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Volumn 6, Issue 14, 2004, Pages 2325-2328

Immobilization of Pd(OAc)2 in ionic liquid on silica: Application to sustainable Mizoroki-Heck reaction

Author keywords

[No Author keywords available]

Indexed keywords

PALLADIUM ACETATE; SILICON DIOXIDE;

EID: 3242695463     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol049343i     Document Type: Article
Times cited : (208)

References (31)
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    • note
    • 2 supported was 560 mg (0.25 mmol/g) based on weight gain.
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    • note
    • 2) in n-dodecane (2 mL) were added iodobenzene 1 (112 mg, 1 mmol), cyclohexyl acrylate 2 (189 mL, 1.2 mmol), and tri(n-butyl)amine (279 mL, 2 mmol) under a nitrogen atmosphere. The suspension was heated at 150 °C until disappearance of iodobenzene 1 by GLC monitoring. After being cooled to room temperature, the n-dodecane layer was passed through a silica column with the aid of n-hexane to remove n-dodecane. Subsequently, the product was eluted with n-hexane-ethyl acetate. The n-hexane-ethyl acetate eluent was evaporated to dryness to give a residue that was purified by medium-pressure LC (eluent = ethyl acetate/n-hexane 1:20) to afford cyclohexyl cinnamate 3 (234 mg, 98%). The catalyst was reused intact for the next reaction without any pretreatment.


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