New persistent heteroarylmethyl radicals resulting from the intramolecular addition of aryloxymethyl radicals onto ketenimines. Synthesis of 2H-1,4-benzoxazines

Synlett

Volumn , Issue 6, 2004, Pages 991-994

  Alajarín, Mateo ^a   Vidal, Angel ^a   Ortín, María Mar ^a   Bautista, Delia ^b  

^a Ulniversidad de Murcia   (Spain)

^b UNIVERSITY OF MURCIA   (Spain)

Author keywords

1,4 benzoxazines; Aryloxymethyl radical; Cyclization; Ketenimine; Persistent

Indexed keywords

BENZOXAZINE DERIVATIVE; ETHER DERIVATIVE; IMINE; METHYL GROUP; RADICAL; SILANE DERIVATIVE; TRIS(TRIMETHYLSILYL)SILANE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CROSS COUPLING REACTION; CYCLIZATION; DECOMPOSITION; SUBSTITUTION REACTION; X RAY ANALYSIS;

EID: 3142764452     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-822883     Document Type: Article

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40. For articles dealing with persistent nitrogen-centered radicals see: (a) Nakatsuji, M.; Miura, Y.; Teki, Y. J. Chem. Soc., Perkin Trans. 2 2001, 738. (b) Miura, Y.; Momoki, M.; Fuchikami, T.; Teki, Y.; Itoh, K.; Mizutani, H. J. Org. Chem. 1996, 61, 4300. (c) Roberts, J. R.; Ingold, K. U. J. Am. Chem. Soc. 1973, 95, 3228. (d) Griller, D.; Mendenhall, G. D.; van Hoof, W.; Ingold, K. U. J. Am. Chem. Soc. 1974, 96, 6068.
41. For articles dealing with persistent nitrogen-centered radicals see: (a) Nakatsuji, M.; Miura, Y.; Teki, Y. J. Chem. Soc., Perkin Trans. 2 2001, 738. (b) Miura, Y.; Momoki, M.; Fuchikami, T.; Teki, Y.; Itoh, K.; Mizutani, H. J. Org. Chem. 1996, 61, 4300. (c) Roberts, J. R.; Ingold, K. U. J. Am. Chem. Soc. 1973, 95, 3228. (d) Griller, D.; Mendenhall, G. D.; van Hoof, W.; Ingold, K. U. J. Am. Chem. Soc. 1974, 96, 6068.
42. For articles dealing with persistent nitrogen-centered radicals see: (a) Nakatsuji, M.; Miura, Y.; Teki, Y. J. Chem. Soc., Perkin Trans. 2 2001, 738. (b) Miura, Y.; Momoki, M.; Fuchikami, T.; Teki, Y.; Itoh, K.; Mizutani, H. J. Org. Chem. 1996, 61, 4300. (c) Roberts, J. R.; Ingold, K. U. J. Am. Chem. Soc. 1973, 95, 3228. (d) Griller, D.; Mendenhall, G. D.; van Hoof, W.; Ingold, K. U. J. Am. Chem. Soc. 1974, 96, 6068.
43. For articles dealing with persistent nitrogen-centered radicals see: (a) Nakatsuji, M.; Miura, Y.; Teki, Y. J. Chem. Soc., Perkin Trans. 2 2001, 738. (b) Miura, Y.; Momoki, M.; Fuchikami, T.; Teki, Y.; Itoh, K.; Mizutani, H. J. Org. Chem. 1996, 61, 4300. (c) Roberts, J. R.; Ingold, K. U. J. Am. Chem. Soc. 1973, 95, 3228. (d) Griller, D.; Mendenhall, G. D.; van Hoof, W.; Ingold, K. U. J. Am. Chem. Soc. 1974, 96, 6068.