Radical polymerization of methacrylates having acetylenic moiety activated by electron-withdrawing group as a reactive functional group

Reactive and Functional Polymers

Volumn 66, Issue 2, 2006, Pages 229-238

  Kuroda, Hirofumi ^a   Nakatsuchi, Sayaka ^a   Kitao, Nobuyoshi ^a   Nakagawa, Tsuyoshi ^a  

^a TOYAMA NATIONAL COLLEGE OF TECHNOLOGY   (Japan)

Author keywords

Acetylenes; Electron withdrawing groups; Methacrylates; Radical polymerization; Reactive polymer

Indexed keywords

ACETYLENE; ELECTRONS; REACTION KINETICS; SYNTHESIS (CHEMICAL); YIELD STRESS;

ACETYLENES; ELECTRON-WITHDRAWING GROUPS; METHACRYLATES; RADICAL POLYMERIZATION; REACTIVE POLYMER;

FREE RADICAL POLYMERIZATION;

EID: 31144462535     PISSN: 13815148     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.reactfunctpolym.2005.07.027     Document Type: Article

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22. The absorptions attributed to acetylene moiety in the IR spectra of insoluble 1 obtained at high concentrations were clearly observed in a similar way to the IR spectra of the soluble 1. The intensities of the absorptions were almost the same as with 2a obtained in the case of Run 3. From the results and the reaction properties of alkynes, the degree of gelation may be low.
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