E- or Z-selective Knoevenagel condensation of acetoacetic derivatives: Effect of acylated substituent, that is, TEMPO and amines, as an auxiliary, and new accesses to trisubstituted E- and Z-2-alkenals and furans

Journal of Organic Chemistry

Volumn 71, Issue 3, 2006, Pages 947-953

  Inokuchi, Tsutomu ^a   Kawafuchi, Hiroyuki ^b  

^a OKAYAMA UNIVERSITY   (Japan)

^b TOYAMA NATIONAL COLLEGE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; AMINES; CARBOXYLIC ACIDS; DERIVATIVES; ELECTRONS; SOLVENTS; THERMOSETS;

ELECTRON-WITHDRAWING GROUP; KNOEVENAGEL CONDENSATION; TEMPO; Z-SELECTIVE KNOEVENAGEL CONDENSATION;

ACETIC ACID;

ACETOACETIC ACID DERIVATIVE; ALDEHYDE DERIVATIVE; ALKENE DERIVATIVE; ALKYL GROUP; AMINE; AROMATIC COMPOUND; CARBOXYLIC ACID; FURAN DERIVATIVE; HYDROXYL GROUP; METHYL GROUP; PIPERIDINE DERIVATIVE; TEMPOL;

ACYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL BOND; CONFORMATION; ISOMER; ISOMERIZATION; KNOEVENAGEL CONDENSATION; MOLECULAR STABILITY; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION; STEREOCHEMISTRY;

ACETOACETATES; ACYLATION; ALDEHYDES; ALKANES; AMINES; CYCLIC N-OXIDES; FURANS; HEAT; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; STEREOISOMERISM;

EID: 32144457342     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo051952w     Document Type: Article

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