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Previously we have reported 25.3 Å, but more sophisticated methods estimate the distance to be 26.5 Å; see ref 39.
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This is a consequence of high absorption in these regions because we excite at 574 nm to minimize the AuP absorption. Therefore the absorption in the mentioned areas are very high as the extinction coefficient is much larger at these wavelengths; see the absorption spectrum in Figure 3a.
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27
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31144464668
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note
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+, the same sets of parameters are used, with the exception of the donor-acceptor distance; see ref 9 for details.
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28
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31144441312
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37
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44
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31144465445
-
-
note
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The singlet excited-state energies of all the different bridges (RB and nB) are found to be proportional to their first reduction potentials.
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