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Volumn 2006, Issue 7, 2006, Pages 338-358

New metal-catalyzed carbocyclization reactions for the construction of complex natural products

Author keywords

Carbocyclization; Diastereoselectivity; Enantioselective; Metallacycles; Polycyclic; Rhodium catalyzed

Indexed keywords


EID: 32044448988     PISSN: 14246376     EISSN: 14246376     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (8)

References (72)
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    • (c) Fujiwara, M.; Ojima, I. In Modern Rhodium-Catalyzed Organic Reactions; Evans, P. A. Ed.; Wiley-VCH: Weinheim, 2005; Ch. 7, p 129 and pertinent references cited therein.
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  • 17
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    • For another example of a rhodium(I)-catalyzed [4+2+2] carbocyclizations see: Gilbertson, S. R.; DeBeof, B. J. Am. Chem. Soc. 2002, 124, 8784.
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    • The rhodium-catalyzed cycloisomerization of 1,3-butadiene is known to favor oligomerization rather than the formation of cyclooctadiene, see: Bosch, M.; Brookhart, M. S.; Ilg, K.; Werner, H. Angew. Chem., Int. Ed. 2000, 39, 2304.
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    • Although the carbocyclization proceeds with heteroatom tethers, the carbon derivatives lead to mixtures, in which enyne cycloisomerization was the major adduct. For a rhodiumcatalyzed version, see: Cao, P.; Wang, B.; Zhang, X. J. Am. Chem. Soc. 2000, 122, 6490.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 6490
    • Cao, P.1    Wang, B.2    Zhang, X.3
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    • For some recent examples of intermolecular rhodium-catalyzed [2+2+2] carbocyclizations of tethered 1,6-diynes, see: (a) McDonald, F. E.; Zhu, H. Y. H.; Holmquist, C. R. J. Am. Chem. Soc. 1995, 117, 6605.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 6605
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    • For examples of an intermolecular metal-catalyzed [2+2+2] carbocyclization with various 1,6-enynes using symmetrical alkynes, see: (a) Pd: Trost, B. M.; Tanoury, G. J. J. Am. Chem. Soc. 1987, 109, 4753.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 4753
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.