet. Chem. 586:1999;85
22. Seayad A., Jayasree S., Damodaran K., Toniolo L., Chaudhari R.V. J. Organomet. Chem. 601:2000;100
23. W. Clegg, G.R. Eastham, M.R.J. Elsegood, R.P. Tooze, X.L. Wang, K. Whiston, J. Chem. Soc. Chem. Commun. (1999) 1877.
24. G.R. Eastham, B.T. Heaton, J.A. Iggo, R.P. Tooze, R. Whyman, S. Zacchini, J. Chem. Soc. Chem. Commun. (2000) 609.
25. G.R. Eastham, R.P. Tooze, M. Kilner, D.F. Foster, D.J. Cole-Hamilton, J. Chem. Soc. Dalton Trans. (2002)1613.
26. W. Clegg, G.R. Eastham, M.R.J. Elsegood, B.T. Heaton, J.A. Iggo, R.P. Tooze, R. Whyman, S. Zacchini, J. Chem. Soc. Dalton Trans. (2002) 3300.
27. Vavasori A., Cavinato G., Toniolo L. J. Mol. Catal. 176:2001;11
28. Vavasori A., Cavinato G., Toniolo L. J. Mol. Catal. 191:2003;9
29. Cavinato G., Vavasori A., Toniolo L., Benetollo F. Inorg. Chim. Acta. 343:2003;183
30. R.P. Tooze, K. Whiston, A.P. Malyan, M.J. Taylor, N.W. Wilson, J. Chem. Soc. Dalton Trans. (2000) 3441.
31. Misono A., Uchida Y., Hidai M., Kudo K. J. Organomet. Chem. 20:1969;7
32. Hidai M., Kokura M., Uchida Y. J. Organomet. Chem. 52:1973;431
33. V.N. Zudin, V.D. Chinakov, V.M. Nekipelov, V.A. Rogov, V.A. Likholobov, Yu.I. Yermakov, J. Mol. Catal. 52 (1989) 27.
34. Grushin V.V. Chem. Rev. 96:1996;2011
35. Bardi R., Del Pra A., Piazzasi A.M., Toniolo L. Inorg. Chim. Acta. 35:1979;L 345
36. Cavinato G., Toniolo L. J. Mol. Catal. 10:1981;161
37. Bardi R., Piazzasi A.M., Del Pra A., Cavinato G., Toniolo L. Inorg. Chim. Acta. 102:1985;99
38. Bohner U., Zundel G. J. Phys. Chem. 89:1985;1408
39. Kubas G.J., Burns C.J., Khalsa G.R.K., Van Der Sluys L.S., Kiss G., Hoff C.D. Organometallics. 11:1992;3390
40. Merwin R.K., Roddick D.M. J. Organomet. Chem. 487:1995;69
41. Bertani R., Cavinato G., Toniolo L., Vasapollo G. J. Mol. Catal. 84:1993;165