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34
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3142783955
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note
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Exact solution of the diffusion equation is given in ref 24 by assuming that surface concentration is not constant and the flux across the surface is proportional to the difference between the actual concentration just within the surface and the concentration in equilibrium with the surrounding atmosphere. In this case, the value of M/M∞ has initially linear dependence on time.
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35
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3142736878
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note
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If the surface reaction controls slightly the flux across the surface, the evaluation of the diffusion constant from eq 8 involves an underestima tion. In this case, evaluated D̃ in Figure 8 gives a lower limit of the exact diffusivity.
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