Secondary bonding interactions observed in two arsenic thiolate complexes

Inorganic Chemistry

Volumn 44, Issue 26, 2005, Pages 9634-9636

  Carter, Timothy G ^a   Healey, Elisabeth Rather ^a   Pitt, Melanie A ^a   Johnson, Darren W ^a  

^a NONE

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EID: 31044443826     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic051522o     Document Type: Article

References (20)

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15. A CSD (Conquest Version 1.7, February 2005 Release) search of compounds that possessed at least one As-S bond (with S also bonded to a C) revealed 59 strucures of which only 45 contained an As ion not also bonded to a carbon atom.
16. 3) δ 8.58 (dd, 3H, J = 7.2, 1.2 Hz), 8.55 (dd, 3H, J = 7.2, 1.2 Hz), 8.22 (dd, 3H, J = 8.4, 1.2 Hz), 8.14 (dd, 3H, J = 8.4, 1.2 Hz), 7.75 (dt, 6H, J = 7.5, 0.9), 4.58 (m, 3H), 4.44 (m, 3H), 3.17 (m, 6H).
17. Jankowski, Z.; Stolarski, R. Pol. J. Chem. 1981, 55, 555.
18. -3.
19. A CSD search revealed that the few As⋯O SBIs previously observed are in the range of 2.7-3.2 Å. For a representative example, see: Tani, K.; Hanabusa, S.; Kato, S.; Mutoh, S.; Suzuki, S.; Ishida, M. J. Chem. Soc., Dalton Trans. 2001, 518.
20. Cline, D. J.; Thorpe, C.; Schneider, J. P. J. Am. Chem. Soc. 2003, 125, 2923.