Fe isotope fractionation during the precipitation of ferrihydrite and transformation of ferrihydrite to goethite

Mineralogical Magazine

Volumn 69, Issue 5, 2005, Pages 667-676

  Clayton, R E ^a   Hudson Edwards, K A ^a   Malinovsky, D ^b   Andersson, P ^c  

^a UNIVERSITY OF LONDON   (United Kingdom)

^b LULEÅ UNIVERSITY OF TECHNOLOGY   (Sweden)

^c SWEDISH MUSEUM OF NATURAL HISTORY   (Sweden)

Author keywords

Ferric nitrate; Ferrihydrite; Fractionation; Goethite; Iron isotope; Transformation

Indexed keywords

FRACTIONATION; IMPURITIES; IRON; ISOTOPES; LOW TEMPERATURE EFFECTS; OXIDATION; PH; PRECIPITATION (CHEMICAL); SOILS; SOLUTIONS; SORPTION; SUBSTRATES;

ABIOTIC CONDITIONS; FERRIC NITRATE; FERRIHYDRITE; GOETHITE; IRON ISOTOPE; TRANSFORMATION;

MINERALOGY;

FERRIHYDRITE; GOETHITE; ISOTOPIC FRACTIONATION; POLLUTANT; SUBSTRATE;

EID: 31344461357     PISSN: 0026461X     EISSN: None     Source Type: Journal    
DOI: 10.1180/0026461056950278     Document Type: Article

References (36)

