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note
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3 (0.45 mmol, 58.12 mg) and stirred for 5 mins. The mixture was filtered and the filtrate was allowed to stand at room temperature. After two weeks, blue-green block crystals of complex 1 were isolated. Yield 25%. Blue-green block crystals of complex 2 were prepared in a similar manner to those of complex 1. Yield 27%. Satisfied elemental analysis was obtained for each complex.
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23
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31344469162
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note
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2 using SHELXL-97 program. All non-H atoms were refined anisotropically, the H atoms attached to C and N atoms were added at calculated position with C-H distances 0.96-0.97 Å and N-H distances 0.90-0.91 Å, respectively, the H atoms linked to O atoms were located from the difference Fourier map and refined freely with O-H distances 0.86(4) Å. CCDC 260194-260195 (for 1 and 2, respectively) contain the supplementary crystallographic data for this paper.
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