A cleaner two-step synthesis of high purity diallyldimethylammonium chloride monomers for flocculant preparation

Journal of Environmental Sciences

Volumn 17, Issue 5, 2005, Pages 798-801

  Tian, Bing Hui ^a   Fan, Bin ^a   Peng, Xian Jia ^a   Luan, Zhao Kun ^a  

^a RESEARCH CENTER FOR ECO ENVIRONMENTAL SCIENCES   (China)

Author keywords

Cleaner process; Diallyldimethylammonium chloride; Flocculant; Microwave irradiation

Indexed keywords

FOURIER TRANSFORM INFRARED SPECTROSCOPY; IRRADIATION; LOW TEMPERATURE OPERATIONS; MONOMERS; SOLIDIFICATION; SYNTHESIS (CHEMICAL);

ATOMIC ADSORPTION SPECTROMETRY; CLEANER PROCESS; MICROWAVE IRRADIATION; POLYDIALLYLDIMETHYLAMMONIUM CHLORIDE (PDADMAC);

FLOCCULATION;

ALLYL COMPOUND; DIALLYLDIMETHYLAMMONIUM CHLORIDE; QUATERNARY AMMONIUM DERIVATIVE;

FLOCCULATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; IRRADIATION; LOW TEMPERATURE OPERATIONS; MONOMERS; SOLIDIFICATION; SYNTHESIS (CHEMICAL);

FLOCCULATION;

ARTICLE; CHEMISTRY; COMPARATIVE STUDY; FLOCCULATION; METHODOLOGY; MICROWAVE RADIATION; SEWAGE; SYNTHESIS; TEMPERATURE; WATER MANAGEMENT;

ALLYL COMPOUNDS; FLOCCULATION; MICROWAVES; QUATERNARY AMMONIUM COMPOUNDS; TEMPERATURE; WASTE DISPOSAL, FLUID; WATER PURIFICATION;

EID: 30744446249     PISSN: 10010742     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (15)

1. Boothe J E, 1969. Synthesis of dimethyl diallyl ammonium chloride[P]. USA 3, 461, 163.
2. Brain A B, 1995. Soluble polymers in water purification[J]. Prog Polym Sci, 20: 987-1041.
3. Butler G B, Bunch R L, 1949. Preparation and polymerization of unsaturated quaternary ammonium compounds[J]. J Am Chem Soc, 71: 3120-3122.
4. Butler G B, Angelo R J, 1958. Preparation and polymerization of unsaturated quaternary ammonium compounds. VIII. A proposed alternating intramolecular-intermolecular chain propagation[J]. J Am Chem Soc, 73: 3128-3131.
5. Caddick S, 1994. Microwave assisted organic reactions[J]. Tetrahedron, 51: 10404-10432.
6. Chang Q, Chen Y, Tian B H, 2000. Study on synthesis and flocculation efficiency of polydimethyldiallylammonium chloride[J]. J Environ Sci, 20: 168-172.
7. Cherng Y J, 2002. Synthesis of substituted pyridines by the reactions halopyridines with sulfer, oxygen and carbon nucleophiles under focused microwave irradiation[J]. Tetrahedron, 58: 4931-4935.
8. Huang J T, Sun J W, Cao A L, 1996. Synthesis and polymerization of diallylaromatic amines as supernucleophilic reagents[J]. Polymer, 37: 837-841.
9. Hunter W E, 1979. Preparation of diallyl dimethyl ammonium chloride and polydiallyl dimethyl ammonium chloride[P]. USA 4, 151, 202.
10. Matsumoto A, 2001. Polymerization of multiallyl monomers[J]. Prog Polym Sci, 26: 189-257.
11. Negi Y J, Harada S, Ishizuka O, 1967. Preparation and cyclopolymerization of diallylamine derivatives[J]. J Polym Sci: Part A-1, 5: 1951-1965.
12. Ren J, Ha H F, 2001. Study on interpenetrating polymer network hydrogel of diallydimethylammonium chloride with kappa-carrageenan by UV irradiation [J]. European Polymer Journal, 37: 2413-2417.
13. Varma R S, 2001. Solvent-free accelerated organic syntheses using microwaves [J]. Pure Appl Chem, 73: 193-198.
14. Wandrey C, Hernández-barajas J, Hunkeler D, 1999. Diallyldimethylammonium chloride and its polymer[J]. Advs Polym Sci, 145: 82-123.
15. Zhao H Z, Luan Z K, Gao B Y, 2002. Synthesis and flocculation properties of poly(diallyldimethyl ammonium chloride-vinyl trimethoxysilane)[J]. J App Polym Sci, 84: 335-342.