Synthesis and isomerisation of two metallated N,O-complexes of ruthenium: Models for the Murai reaction

Inorganica Chimica Acta

Volumn 359, Issue 3, 2006, Pages 815-820

  Jazzar, Rodolphe F R ^a   Varrone, Maurizio ^a   Burrows, Andrew D ^a   MacGregor, Stuart A ^b   Mahon, Mary F ^a   Whittlesey, Michael K ^a  

^a University of Bath Claverton Down   (United Kingdom)

^b HERIOT WATT UNIVERSITY   (United Kingdom)

Author keywords

Cyclometallation; Density functional theory; Hydride ligands; Murai reaction; Phosphine ligands; Ruthenium complexes

Indexed keywords

CATALYST ACTIVITY; DENSITY FUNCTIONAL THEORY; ISOMERS; LIGANDS; PHOSPHORUS COMPOUNDS; REACTION INTERMEDIATES; SYNTHESIS (CHEMICAL);

CYCLOMETALLATION; HYDRIDE LIGANDS; MURAI REACTION; PHOSPHINE LIGANDS; RUTHENIUM COMPLEXES;

RUTHENIUM COMPOUNDS;

EID: 30944467923     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2005.05.021     Document Type: Article

References (38)

1. F. Kakiuchi, and S. Murai S. Murai Topics in organometallic chemistry vol. 3 1999 Springer-Verlag Berlin 47 79
2. B.M. Trost, F.D. Toste, and A.B. Pinkerton Chem. Rev. 101 2001 2067
3. V. Ritleng, C. Sirlin, and M. Pfeffer Chem. Rev. 102 2002 1731
4. F. Kakiuchi, and S. Murai Acc. Chem. Res. 35 2002 826
5. C.-H. Jun, C.W. Moon, and D.-Y. Lee Chem. Eur. J. 8 2002 2423
6. F. Kakiuchi, and N. Chatani Adv. Synth. Cat. 345 2003 1077
7. S. Murai, F. Kakuishi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani Nature 366 1993 529
8. S. Murai, F. Kakuichi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, and N. Chatani Pure Appl. Chem. 66 1994 1527
9. F. Kakiuchi, S. Sekine, Y. Tanaka, A. Kamatani, M. Sonoda, N. Chatani, and S. Murai Bull. Chem. Soc. Jpn. 68 1995 62
10. S. Murai, F. Kakuichi, and N. Chatani Pure Appl. Chem. 69 1997 589
11. N. Fuji, F. Kakiuchi, A. Yamada, N. Chatani, and S. Murai Bull. Chem. Soc. Jpn. 71 1998 285
12. F. Kakiuchi, T. Sato, M. Yamaushi, N. Chatani, and S. Murai Chem. Lett. 1999 19
13. N. Chatani, T. Asaumi, S. Yorimitsu, T. Ikeda, F. Kakiuchi, and S. Murai J. Am. Chem. Soc. 123 2001 10935
14. F. Kakiuchi, T. Sato, N. Igi, N. Chatani, and S. Murai Chem. Lett. 2001 386
15. F. Kakiuchi, S. Kan, K. Igi, N. Chatani, and S. Murai J. Am. Chem. Soc. 125 2003 1698
16. T. Matsubara, N. Koga, D.G. Musaev, and K. Morokuma J. Am. Chem. Soc. 120 1998 12692
17. T. Matsubara, N. Koga, D.G. Musaev, and K. Morokuma Organometallics 19 2000 2318
18. Chelation assistance may not always be needed. X. Zhang, M. Kanzelberger, T.J. Emge, and A.S. Goldman J. Am. Chem. Soc. 126 2004 13192
19. B.M. Trost, K. Imi, and I.W. Davies J. Am. Chem. Soc. 117 1995 5371
20. Y. Guari, S. Sabo-Etienne, and B. Chaudret J. Am. Chem. Soc. 120 1998 4228
21. S. Busch, and W. Leitner Chem. Commun. 1999 2305
22. S.D. Drouin, D. Amoroso, G.P.A. Yap, and D.E. Fogg Organometallics 21 2002 1042
23. Y. Guari, A. Castellanos, S. Sabo-Etienne, and B. Chaudret J. Mol. Cat. A 212 2004 77
24. K. Hiraki, T. Ishimoto, and H. Kawano Bull. Chem. Soc. Jpn. 73 2000 2099
25. R.F.R. Jazzar, M.F. Mahon, and M.K. Whittlesey Organometallics 20 2001 3745
26. 3).
27. A.D. Burrows, M.F. Mahon, M.T. Palmer, and M. Varrone Inorg. Chem. 41 2002 1695
28. 3)H] is the same as that in 2.
29. The isomerisation of related cyclometallated N-benzylideneaniline and 2-phenylpyridine complexes of ruthenium has been described. K. Hiraki, M. Koizumi, S. Kira, and H. Kawano Chem. Lett. 1998 47
30. M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, V.G. Zakrzewski, J.A. Montgomery Jr., R.E. Stratmann, J.C. Burant, S. Dapprich, J.M. Millam, A.D. Daniels, K.N. Kudin, M.C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B. Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G.A. Petersson, P.Y. Ayala, Q. Cui, K. Morokuma, N. Rega, P. Salvador, J.J. Dannenberg, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J. Cioslowski, J.V. Ortiz, A.G. Baboul, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, J.L. Andres, C. Gonzalez, M. Head-Gordon, E.S. Replogle, and J.A. Pople Gaussian 98, revision A.11.4 2002 Gaussian, Inc. Pittsburgh, PA
31. L.S. Van der Sluys, G.J. Kubas, and K.G. Caulton Organometallics 10 1991 1033
32. C.D. Andrews, A.D. Burrows, J.M. Lynam, M.F. Mahon, and M.T. Palmer New J. Chem. 25 2001 824
33. G.M. Sheldrick Acta. Cryst. 467-473 1990 A46
34. G. Sheldrick shelxl-97, a computer program for crystal structre refinement 1997 University of Göttingen Göttingen
35. D. Andrae, U. Häusserman, M. Dolg, H. Stoll, and H. Preuss̃ Theor. Chim. Acta 77 1990 123
36. A. Höllwarth, M. Böhme, S. Dapprich, A.W. Ehlers, A. Gobbi, V. Jonas, K.F. Köhler, R. Stegmann, A. Veldkamp, and G. Frenking Chem. Phys. Lett. 208 1993 237
37. W.J. Hehre, R. Ditchfield, and J.A. Pople J. Chem. Phys. 56 1972 2257
38. P.C. Hariharan, and J.A. Pople Theor. Chim. Acta 28 1973 213