1-(Trifluoromethyl)vinylation via oxirane or oxetane ring-opening: A facile synthesis of 4- or 5-hydroxy-functionalized 2-trifluoromethyl-1-alkenes

Synthesis

Volumn , Issue 1, 2006, Pages 128-132

  Nadano, Ryo ^a   Ichikawa, Junji ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

(Trifluoromethyl)vinyl group; Lithium halogen exchange; Oxirane; Ring opening; Unsaturated alcohol

Indexed keywords

ALCOHOLS; ETHERS; LITHIUM COMPOUNDS; OLEFINS; VINYL RESINS;

(TRIFLUOROMETHYL)VINYL GROUP; LITHIUM-HALOGEN EXCHANGE; OXIRANE; RING-OPENING; UNSATURATED ALCOHOL;

AROMATIC COMPOUNDS;

1 (TRIFLUOROMETHYL)VINYL DERIVATIVE; 1 (TRIFLUOROMETHYL)VINYLLITHIUM; ALKENE DERIVATIVE; ALLYL ALCOHOL; BROMO 3,3,3 TRIFLUOROPROPENE; BUTYLLITHIUM; ETHER DERIVATIVE; ETHYLENE OXIDE DERIVATIVE; FLUORINE DERIVATIVE; FUNCTIONAL GROUP; HYDROXYL GROUP; LITHIUM DERIVATIVE; OXETANE DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; ENANTIOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RACEMIZATION; RING OPENING; STOICHIOMETRY; SYNTHESIS;

EID: 30944457082     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-918413     Document Type: Article

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