Regeneration in the melt of recycle and regrind thermoplastics using neoalkoxy titanates and zirconates

Global Plastics Environmental Conference 2005: GPEC 2005 - Creating Sustainability for the Environment

Volumn , Issue , 2005, Pages 41-73

  Monte, Salvatore J ^a  

^a Kenrich Petrochemicals Inc   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PROTON COORDINATION; REACTIVE SUBSTRATES; REGRIND THERMOPLASTICS;

CATALYSIS; CONDENSATION; COPOLYMERIZATION; PROTONS; TITANIUM COMPOUNDS; ZIRCON;

THERMOPLASTICS;

EID: 30644465845     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (71)

1. Monte, S.J., Kenrich Petrochemicals, Inc., "KenReact® Reference Manual - Titanate, Zirconate and Aluminate Coupling Agents", Third Revised Edition, March 1995, 340 pgs.
2. Monte, S.J. and Sugerman, G., Kenrich Petrochemicals, Inc.: S.M. Gabayson and W.E. Chitwood, General Dynamics, "Enhanced Bonding of Fiber Reinforcements to Thermoset Resins", 33rd International SAMPE Symposium, Anaheim, CA, March 7-10, 1988.
3. rd Int'1 SAMPE Symp., Anaheim, CA, March 7-10, 1988 (SAMPE II).
4. Monte, S.J. and G. Sugerman, G., "High Temperature Inorganic Anti-corrosive Coatings Using Organometallic Titanate & Zirconate Quat Blends (QB)," Corrosion '90, Las Vegas, NV, April 23-27, 1990, #432.
5. Monte, S.J. and Sugerman, G., "Corrosion Resistant One Hundred Percent Solids, Environmentally Sound Coatings", Water-Borne & Higher Solids Coatings Symposium, New Orleans, LA Feb. 3-5, 1988.
6. Monte, S.J. and Sugerman, G., "Alkoxy Titanates and Zirconates as Corrosion Inhibitors in Clear Coats and Unfilled Polymers", Corrosion/88, NACE, St. Louis, MO, March 21-25, 1988.
7. Monte, S. J. and Sugerman, G., "Very High Solids and Waterborne Anticorrosive Coatings", Western Coatings Societies' 19th Biennial Symposium and Show, Anaheim, CA. March 14-16, 1989.
8. Monte, S.J. and Sugerman, G., "The Usage of Organometallic Reagents as Catalysts and Adhesion Promoters in Reinforced Composites", Second International Conference on Composite Interfaces (ICCIII), Case Western Reserve University, Cleveland, Ohio, June 13-17, 1988.
9. th Annual Technical Conference, November 1981.
10. th Annual Technical / Marketing Conference, October 1985.
11. Monte, S.J. "Injection Molding with Neoalkoxy Titanates and Zirconate', SPE RETEC, White Haven, PA, USA October 19, 1995.
12. Monte, S.J., "Titanium and Zirconium Esters vs. Couplers and Single Site Catalysts for In-Situ Repolymerization and Copolymerization Useful for Recycled Polymeric Compositions," ACS Rubber Div., Louisville, KY, Oct. 8-11, 1996, Paper No. 57.
13. Monte, S.J., "Better Bonding and Metallocene-like Catalysis Benefits for Elastomers", Rubber Technology International '96, UK & Int' l Press, a Div. of Auto Intermediates Ltd (1996).
14. Monte, S.J. "Compounding and Molding with Neoalkoxy Titanates and Zirconates", Polyblends '97 SPE Div./Sect. Conference, NRCC, Montreal, Canada, Oct. 9, 1997.
15. Monte, S.J., "Increased Productivity of Thermoplastics Using Organometallic Titanate and Zirconate Coupling Agents", SPE ANTEC, May 1-3, 1989.
