Electron photodetachment from aqueous anions. 1. Quantum yields for generation of hydrated electron by 193 and 248 nm laser photoexcitation of miscellaneous inorganic anions

Journal of Physical Chemistry A

Volumn 108, Issue 25, 2004, Pages 5490-5502

  Sauer Jr , Myran C ^a   Crowell, Robert A ^a   Shkrob, Ilya A ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDRATED ELECTRONS; LASER PHOTOEXCITATION; PHOTOEXCITATION; QUANTUM YIELDS;

ABSORPTION; KINETIC THEORY; LASERS; MOLECULAR DYNAMICS; PHOTOCHEMICAL REACTIONS; PHOTOLYSIS; SOLUTIONS;

ELECTRON EMISSION;

EID: 3142752733     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp049722t     Document Type: Article

References (109)

1. Blandamer, M. J.; Fox, M. F. Chem. Rev. 1970, 70, 59.
2. Bradforth, S. E.; Jungwirth, P. J. Phys. Chem. A 2002, 106, 1286 and references therein.
3. Kloepfer, J. A.; Vilchiz, V. H.; Lenchenkov, V. A.; Bradforth, S. E. Chem. Phys. Lett. 1998, 298, 120.
4. Kloepfer, J. A.; Vilchiz, V. H.; Lenchenkov, V. A.; Chen, X.; Bradforth, S. E. J. Chem. Phys. 2002, 117, 776.
5. (a) Vilchiz, V. H.; Kloepfer, J. A.; Germaine, A. C.; Lenchenkov, V. A.; Bradforth, S. E. J. Phys. Chem. A 2001, 705, 1711.
6. (b) Pommeret, S.; Naskrecki, R.; van der Meulen, P.; Menard, M.; Vigneron, G.; Gustavsson, T. Chem. Phys. Lett. 1998, 288, 833.
7. (c) Anderson, N. A.; Hang, K.; Asbury, J. B.; Lian, T. Chem. Phys. Lett. 2000, 329, 386.
8. Kloepfer, J. A.; Vilchiz, V. H.; Germaine, A. C.; Lenchenkov, V. A.; Bradforth, S. E. J. Chem. Phys. 2000, 113, 6288.
9. Kloepfer, J. A.; Vilchiz, V. H.; Lenchenkov, V. A.; Bradforth, S. E. Liquid Dynamics: Experiment, Simulation, and Theory; 2002; Vol. 820, p 108.
10. Martini, I. B.; Barthel, E. R.; Schwartz, B. J. J. Am. Chem. Soc. 2002, 124, 7622.
11. Barthel, E. R.; Martini, I. B.; Schwartz, B. J. J. Chem. Phys. 2000, 112, 9433.
12. Barthel E. R.; Sohwartz, B. J. Chem. Phys. Lett. 2003, 375, 435.
13. Chen, X.; Kloepfer, J. A.; Bradforth, S. E.; Lian, R.; Crowell, R. A.; Shkrob, I. A. Manuscript in preparation.
14. Lian, R.; Crowell, R. A.; Shkrob, I. A.; Bartels, D. M.; Chen, X.; Bradforth, S. E. J. Chem. Phys. in press; preprint available on http://www.arXiv.org/abs/physics/0401071.
15. Lenchenkov, V. A.; Chen, X.; Vilchiz, V. H.; Bradforth, S. E. Chem. Phys. Lett. 2001, 342, 111.
16. Lenchenkov, V. A.; Kloepfer, J. A.; Vilchiz, V. H.; Bradforth, S. E. iTo be submitted to J. Phys. Chem.
17. Airey P. L.; Dainton, F. S. Proc. R. Soc. A 1966, 291, 341.
18. Jortner, J.; Ottolenghi, M.; Stein, G. J. Phys. Chem. 1962, 66, 20291 2037.
19. Lian, R.; Oulianov, D. A.; Crowell, R. A.; Shkrob, I. A.; Chen, X.; Bradforth, S. E. To be submitted to J. Phys. Chem. (part 3 of the series).
