Natural bond orbital analyses of persulfoxide stabilization by remote functional groups. The conformationally induced electrostatic stabilization sulfide photooxygenation mechanism

Journal of Organic Chemistry

Volumn 71, Issue 3, 2006, Pages 1247-1250

  Clennan, Edward L ^a   Hightower, Sean E ^a  

^a UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CONFORMATIONS; NITROGEN; OXYGEN; REACTION KINETICS;

CONFORMATIONALLY INDUCED ELECTROSTATIC STABILIZATION (CIES); DONOR ATOMS; PERSULFOXIDE STABILIZATION; SULFIDE PHOTOOXYGENATION MECHANISM;

SULFUR COMPOUNDS;

1,5 DITHIOCYCLOOCTANE; ACETONE; CYCLOOCTANE; CYCLOOCTANE DERIVATIVE; DIMETHYLPERSULFOXIDE; ETHYLENE OXIDE DERIVATIVE; FUNCTIONAL GROUP; NITROGEN; ORGANIC SOLVENT; OXYGEN; OZONE; SULFIDE; SULFOXIDE; SULFUR; THIADIOXIRANE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; CONFORMATIONAL TRANSITION; CONFORMATIONALLY INDUCED ELECTROSTATIC STABILIZATION; DECOMPOSITION; ENERGY TRANSFER; GEOMETRY; HYDROGEN BOND; PHOTOOXIDATION; QUANTUM YIELD;

EID: 32144444848     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo052269c     Document Type: Article

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