16. Monte, S.J., "Coupling Agents Increase PVC Productivity", Plastics Compounding Magazine, November/December 1989.
17. Glaysher, W.A., Haff, D.R., Schlaubitz, H.H., and Monte, S. J., "The Use of Organometallic Coupling Agents as Process Aids in Blow Molded HDPE'" SPE RETEC, High Performance Blow Molding Conference, Oct. 9-10. 1990.
18. Monte, S.J., "New Opportunities in Recycled Plastics With Neoalkoxy, Titanate and Zirconate Coupling Agents'" SPE Recycle RETEC, October 31, 1989.
19. Monte, S.J., "More Efficient Manufacture of Better Foamed, Filled and Unfilled Polymer Compounds With Titanate and Zirconate Coupling Agents", Northeast Regional Rubber & Plastics Exposition, September 21-22, 1994, Mahwah, NJ.
20. Monte, S.J., Sugerman, G. "The Use of Organometallic Titanates & Zirconates as Reactants and Compatabilizers in Polymers", Compalloy '90, Mar. 9, 1990, New Orleans, LA.
21. Plueddemann, Edwin P., "Silane Coupling Agents", Pg. 114, 1982 Plenum Press.
22. Voelkel, A. and Grzeskowiak, T., Poznan University of Technology, Institute of Chemical Technology and Engineering, "The Use of Solubility Parameters in Characterization of Titanate Modified Silica Gel by Inverse Gas Chromatography", Chromatographia Vol. 51, No. 9/10, May 2000.
23. Wang, Yeh and Huang, Jiang-Shen, Dept. of Chem. Eng' g, Tunghai University, "Single Screw Extrusion Compounding of Particulate Filled Thermoplastics: State of Dispersion and Its Influence on Impact Properties", Journal of Applied Polymer Science, Vol. 60, 1779-1791 (1996).
24. Krysztafkiewicz, A.; Rager, B.; Jesionowski, T., Institute of Technology and Chemical Engineering, Poznan University of Technology, "The Effect of Surface Modification on Physiochemical Properties of Precipitated Silica", Journal of Materials Science 32 (1997) 1333-1339.
25. 3 Filled PP/HDPE Composites Using Different Surface Modifiers".
26. 3 composites", Polymer (2002), 43(8), 2501-2506 CODEN: POLMAG; ISSN: 0032-3861.
27. Gonzalez, J.; Albano, C.; Ichazo, M.; Hernandez, M.; Sciamanna, R., Departamento de Mecanica, Universidad Simon Bolivar, Caracas, 1080A, Venez., "Analysis of thermogravimetric data of blends of polyolefins with calcium carbonate treated with Lica 12", Polym. Degrad. Stab. (2001), 73(2), 211-224 CODEN: PDSTDW; ISSN: 0141-3910, Elsevier Science Ltd.
28. 3 Particles".
29. Sharma, Y.N.; Patel, R.D.; Dhimmar, I.H.; and Bhardwaj, I.S.; Research Center, Indian Petrochemicals Corporation, Ltd., Baroda-391 346, India, Journal of Applied Polymer Science, Vol. 27, 97-104 (1982), John Wiley & Sons, Inc., "Studies of the Effect of Titanate Coupling Agent on the Performance of Polypropylene-Calcium Carbonate Composite".
30. Szijártó, K.; Kiss, P, Polymer Composites, 1986 Walter de Gruyter & Co., Berlin-New York, "Filling of Polymers with the Aid of Coupling Agents".
31. Qu, Xiong-wei; Ji, Rong-qin; Pan, Ming-wang; Zhang, Liu-cheng, Sch. Chem. Eng. Technol., Hebei Univ. Technol., Tianjin, 300130, Peop. Rep. China, "Study on application of titanate coupling agents in CaCO3-filled PVC composites", Hebei Gongye Daxue Xuebao (2001), 30(1), 84-88, CODEN: HGXUFT; ISSN: 1007-2373, Hebei Gongye Daxue Bianweihui
