[M(R-dmet)2] bis(1,2-dithiolenes): A promising new class intermediate between [M(dmit)2] and [M(R,R′-timdt)2] (M = Ni, Pd, Pt)

Inorganic Chemistry

Volumn 44, Issue 26, 2005, Pages 9610-9612

  Aragoni, M Carla ^a   Arca, Massimiliano ^a   Devillanova, Francesco A ^a   Isaia, Francesco ^a   Lippolis, Vito ^a   Mancini, Annalisa ^a   Pala, Luca ^a   Slawin, Alexandra M Z ^b   Woollins, J Derek ^b  

^a UNIVERSITY OF CAGLIARI   (Italy)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 31144477273     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic051260q     Document Type: Article

References (22)

1. Yang, C.; Qin, J.; Si, J.; Wang, Y.; Ye, P.; Li, Y. Synth. Met. 1999, 1-3, 1578.
2. Faulmann, C.; Cassoux, P. Prog. Inorg. Chem. 2004, 52, 399.
3. (a) Chen, X. F.; Chen, H.; Gao, X.; Zang, X. P.; Cheng, Z. Supramol. Sci. 1998, 5, 531.
4. (b) Mueller-Westerhoff, U. T.; Vance, B.; Yoon, D. I. Tetrahedron 1991, 47, 909.
5. McNamara, J. P.; Joule, J. A.; Hillier, I. H.; Garner, C. D. Chem. Commun. 2005, 177 and references cited therein.
6. (a) Kirk, M. L.; McNaughton, R. L.; Helton, M. E. Prog. Inorg. Chem. 2004, 52, 111.
7. (b) Ray, K.; Weyhermüller, T.; Wieghardt, K. Inorg. Chem. 2005, 44, 5345.
8. Ward, M. D.; McCleverty, J. A. J. Chem. Soc., Dalton Trans. 2002, 275.
9. Beswick, C. L.; Schulman, J. M.; Stiefel, E. I. Prog. Inorg. Chem. 2004, 52, 55.
10. Pullen, A. E.; Olk, R.-M. Coord. Chem. Rev. 1999, 188, 211.
11. Kato, R. Chem. Rev. 2004, 104, 5319.
12. Aragoni, M. C.; Arca, M.; Demartin, F.; Devillanova, F. A.; Garau, A.; Isaia, F.; Lelj, F.; Lippolis, V.; Verani, G. J. Am. Chem. Soc. 1999, 121, 7098.
13. Aragoni, M. C.; Arca, M.; Demartin, F.; Devillanova, F. A.; Lelj, F.; Isaia, F.; Lippolis, V.; Mancini, A.; Pala, L.; Verani, G. Eur. J. Inorg. Chem. 2004, 3099 and references cited therein.
14. Aragoni, M. C.; Arca, M.; Cassano, T.; Denotti, C.; Devillanova, F. A.; Frau, R.; Isaia, F.; Lelj, F.; Lippolis, V.; Nitti, L.; Romaniello, P.; Tommasi, R.; Verani, G. Eur. J. Inorg. Chem. 2003, 1939.
15. Aragoni, M. C.; Arca, M.; Caironi, M.; Denotti, C.; Devillanova, F. A.; Grigiotti, E.; Isaia, F.; Laschi, F.; Lippolis, V.; Natali, D.; Pala, L.; Sampietro, M.; Zanello, P. Chem. Commun. 2004, 1882.
16. Scheibe, S.; Pedersen, B. J.; Lawesson, S.-O. Bull. Soc. Chim. Belg. 1978, 87, 229.
17. The unit cell of 4 contains two crystallographically independent centrosymmetric units (Figure S1 in the Supporting Information). A list of bond distances and angles for both units and a packing diagram in color for 4 is provided as the Supporting Information.
18. 2] dithiolenes.
19. 4 octaatomic rings was observed. See: Aragoni, M. C.; Arca, M.; Devillanova, F. A.; Isaia, F.; Lippolis, V.; Mancini, A.; Pala, L.; Slawin, A. M. Z.; Woollins, J. D. Chem. Commun. 2003, 2226.
20. 2btiaz with the mPW1PW functional. LanL2DZ basis sets with ECPs were used for the metal centers, while Schafer et al. pVDZ basis sets were used for C, H, N, and S. More details are reported in the Supporting Information.
21. -1 for 5, 6, and 7, respectively).
22. 1Bu transition: 1.429 (0.481), 1.286 (0.397), and 1.420 (0.497) eV for 5-7, respectively.