20. Sheu, W.-S.; Rossky, P. J. Chem. Phys. Lett. 1993, 202, 186/233; J. Am. Chem. Soc. 1993, 115, 7729; J. Phys. Chem. 1996, 100, 1295.
21. Sheu, W.-S.; Rossky, P. J. Chem. Phys. Lett. 1993, 202, 186/233; J. Am. Chem. Soc. 1993, 115, 7729; J. Phys. Chem. 1996, 100, 1295.
22. Sheu, W.-S.; Rossky, P. J. Chem. Phys. Lett. 1993, 202, 186/233; J. Am. Chem. Soc. 1993, 115, 7729; J. Phys. Chem. 1996, 100, 1295.
23. Borgis D.; Staib, A. Chem. Phys. Lett. 1994, 230, 405; J. Chem. Phys. 1995, 103, 2642; J. Chim. Phys. 1996, 93, 1628; J. Phys.: Condens. Matter 1996, 8, 9389; J. Mol. Struct. 1997, 436, 537.
24. Borgis D.; Staib, A. Chem. Phys. Lett. 1994, 230, 405; J. Chem. Phys. 1995, 103, 2642; J. Chim. Phys. 1996, 93, 1628; J. Phys.: Condens. Matter 1996, 8, 9389; J. Mol. Struct. 1997, 436, 537.
25. Borgis D.; Staib, A. Chem. Phys. Lett. 1994, 230, 405; J. Chem. Phys. 1995, 103, 2642; J. Chim. Phys. 1996, 93, 1628; J. Phys.: Condens. Matter 1996, 8, 9389; J. Mol. Struct. 1997, 436, 537.
26. Borgis D.; Staib, A. Chem. Phys. Lett. 1994, 230, 405; J. Chem. Phys. 1995, 103, 2642; J. Chim. Phys. 1996, 93, 1628; J. Phys.: Condens. Matter 1996, 8, 9389; J. Mol. Struct. 1997, 436, 537.
27. Borgis D.; Staib, A. Chem. Phys. Lett. 1994, 230, 405; J. Chem. Phys. 1995, 103, 2642; J. Chim. Phys. 1996, 93, 1628; J. Phys.: Condens. Matter 1996, 8, 9389; J. Mol. Struct. 1997, 436, 537.
28. Borgis, D.; Staib, A. J. Chem. Phys. 1996, 104, 4776/9027.
29. Sauer, M. C., Jr.; Lian, R.; Crowell, R. A.; Bartels, D. M.; Shkrob, I. A.; Bradforth, S. E. To be submitted to J. Phys. Chem. (part 2 of the series); preprint available on http://www.arXiv.org/physics/0404056.
