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4 crystallizes in the orthorhombic space group Pnma with a = 7.483 Å. b = 5.772 Å. c = 10.072 Å. ((a) Wyckoff. R. W. G. Crystal Structures, v.3 Wiley-Interscience: New York, 1965; Vol. 3, pp 95-97). (b) Ojima, K.; Nishihata, Y.; Sawada. A. Acta Crystallogr. Sect. B, 1995, B51, 287-293.) To be consistent with Buckley, our Miller indices refer to ratios determined by classical goniometry where b > c > a in the nonstandard setting Pcmn. (c) von Groth, P. Chemische Kristallographie: W. Engelmann. Leipzig, Germany, 1908; Vol. 2, p 351. (d) Tutton, A. E. J. Chem. Soc. 1894, 628-717.
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