Large-scale one-pot synthesis of N-heterocyclic carbene-Pd(allyl)Cl complexes

Synthesis

Volumn , Issue 2, 2006, Pages 366-367

  Navarro, Oscar ^a   Nolan, Steven P ^a  

^a UNIVERSITY OF NEW ORLEANS   (United States)

Author keywords

Homogeneous catalysis; N heterocyclic carbene; Palladium

Indexed keywords

CATALYSIS; CATALYSTS; COMPLEXATION; PALLADIUM COMPOUNDS; SOLVENTS; SYNTHESIS (CHEMICAL);

CROSS-COUPLING; HOMOGENEOUS CATALYSIS; N-HETEROCYCLIC CARBENE;

NITROGEN COMPOUNDS;

2 PROPANOL; CARBENE; PALLADIUM COMPLEX; SOLVENT;

ANALYTIC METHOD; ARTICLE; ARYLATION; CATALYSIS; CATALYST; COMPLEX FORMATION; DRUG ISOLATION; SUZUKI REACTION; SYNTHESIS; TELOMERE;

EID: 31544483930     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-918497     Document Type: Article

References (22)

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6. 3 was not included in this study.
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20. (IPr)Pd(allyl)Cl is commercially available from Strem Chemicals in small quantities (hundreds of mg) and from Umicore AG in larger quantities. For more references on uses of this pre-catalyst, see: (a) Marion, N.; Navarro, O.; Kelly, R. A. III; Nolan, S. P. Synthesis 2003, 2590.
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22. IPr·HCl and SIPr·HCl are commercially available from Strem Chemicals.