30. Shushin, A. I. J. Chem. Phys, 1992, 97, 1954; Chem. Phys. Lett. 1985, 118, 197; J. Chem. Phys. 1991, 95, 3657.
31. Shushin, A. I. J. Chem. Phys, 1992, 97, 1954; Chem. Phys. Lett. 1985, 118, 197; J. Chem. Phys. 1991, 95, 3657.
32. Shushin, A. I. J. Chem. Phys, 1992, 97, 1954; Chem. Phys. Lett. 1985, 118, 197; J. Chem. Phys. 1991, 95, 3657.
33. Shirom, M.; Stein, G. J. Chem. Phys. 1971, 55, 3372.
34. Iwata, A.; Nakashima, N.; Kusaba, M.; Izawa, Y.; Yamanaka, C. Chem. Phys. Lett. 1993, 207, 137.
35. Handbook of Radiation Chemistry; Tabata, Y., Ito, Y., Tagawa, S., Eds.; CRC Press: Boca Raton, FL, 1991; Table VI.6.
36. Rahn, R. O. Photochem. Photobiol. 1993, 58, 874.
37. Logan, S. R. J. Chem. Soc., Faraday Trans. 1991, 87, 927
38. Dainton, F. S.; Fowles, P. Proc. R. Soc. A 1965, 287, 295
39. Dainton, F. S.; Fowles, P. Proc. R. Soc. A 1965, 287, 312.
40. Jortner, J.; Ottolenghi, M.; Stein, G. J. Phys. Chem. 1964, 68, 247.
41. Farkas, L.; Hirschberg, Y. J. Am. Chem. Soc. 1937, 59, 2450. Getof, N. Monatsch. Chem. 1968, 99, 136. Bernas, A.; Bodard, M.; Saghattchian, D. J. Chim. Phys. 1965, 52, 1418. Von Sonntag, C. Tetrahedron 1969, 25, 5853. Davies, A. K.; Khan, K. A.; McKellar, J. F.; Phillips, G. O. Mol. Photochem. 1976, 7, 389.
42. Farkas, L.; Hirschberg, Y. J. Am. Chem. Soc. 1937, 59, 2450. Getof, N. Monatsch. Chem. 1968, 99, 136. Bernas, A.; Bodard, M.; Saghattchian, D. J. Chim. Phys. 1965, 52, 1418. Von Sonntag, C. Tetrahedron 1969, 25, 5853. Davies, A. K.; Khan, K. A.; McKellar, J. F.; Phillips, G. O. Mol. Photochem. 1976, 7, 389.
43. Farkas, L.; Hirschberg, Y. J. Am. Chem. Soc. 1937, 59, 2450. Getof, N. Monatsch. Chem. 1968, 99, 136. Bernas, A.; Bodard, M.; Saghattchian, D. J. Chim. Phys. 1965, 52, 1418. Von Sonntag, C. Tetrahedron 1969, 25, 5853. Davies, A. K.; Khan, K. A.; McKellar, J. F.; Phillips, G. O. Mol. Photochem. 1976, 7, 389.
44. Farkas, L.; Hirschberg, Y. J. Am. Chem. Soc. 1937, 59, 2450. Getof, N. Monatsch. Chem. 1968, 99, 136. Bernas, A.; Bodard, M.; Saghattchian, D. J. Chim. Phys. 1965, 52, 1418. Von Sonntag, C. Tetrahedron 1969, 25, 5853. Davies, A. K.; Khan, K. A.; McKellar, J. F.; Phillips, G. O. Mol. Photochem. 1976, 7, 389.
45. Farkas, L.; Hirschberg, Y. J. Am. Chem. Soc. 1937, 59, 2450. Getof, N. Monatsch. Chem. 1968, 99, 136. Bernas, A.; Bodard, M.; Saghattchian, D. J. Chim. Phys. 1965, 52, 1418. Von Sonntag, C. Tetrahedron 1969, 25, 5853. Davies, A. K.; Khan, K. A.; McKellar, J. F.; Phillips, G. O. Mol. Photochem. 1976, 7, 389.
46. Kusaba, M.; Nakashima, N.; Kawamura, W.; Izawa, Y.; Yamanaka, C. Chem. Phys. Lett. 1992, 197, 136.
47. Gupta, R. Appl. Opt. 1998, 37, 5964.
48. Hale, G. M.; Querry, M. R. Appl. Opt. 1973, 12, 555.
49. Hart, E. J.; Anbar, M. The Hydrated Electron; Wiley-Interscience: New York, 1970; p 113.
50. The spectrum was taken from: Jou, F.-Y.; Freeman, G. R. Can. J. Chem. 1979, 57, 591. The molar absorptivity at the maximum was from: Elliot, A. J.; Ouellette, D. C.; Stuart, C. R. The Temperature Dependence of the Rate Constants and Yields for the Simulation of the Radiolysis of Heavy Water. AECL report 11658; AECL Research, Chalk River Laboratories: Chalk River, Ontario, Canada, 1996.
51. The spectrum was taken from: Jou, F.-Y.; Freeman, G. R. Can. J. Chem. 1979, 57, 591. The molar absorptivity at the maximum was from: Elliot, A. J.; Ouellette, D. C.; Stuart, C. R. The Temperature Dependence of the Rate Constants and Yields for the Simulation of the Radiolysis of Heavy Water. AECL report 11658; AECL Research, Chalk River Laboratories: Chalk River, Ontario, Canada, 1996.
