Statistical mechanics of diffusion in polymers: Conductivity and electroosmosis in ion exchange membranes

Journal of Membrane Science

Volumn 240, Issue 1-2, 2004, Pages 25-35

  Schaetzel, Pierre ^a   Nguyen, Q T ^a   Riffault, Benoît ^a  

^a UNIVERSITÉ DE CAEN   (France)

Author keywords

Dusty gas model; Generalized Nernst Planck equation; Ion exchange membrane; Simulation

Indexed keywords

COMPUTER SIMULATION; DIFFUSION; ION EXCHANGE; OSMOSIS; STATISTICAL MECHANICS; SWELLING;

ION-EXCHANGE CAPACITY; MEMBRANE SCIENCE;

POLYMERIC MEMBRANES;

POLYMER;

CONDUCTION; DIFFUSION; ION EXCHANGE; MEMBRANE; OSMOSIS; SWELLING;

ANALYTIC METHOD; ARTICLE; DIFFUSION; ELECTROOSMOSIS; EMPIRICISM; GAS; ION EXCHANGE; MATHEMATICAL COMPUTING; MATHEMATICAL MODEL; MEMBRANE CONDUCTANCE; MEMBRANE MODEL; MEMBRANE TRANSPORT; MOLECULAR MECHANICS; PRIORITY JOURNAL; QUALITATIVE ANALYSIS; SIMULATION; STATISTICAL ANALYSIS; TRANSPORT KINETICS;

EID: 3142540718     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2004.04.009     Document Type: Article

References (18)

1. Schaetzel P., Auclair B. Transport properties of a weak acid ion-exchange membrane: the frictional model and the Stefan-Maxwell diffusion model. Definition of the heterogeneous membrane model. Electrochim. Acta. 38:1993;329-340
2. Despić A., Hills G.J. Electrochemical properties of ion-exchange resins. Part 2. Ionic conductance in cross-linked polymethacrylic acid. Trans. Faraday Soc. 51:1955;1260-1267
3. Despić A., Hills G.J. Electro-osmosis in charged membranes. The determination of primary solvation numbers. Faraday Soc. Discuss. 21:1956;150-162
4. Despić A., Hills G.J. Ionic self-diffusion coefficients in ion-exchange resins. Trans. Faraday Soc. 53:1957;1262-1268
5. Schaetzel P., Favre E., Auclair B., Nguyen Q.T. Mass transfer through ion exchange membranes. Comparison between the diffusion and the diffusion-convection Stefan-Maxwell equations. Electrochim. Acta. 42(16):1997;2475-2483
6. F. Helfferich, Ion Exchange, McGraw-Hill Book Company Inc., New York, 1962.
7. Spiegler K.S. Transport processes in ionic membranes. J. Chem. Soc., Faraday Trans. 54(9):1958;1408-1428
8. Schaetzel P., Auclair B. The generalized multicomponent Nernst-Planck diffusion equation - diffusion and self diffusion coefficients. Electrochim. Acta. 43(21-22):1998;3375-3377
9. Schaetzel P., Vauclair C., Luo G., Nguyen Q.T. The solution-diffusion model - order of magnitude calculation of coupling between the fluxes in pervaporation. J. Membr. Sci. 191(1-2):2001;103-108
10. R.A. Robinson, R.H. Stokes, Electrolyte Solutions, Butterworths and Co. Ltd., London, 1959.
11. Schaetzel P., Favre E., Nguyen Q.T., Neel J. Mass transfer analysis of pervaporation through an ion exchange membrane. Desalination. 90:1993;259-276
12. Schaetzel P., Bendjama Z., Vauclair C., Nguyen Q.T. Ideal and non-ideal diffusion through polymers - application to pervaporation. J. Membr. Sci. 191(1-2):2001;95-102
13. H. Fujita, Diffusion in Polymer-Diluent Systems, Fortschr. Hochpolym.-Forsch., Bd. 3, S. 1-47, 1961.
14. Zabolotsky V.I., Manzanares J.A., Nikonenko V.V., Lebedev K.A., Lovtsov E.G. Space charge effect on competitive ion transport through ion-exchange membranes. Desalination. 147(1-3):2002;387-392
15. Basu S., Sharma M.M. An improved space-charge model for flow through charged microporous membranes. J. Membr. Sci. 124(1(5)):1997;77-91
16. Palatý Z., Aková A. Transport of some strong incompletely dissociated acids through anion-exchange membrane. J. Colloid. 268(1):2003;188-199
17. Guzman-Garcia A.G., Pintauro P.N., Verbrugge M.W., Hill R.F. Development of a space-charge transport model for ion-exchange membranes. AIChE J. 36(7):1990;1061-1074
18. Yahan Yang P.N., Pintauro P.N. Multicomponent space-charge transport model for ion-exchange membranes. AIChE J. 46(6):2000;1177-1190