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Volumn 110, Issue 1, 2006, Pages 319-326

Interplay between barrier width and height in electron tunneling: Photoinduced electron transfer in porphyrin-based donor-bridge-acceptor systems

Author keywords

[No Author keywords available]

Indexed keywords

BRIDGE COMPONENTS; DISTANCE MEASUREMENT; ELECTRON TRANSITIONS; ELECTRONS; PHOTOSYNTHESIS; PORPHYRINS; PRODUCT DESIGN;

EID: 31144432348     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp054420s     Document Type: Article
Times cited : (90)

References (44)
  • 13
    • 31144453200 scopus 로고    scopus 로고
    • note
    • Previously we have reported 25.3 Å, but more sophisticated methods estimate the distance to be 26.5 Å; see ref 39.
  • 25
    • 31144432533 scopus 로고    scopus 로고
    • note
    • This is a consequence of high absorption in these regions because we excite at 574 nm to minimize the AuP absorption. Therefore the absorption in the mentioned areas are very high as the extinction coefficient is much larger at these wavelengths; see the absorption spectrum in Figure 3a.
  • 27
    • 31144464668 scopus 로고    scopus 로고
    • note
    • +, the same sets of parameters are used, with the exception of the donor-acceptor distance; see ref 9 for details.
  • 36
    • 31144441312 scopus 로고    scopus 로고
    • note
    • + electrode (E = 0.45 versus SHE).
  • 44
    • 31144465445 scopus 로고    scopus 로고
    • note
    • The singlet excited-state energies of all the different bridges (RB and nB) are found to be proportional to their first reduction potentials.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.