52. Bartels, D. M.; Crowell, R. A. J. Phys. Chem. A 2000, 104, 3349.
53. Weeks, J. L.; Matheson, M. S. J. Am. Chem. Soc. 1956, 78, 1273. Dainton, F. S. J. Am. Chem. Soc. 1956, 78, 1278.
54. Weeks, J. L.; Matheson, M. S. J. Am. Chem. Soc. 1956, 78, 1273. Dainton, F. S. J. Am. Chem. Soc. 1956, 78, 1278.
55. Quickenden, T. I.; Irvin, J. A. J. Chem. Phys. 1980, 72, 4416.
56. Lymar, S. V.; Schwartz, H. A.; Czapski, G. Radiat. Phys. Chem. 2000, 59, 387 and references therein.
57. Weeks, J. L.; Rabani, J. J. Phys. Chem. 1966, 70, 2100.
58. Crowell, R. A.; Lian, R.; Sauer, Jr., M. C.; Oulianov, D. A.; Shkrob, I. A. Chem. Phys. Lett. 2004, 383, 481.
59. Behar, D.; Czapski, G.; Duchovy, I. J. Phys. Chem. 1970, 74, 2206.
60. Nielsen, S. O.; Michael, B. D.; Hart, E. J. J. Phys. Chem. 1976, 80, 2482.
61. Volman, D. H.; Chen, J. C. J. Am. Chem. Soc. 1959, 81, 4141.
62. Loraine, G. A.; Glaze, W. H. J. Adv. Oxid. Technol. 1999, 4, 424.
63. Czapski, G., Bielski, B. H. J. Radiat. Phys. Chem. 1993, 41, 503; see also Boyle, J. W.; Ghormley, J. A.; Hochanadel, C. J.; Riley, J. F. J. Phys. Chem. 1969, 73, 2886 and Nielsen, S. O.; Michael, B. D.; Hart, E. J. J. Phys. Chem. 1976, 80, 2482.
64. Czapski, G., Bielski, B. H. J. Radiat. Phys. Chem. 1993, 41, 503; see also Boyle, J. W.; Ghormley, J. A.; Hochanadel, C. J.; Riley, J. F. J. Phys. Chem. 1969, 73, 2886 and Nielsen, S. O.; Michael, B. D.; Hart, E. J. J. Phys. Chem. 1976, 80, 2482.
65. Czapski, G., Bielski, B. H. J. Radiat. Phys. Chem. 1993, 41, 503; see also Boyle, J. W.; Ghormley, J. A.; Hochanadel, C. J.; Riley, J. F. J. Phys. Chem. 1969, 73, 2886 and Nielsen, S. O.; Michael, B. D.; Hart, E. J. J. Phys. Chem. 1976, 80, 2482.
66. Perrin, D. D. Ionization Constants of Inorganic Acids and Bases in Aqueous Solution; Pergamon: Oxford, U.K., 1982.
67. Ley, H.; Arenas, B. Z. Phys. Chem. 1932, 17, 177.
68. Perkampus, H.-H. UV-Vis Atlas of Organic Compounds; VCH: New York, 1992; Part 2.
69. Cohen; S. R.; Plane, R. A. J. Phys. Chem. 1957, 61, 1096 (more recent estimates of the association constant are given by: Capone, S.; et al. Thermochim. Acta 1986, 702, 1 (Table 5 therein)).
70. Cohen; S. R.; Plane, R. A. J. Phys. Chem. 1957, 61, 1096 (more recent estimates of the association constant are given by: Capone, S.; et al. Thermochim. Acta 1986, 702, 1 (Table 5 therein)).
