Photodissociation rate constants for VUV processes of CF3Cl and CF2Cl2 in the upper atmosphere. A MQDO study

Journal of Physical Chemistry A

Volumn 108, Issue 26, 2004, Pages 5699-5703

  Mayor, E ^a   Velasco, A M ^a   Martin I ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

IONOSPHERE; KINETIC ENERGY; MATHEMATICAL MODELS; PARAMETER ESTIMATION; PHOTODISSOCIATION; RATE CONSTANTS; ULTRAHIGH VACUUM; ULTRAVIOLET RADIATION; X RAYS;

ELECTRIC DIPOLE MECHANISM; MOLECULAR QUANTUM DEFECT ORBITAL (MQDO); RYDBERG ELECTRON;

CHLOROFLUOROCARBONS;

EID: 3142722000     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp049718h     Document Type: Article

References (34)

1. Molina, M. J.; Rowland, F. S. Nature 1974, 249, 810.
2. Creasey, J. C.; Smith, D. M.; Tuckett, R. P.; Yoxall, K. R.; Codling, K.; Hatherly, P. A. J. Phys. Chem. 1996, 100, 4350.
3. Arnold, S. J.; Rojeska, H. Appl. Opt. 1973, 12, 169.
4. Wayne, R. P. Chemistry of Atmospheres, 3rd ed.; University Press: Oxford, 2001.
5. Torres, I.; Martinez, R.; Sánchez Rayo, M. N.; Castaño, F. J. Phys. B: At. Mol. Opt. Phys. 2000, 33, 3615.
6. Velasco, A. M.; Mayor, E.; Martín, I. Chem. Phys. Lett. 2003, 376, 159.
7. Velasco, A. M.; Mayor, E.; Martín, I. Chem. Phys. Lett. 2003, 377, 189.
8. Martín, I.; Lavín, C.; Velasco, A. M.; Martín, M. O.; Karwowski, J.; Diercksen, G. H. F. Chem. Phys. Lett. 1996, 202, 307.
9. Martín, I.; Lavín, C.; Karwowski, J. Chem. Phys. Lett. 1996, 255, 89.
10. Velasco, A. M.; Martín, I.; Lavín, C. Chem. Phys. Lett. 1997, 264, 579.
11. Martín, I.; Velasco, A. M.; Lavín, C. Adv. Quantum Chem. 2001, 39, 145.
12. Velasco, A. M.; Bustos, E.; Martín, I.; Lavín, C. J. Phys. Chem. A 2002, 106, 6401.
13. Martín, I.; Velasco, A. M.; Lavín, C.; Olalla, E.; Bustos, E. Int. J. Quantum Chem. 2001, 85, 345.
14. Bustos, E.; Velasco, A. M.; Martín, I.; Lavín, C. J. Phys. Chem. A 2002, 106, 35.
15. Martín, I.; Simons, G. J. Chem. Phys. 1975, 62, 4799.
16. Seinfeld, J. H.; Pandis, S. N. Atmospheric Chemistry and Physics; Wiley-Interseience: New York, 1998.
17. Kirby, K. E.; Constantinides, E. R.; Babeu, S.; Oppenheimer, M.; Victor, G. A. At. Data Nucl. Data Tables 1979, 23, 63.
18. Picone, J. M.; Hedin, A. E.; Drob, D. P.; Aikin, A. C. J. Geophys. Res. 2002, 107, 1468.
19. Yen, M. W.; Johnson, P. M.: White, M. G. J. Chem. Phys. 1993, 99, 126.
20. Zhang, W.; Cooper, G.; Ibuki, T.; Brion, C. E. Chem. Phys. 1991, 151, 343.
21. Zhang, W.; Cooper, G.; Ibuki, T.; Brion, C. E. Chem. Phys. 1991, 151, 357.
22. Fano, U.; Cooper, J. W. Rev. Mod. Phys. 1968, 40, 441.
23. Au, J. W.; Burton, G. R.; Brion, C. E. Chem. Phys. 1997, 221, 151.
24. Suto, M.; Lee, L. C. J. Chem. Phys. 1983, 179, 127.
25. Novak, I.; Benson, J. M.; Potts, A. W. J. Electron. Spectrosc. Relat. Phenom. 1966, 41, 175.
26. Cooper, G.; Zhang, W.; Brion, C. E.; Tan, K. H. Chem. Phys. 1990, 145, 117.
27. Bozek, J. D.; Bancroft, G. M.; Cutler, J. N.; Tan, K. H.; Yates, B. W.; Tse, J. S. Chem. Phys. 1989, 132, 257.
28. Finlayson-Pitts, B. J.; Pitts, J. N. Chemistry of the Upper and Lower Atmosphere; Academic Press: New York, 2000.
29. Nolle, A.; Heydtmann, H.; Meller, R.; Moortgart, G. K Geophys. Res. Lett. 1993, 20, 707.
30. Simon, P. C.; Gillotay, D.; Vanlaethem-Meuree, N.; Wisemberg, J. J. Atmos. Chem. 1998, 7, 107.
31. Royal Greenwich Observatory, USAF, NOAA web: ftp://ftp.ngdc.NOAA.noaa. gov/STP/SOLAR_DATA/SOLAR_RADIO/FLUX/.
32. Woods, T. N.; Rottman, G. J. J. Geophys. Res. 1990, 95, 6227.
33. Mount, G. H.; Rottman, G. J. J. Geophys. Res. 1985, 90, 13031.
34. Vatsa, R. K.; Volpp, H.-R. Chem. Phys. Lett. 2001, 340, 289.