1. Anbar, A.D. (2004) Iron stable isotopes: beyond biosignatures. Earth and Planetary Science Letters, 217, 223-236.
2. Anbar, A.D., Roe, J.E., Barling, J. and Nealson, K.H. (2000) Nonbiological fractionation of Fe isotopes. Science, 288, 126-128.
3. Anbar, A.D., Knab, K. and Barling, J. (2001) Precise determination of mass-dependent variations in the isotopic composition of Mo using MC-ICP-MS. Analytical Chemistry, 73, 1425.
4. Andrén, H., Rodushkin, I., Stenberg, A., Malinovsky, D. and Baxter, D.C. (2004) Sources of mass bias and isotope ratio variation in multi-collector ICP-MS: optimization of instrumental parameters based on experimental observations. Journal of Analytical Atomic Spectrometry, 19, 1217-1224.
5. Beard, B.L. and Johnson, C.M. (2004) Fe isotope variations in the modern and ancient Earth and other planetary bodies. Pp. 319-357 in: Biomineralization (P.M. Dove, J.J. de Yoreo and S. Weiner, editors). Reviews in Mineralogy and Geochemistry, 55, Mineralogical Society of America and the Geochemical Society, Washington, D.C.
6. Brantley, S.L., Liermann, L.J., Guynn, R.L., Anbar, A., Icopini, G.A. and Barling, J. (2004) Fe isotopic fractionation during mineral dissolution with and without bacteria. Geochimica et Cosmochimica Acta, 68, 3189-3204.
7. 3+ reduction in a jet-fuel contaminated aquifer. Mineralogical Magazine, 62A, 255-256.
8. Bullen, T.D., White, A.F., Childs, C.W. Vivet, D.V. and Schultz, M.S. (2001) Demonstration of significant abiotic iron isotope fractionation in nature. Geology, 29, 699-702.
9. Bullen, T.D., White, A., Mandernack, K. and Witte, K. (2002) Iron isotope fractionation: does equilibrium or disequilibrium rule? Geochimica et Cosmochimica Acta, 66, A110.
10. Cardinal, D., Alleman, L.Y., de Jong, J., Ziegler, K. and Andre, L. (2003) Isotopic composition of silicon measured by multicollector plasma source mass spectrometry in dry plasma mode Journal of Analytical Atomic Spectrometry, 18, 213-218.
11. Criss, R.E. (1999) Principles of Stable Isotope Distribution. Oxford University Press, New York.
12. Croal, L.R., Johnson, C.M., Beard, B.L. and Newman, D.K. (2004) Iron isotope fractionation by Fe(II)-oxidizing photoautotrophic bacteria. Geochimica et Cosmochimica Acta, 68, 1227-1242.
13. 3+-Perchloratlösungen. Helvetica Chimica Acta, 26, 212-214.
14. Hair, N.J. and Beattie, J.K. (1977) Structure of hexaqua iron (III) nitrate trihydrate. Comparison of iron (II) and iron (III) bond lengths in high-spin octahedral environments. Inorganic Chemistry, 16, 245-250.
15. Hudson-Edwards, K.A., Jamieson, H.E., Charnock, J.M. and Macklin, M.G. (2005) Arsenic speciation in waters and sediment of ephemeral floodplain pools, Ríos Agrio-Guadiamar, Aznalcóllar, Spain. Chemical Geology, 219, 175-192.
16. Jenne, E.A. (1968) Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: the significant role of hydrous Mn and Fe oxides. Advances in Chemistry Series, 73, 337-388.
17. Johnson, C.A. (1986) The regulation of trace element concentrations in river and estuarine waters contaminated with acid mine drainage: The adsorption of Cu and Zn on amorphous Fe oxyhydroxide. Geochimica et Cosmochimica Acta, 50, 2433-2438.
18. Johnson, C.M., Beard, B.L. and Albarède, F., editors (2004) Geochemistry of Non-traditional Stable Isotopes. Reviews in Mineralogy and Geochemistry, 55, Mineralogical Society of America and the Geochemical Society, Washington, D.C.
19. Johnson, C.M., Skulan, J.L., Beard, B.L., Sun, H., Nealson, K.H. and Braterman, P.S. (2002) Isotopic fractionation between Fe(III) and Fe(II) in aqueous solutions. Earth and Planetary Science Letters, 195, 141-153.
20. Kukkadapu, R.K., Zachara, J.M., Fredrickson, J.K., Smith, S.C., Dohnalkova, A.C. and Russell, C.K. (2003) Transformation of 2-line ferrihydrite to 6-line ferrihydrite under oxic and anoxic conditions. American Mineralogist, 88, 1903-1914.
21. Malinovsky, D., Stenberg, A., Rodushkin, I., Andren, H., Ingri, J., Öhlander, B. and Baxter, D.C. (2003) Performance of high resolution MC-ICP-MS for Fe isotope ratio measurements in sedimentary geologic materials. Journal of Analytical Atomic Spectrometry, 18, 687-695.
22. Mandernack, K.W., Bullen, T.D., Shanks, W.S. and Emerson, D. (2002) Stable oxygen and iron isotopic analyses of biotic and abiotic iron oxides precipitated in stream waters and in laboratory synthesis experiments. International Association of Geochemistry and Cosmochemistry, 4th International Symposium on Applied Isotope Geochemistry (AIG-IV), Pacific Grove, California, USA, Program and Abstracts, 7.
23. Marechal, C., Télouk, P. and Albarède, F. (1999) Precise analysis of copper and zinc isotope compositions by plasma source mass spectrometry. Chemical Geology, 156, 251-273.
24. Matthews, A., Zhu, X.-K. and O'Nions, R.K. (2001) Kinetic iron stable isotope fractionation between iron (-II) and (-III) complexes in solution. Earth and Planetary Science Letters, 192, 81-92.
25. O'Neil, J.R. (1986) Theoretical and experimental aspects of isotopic fractionation. Pp. 1-40 in: Stable Isotopes in High Temperature Geological Processes (J.W. Valley, H.P. Taylor, Jr. and J.R. O'Neil, editors). Reviews in Mineralogy, 16, Mineralogical Society of America, Washington D.C.
26. Parkman, R.H., Charnock, J.M., Bryan, N.D., Livens, F.R. and Vaughan, D.J. (1999) Reactions of copper and cadmium ions in aqueous solution with goethite, lepidocrocite, mackinawite and pyrite. American Mineralogist, 84, 407-419.
27. Roe, J.E., Anbar, A.D. and Barling, J. (2003) Nonbiological fractionation of Fe isotopes: evidence of an equilibrium isotope effect. Chemical Geology, 195, 69-85.
28. Schauble, E.A. (2004) Applying stable isotope fractionation theory to new systems. Pp. 65-111 in: Geochemistry of Non-traditional Stable Isotopes (C.M. Johnson, B.L. Beard and F. Albarède, editors). Reviews in Mineralogy and Geochemistry, 55. Mineralogical Society of America and the Geochemical Society, Washington, D.C.
29. Schwertmann, U. and Cornell, R.M. (1991) Iron Oxides in the Laboratory: Preparation and Characterization. VCH Publishers, Weinheim, Germany, 91 pp.
30. Schwertmann, U. and Murad, E. (1983) Effect of pH on the formation of goethite and hematite from ferrihydrite. Clays and Clay Minerals, 4, 277-284.
31. Skulan, J.L., Beard, B.L. and Johnson, C.M. (2002) Kinetic and equilibrium Fe isotope fractionation between aqueous Fe(III) and hematite. Geochimica et Cosmochimica Acta, 66, 2995-3015.
32. Welch, S.A., Beard, B.L., Johnson, C.M. and Braterman, P.S. (2003) Kinetic and equilibrium Fe isotope fractionation between aqueous Fe(III) and Fe(III). Geochimica et Cosmochimica Acta, 67, 4231-4250.
33. Wiesli, R.A., Beard, B.L. and Johnson, C.M. (2003) Experimental determination of Fe isotope fractionation between aq. Fe(II), 'green rust' and siderite. Geochimica et Cosmochimica Acta, 67, A533.
34. Woodhead, J. (2002) A simple method for obtaining highly accurate Pb isotope data by MC-ICP-MS. Journal of Analytical Atomic Spectrometry, 17, 1381-1385.
35. Zhu, X.-K., O'Nions, R.K., Guo, Y. and Reynolds, B.C. (2000) Secular variation of iron isotopes in north Atlantic Deep Water. Science, 287, 2000-2002.
36. Zhu, X.-K., Guo, Y., Williams, R.J.P., O'Nions, R.K., Matthews, A., Belshaw, N.S., Canters, G.W., de Waal, E.C., Weser, U., Burgess, B.K. and Salvato, B. (2002) Mass fractionation processes of transition metal isotopes. Earth and Planetary Science Letters, 200, 47-62.