71. Davies, C. W. J. Am. Chem. Soc. 1937, 59, 1760.
72. Elliot, A. J. Can. J. Chem. 1992, 70, 1658.
73. Schwartz, H. A.; Bielski, H. J. J. Phys. Chem. 1986, 90, 1445.
74. Nagarajan, V.; Fessenden, R. W. J. Phys. Chem. 1985, 89, 2330.
75. Jayson, G. G.; Parsons, B. J.; Swallow, A. J. J. Chem. Soc., Faraday Trans. 1973, 69, 1597.
76. Zehavi, D.; Rabani, J. J. Phys. Chem. 1972, 76, 312.
77. Devonshire, R.; Weiss, J. J. J. Phys. Chem. 1968, 72, 3815.
78. Karmann, W.; Meissner, G.; Henglein, A. Z. Naturforsch. B 1967, 22, 273.
79. Dogliotti, L.; Hayon, E. J. Phys. Chem. 1968, 72, 1800.
80. Elliot, A. J.; Sopchyshyn, F. C. Int. J. Chem. Kinet. 1984, 16, 1247.
81. Hayon, E.; Treinin, A.; Wilf, J. J. Am. Chem. Soc. 1972, 94, 47.
82. Anbar, M.; Hart, E. J. J. Phys. Chem. 1965, 69, 1244.
83. Kambhampati, K.; Son, D. H.; Kee, T. W.; Barbara, P. F. J. Phys. Chem. A 2002, 706, 2374; J. Phys. Chem. 2001, 105, 8269; Chem. Phys. Lett. 2001, 342, 571.
84. Kambhampati, K.; Son, D. H.; Kee, T. W.; Barbara, P. F. J. Phys. Chem. A 2002, 706, 2374; J. Phys. Chem. 2001, 105, 8269; Chem. Phys. Lett. 2001, 342, 571.
85. Kambhampati, K.; Son, D. H.; Kee, T. W.; Barbara, P. F. J. Phys. Chem. A 2002, 706, 2374; J. Phys. Chem. 2001, 105, 8269; Chem. Phys. Lett. 2001, 342, 571.
86. Ohno, S. Bull. Chem. Soc. Jpn. 1967, 40, 1765. Shirom, M.; Stein, G. J. Chem. Phys. 1971, 55, 3379.
87. Ohno, S. Bull. Chem. Soc. Jpn. 1967, 40, 1765. Shirom, M.; Stein, G. J. Chem. Phys. 1971, 55, 3379.
88. Kopitzky, R.; Grothe, H. Chem. Eur. J. 2002, 8, 5601.
89. Ibers, J. A.; Davidson, N. J. Am. Chem. Soc. 1951, 73, 476.
90. Rabinovitch, E. Rev. Mod. Phys. 1942, 14, 112.
91. Awtrey, A. D.; Connick, R. E. J. Am. Chem. Soc. 1951, 73, 1842; the spectrum for thiosulfate can also be found in: Fox, M. F.; Hayon E. J. Chem. Soc., Faraday. Trans. 1 1977, 73, 872.
92. Awtrey, A. D.; Connick, R. E. J. Am. Chem. Soc. 1951, 73, 1842; the spectrum for thiosulfate can also be found in: Fox, M. F.; Hayon E. J. Chem. Soc., Faraday. Trans. 1 1977, 73, 872.
93. Weeks, J. L.; Meaburn, G. M. A. C.; Gordon, S. Radiat. Res. 1963, 19, 559.
94. Fox, M. F.; Hayon E. J. Chem. Soc., Faraday Trans. 1 1979, 75, 1380; see also the spectra in: Noda, L. H.; Kuby, S. A.; Lardy, H. J. Am. Chem. Soc. 1953, 75, 913. Ellis, A. J.; Golding, R. M. J. Chem. Soc. 1959, 127. Suman, P.; Szafranski, W. Anal. Chem. 1976, 48, 2162.
95. Fox, M. F.; Hayon E. J. Chem. Soc., Faraday Trans. 1 1979, 75, 1380; see also the spectra in: Noda, L. H.; Kuby, S. A.; Lardy, H. J. Am. Chem. Soc. 1953, 75, 913. Ellis, A. J.; Golding, R. M. J. Chem. Soc. 1959, 127. Suman, P.; Szafranski, W. Anal. Chem. 1976, 48, 2162.
