Mixed-valent and radical states of complexes [(bpy)2M(μ-abpy) M′(bpy)2]n+, M,M′ = Ru or Os, abpy = 2,2′-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes

Inorganica Chimica Acta

Volumn 359, Issue 3, 2006, Pages 821-829

  Heilmann, Martina ^a   Frantz, Stéphanie ^a   Kaim, Wolfgang ^a   Fiedler, Jan ^b   Duboc, Carole ^c  

^a UNIVERSITY OF STUTTGART   (Germany)

^b J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^c GRENOBLE HIGH MAGNETIC FIELD LABORATORY   (France)

Author keywords

Mixed valency; Osmium compounds; Radical ligands; Ruthenium compounds; Spectroelectrochemistry

Indexed keywords

CHARGE TRANSFER; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; LIGANDS; OSMIUM COMPOUNDS; SPECTROELECTROCHEMISTRY; SPIN ORBIT COUPLING;

CYCLIC VOLTAMMETRIC; EXCHANGE MECHANISM; MIXED VALENCY; MONONUCLEAR PRECURSORS; ONE-ELECTRON REDUCTIONS; OXIDATION POTENTIALS; RADICAL LIGAND; SPIN-ORBIT COUPLING CONSTANTS;

RUTHENIUM COMPOUNDS;

EID: 30944455673     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2005.04.044     Document Type: Article

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