32. Yu, G., Zhang, M.Q., Zeng, H.M., "Carbon-Black-Filled Polyolefine as a Positive Temperature Coefficient Material: Effect of Composition, Processing, and Filler Treatment", Journal of Applied Polymer Science, Vol. 70, 559-566 (1998).
33. 2 reinforced epoxy system", Mater. Lett.(1996), 26(6), 299-303 Coden:MLETDJ;ISSN:0167-577X.
34. Ren, Z.; Shanks, R. A.; Rook, T. J., Department of Applied Chemistry, RMIT, University, Melbourne, 3001, Australia, Polymers & Polymer Composites (2002), 10(2), 173-181, CODEN: PPOCEC; ISSN: 0967-3911, Rapra Technology Ltd., "Processing and properties of polypropylene composites with high filler content".
35. th (Vol. 3), 2550-2554 CODEN: ACPED4; ISSN: 0272-5223, "Interfacial interactions and structure development in injection molded HDPE/hydroxyapatite composites".
36. Vaz, C. M.; Reis, R. L.; Cunha, A. M., CS Department of Polymer Engineering, University of Minho, Guimaraes, 4800-058, Portugal, Biomaterials (2001), Volume Date 2002, 23(2), 629-635, CODEN: BIMADU; ISSN: 0142-9612, Elsevier Science Ltd., "Use of coupling agents to enhance the interfacial interactions in starch-EVOH/hydroxylapatite composites"
37. Horibe, Hideo; Nishiyama, Itsuo; Hiroi, Osamu; Mori, Teijiro; Hayashi, Tatsuya; Takahashi, Chie; Murata, Shiro; Nishina, Kenichi; Sogabe, Manabu; Ishikawa, Masahiro, US 2002137831 dated 2002-09-26, "Polymeric PTC composition and circuit protection device made therefrom".
38. Kataoka, Mitsumune, NEC Tokin Corp., Japan, JP 2002226601 dated 2002-08-14 "Preparation of electrically conductive composition for fabrication of positive-temperature-coefficient (PTC) devices."
39. Yang, Huaming, Department of Mineral Engineering, Zhongnan University, Changsha, 410083, Peop. Rep. China, Feijinshukuang (2001), 24(2), 24, 36, CODEN: FEIJDJ; ISSN: 0253-2298, Feijinshukuang Bianjibu Journal, "Preparation of activated saponite powder and its use in PP plastic".
40. Monte, S. J.; Sugerman, G; Kenrich Petrochemicals, Inc., U.S. 6, 197, 135 dated March 6, 2001, "Enhanced Energetic Composites".
41. Monte, S.J.; Sugerman, Kenrich Petrochemicals, Inc.; G; Dixon, Scott J. USAF Contractor, U.S. 5,753,853 dated May 19, 1998, "Solid Propellant with Titanate Bonding Agent".
42. Mitsubishi Cable Ind., US 4,769,179 - 9/6/88.
43. Eichler, Hans-Jürgen; Palmer Michael; Herbiet, René, ALUSUISSE MARTINS WERK GMBH, WO 00015710 dated 14. September 1999, "Surface-Modified Filling Material Composition".
44. Jiang, Pingkai; Wang, Genlin; Zhu, Zikang; Wu, Haifeng; School of Chemistry and Chemical Engineering, Shanghai Jiaotong Univ., 200240, Peop. Rep. China; Hecheng Shuzhi Ji Suliao (2001), 18(5), 35-38; CODEN: HSSUEJ; ISSN: 1002-1396; Hecheng Shuzhi Ji Suliao Bianjibu; "Interfacial and mechanical properties of aluminum hydroxide highly filled polyethylene composite".
45. Wang, Genlin; Jiang, Pingkai; Zhu, Zikang; Yin, Jie, School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai, 200240, Peop. Rep. China, Journal of Applied Polymer Science (2002), 85(12), 2485-2490, CODEN: JAPNAB; ISSN: 00218995, John Wiley & Sons, Inc., "Structure-property relationships of LLDPE-highly filled with aluminum hydroxide".