96. Fox, M. F.; Hayon E. J. Chem. Soc., Faraday Trans. 1 1979, 75, 1380; see also the spectra in: Noda, L. H.; Kuby, S. A.; Lardy, H. J. Am. Chem. Soc. 1953, 75, 913. Ellis, A. J.; Golding, R. M. J. Chem. Soc. 1959, 127. Suman, P.; Szafranski, W. Anal. Chem. 1976, 48, 2162.
97. Fox, M. F.; Hayon E. J. Chem. Soc., Faraday Trans. 1 1979, 75, 1380; see also the spectra in: Noda, L. H.; Kuby, S. A.; Lardy, H. J. Am. Chem. Soc. 1953, 75, 913. Ellis, A. J.; Golding, R. M. J. Chem. Soc. 1959, 127. Suman, P.; Szafranski, W. Anal. Chem. 1976, 48, 2162.
98. Fox, M. F.; Smith C. B. J. Chem. Soc., Faraday Trans. 1 1981, 77, 1497.
99. Gusarsky, E.; Treinin, A. J. Phys. Chem. 1965, 69, 3176.
100. Waltz, W. L.; Adamson, A. W. J. Phys. Chem. 1969, 73, 4250.
101. Ohno, S. Bull. Chem. Soc. Jpn. 1967, 40, 1770.
102. Barret, J.; Fox, M. F.; Mansell, A. L. J. Phys. Chem. 1965, 69, 2996.
103. Jortner, J.; Raz, B.; Stein G. Trans. Faraday Soc. 1960, 56, 1273. See also spectra in: Stein, G.; Treinin, A. Trans. Faraday. Soc. 1959, 55, 1091. Jortner, J.; Treinin, A. Trans. Faraday Soc. 1962, 58, 1503. Fox, M. F.; Hayon, E. J. Chem. Soc., Faraday Trans. 1 1977, 73, 1003.
104. Jortner, J.; Raz, B.; Stein G. Trans. Faraday Soc. 1960, 56, 1273. See also spectra in: Stein, G.; Treinin, A. Trans. Faraday. Soc. 1959, 55, 1091. Jortner, J.; Treinin, A. Trans. Faraday Soc. 1962, 58, 1503. Fox, M. F.; Hayon, E. J. Chem. Soc., Faraday Trans. 1 1977, 73, 1003.
105. Jortner, J.; Raz, B.; Stein G. Trans. Faraday Soc. 1960, 56, 1273. See also spectra in: Stein, G.; Treinin, A. Trans. Faraday. Soc. 1959, 55, 1091. Jortner, J.; Treinin, A. Trans. Faraday Soc. 1962, 58, 1503. Fox, M. F.; Hayon, E. J. Chem. Soc., Faraday Trans. 1 1977, 73, 1003.
106. Jortner, J.; Raz, B.; Stein G. Trans. Faraday Soc. 1960, 56, 1273. See also spectra in: Stein, G.; Treinin, A. Trans. Faraday. Soc. 1959, 55, 1091. Jortner, J.; Treinin, A. Trans. Faraday Soc. 1962, 58, 1503. Fox, M. F.; Hayon, E. J. Chem. Soc., Faraday Trans. 1 1977, 73, 1003.
107. Buck, R. P.; Singhadeja, S.; Rogers, L. B. Anal. Chem. 1954, 26, 1240.
108. Jortner, J.; Raz, B.; Stein, G. J. Chem. Phys. 1961, 34, 1455; Weeks, J. L.; Meaburn, G. M. A. C.; Gordon, S. Radiat. Res. 1963, 19, 559.
109. Jortner, J.; Raz, B.; Stein, G. J. Chem. Phys. 1961, 34, 1455; Weeks, J. L.; Meaburn, G. M. A. C.; Gordon, S. Radiat. Res. 1963, 19, 559.