46. Wang, Gen-Lin; Jiang, Ping-Kai; Zhu, Zi-Kang; Yin, Jie, School of Chemistry and Chemical Engineering, Shanghai Jiaotong, University, Shanghai, 200240, Peop. Rep. China, Chinese Journal of Polymer Science (2002), 20(3), 253-259, CODEN: CJPSEG; ISSN: 0256-7679, Springer-Verlag, "Morphology and properties of linear low-density polyethylene highly loaded with aluminum hydroxide".
47. Braga, Vittorio; Goberti, Paolo; Zucchelli, Ugo; Marchini, Roberta, Basell Technology Company Bv, Neth., WO 2001048075, EP 1155080 dated 2001-11-21, "Flame-proof polyolefim compositions".
48. Imahashi, Takeshi; Kazuki, Keiko, Kyowa Kagaku Kogyo K. K., Japan, JP 2001312925 dated 200111-09, "Heat deterioration-, water-, and fire-resistant electrically insulated electric wires and cables, and moldings".
49. Chiang, Wen-Yen; Hu, Chia-Hao, Department of Chemical Engineering, Tatung University, Taipei, 104, Taiwan, Composites, Part A (2001), 32A(3-4), 517-524,CODEN: CASMFJ; ISSN: 1359-835X, Elsevier Science Ltd., "Approaches of interfacial modification for flame retardant polymeric materials".
50. Kato, Masaharu; Omoto, Masanobu; Ishimatsu, Hirofumi; Madalle, James; Kratzer, Jeff A.; EP 0 708 143 A1 dated 24.04.1996, "Polyviny1 Chloride Based Resin Composition and Products Derived Therefrom".
51. Field, R. and Cowe, P.L., "The Organic Chemistry of Titanium", Butterworth & Co., Washington, D.C., 1965 (213 pp. 791 references).
52. Korea Institute of Science and Technology, U.S. 5,237,042, Aug. 17, 1993.
53. Kim, C.Y., Cho, H.N., Yoo, H.W., Kim, H.J., Korea Institute of Science and Technology, "Method for the Preparation of Polyester by Use of Composite Catalyst", U.S. 5,714,570 dated Feb. 3, 1998.
54. Cho, Hyun Nam; Hong, Jae Min; Ko, Young Chan; Choi, Il Seok; Heo, Young Jin, S. Korea, US 6040417 dated 2000-03-21, "Process for preparing polyethylene naphthalate-based polymers by using composite catalysts comprising titanium compounds and aromatic phosphites"
55. Lee, Sang-Soo; Kim, Junkyung; Park, Min; Lim, Soonho; Choe, Chul Rim, CS Polymer Hybrids Research Center, Korea Institute of Science and Technology, Seoul, 136-791, S. Korea, Journal of Polymer Science, Part B: Polymer Physics (2001), 39(21), 2589-2597, CODEN: JPBPEM; ISSN: 0887-6266, John Wiley & Sons, Inc., "Transesterification reaction of the BaSO4-filled PBT/poly(ethylene terephthalate) blend".
56. Kitani, Ichiro; Okamoto, Takahiro; Uemura, Shingo, Lion Corp., Japan, JP 2001232210 dated 2001-08-28, "Production method alkoxy catalysts".
57. Donald W. Kelley, U.S. Patent 4,837,272, June 6, 1989.
58. Monte, S.J., Sugarman, G., Kenrich Petrochemicals, Inc., "Repolymerization", U.S. Patent 4,657,988 dated April 14, 1987.
59. Waha, Chuah Ai; Choongb, Leong Yub; Neonb, Gan Seng,a Petronas Research and Scientific Services, b Dept. Chem. Eng'g., U. of Malaysia, European Polymer Journal 36 (2000) 789-801.
60. Galanti, Andrea; Laus, Michele; Fiorini, Maurizio, CS Mixer S.r.l., Ravenna, Italy, "Reinforcement of SBS by organophilic clay fillers", Kautsch. Gummi Kunstst. (1999), 52(1), 21-25, CODEN: KGUKAC; ISSN: 0022-9520, PB Huethig GmbH, ce 39-9 (Synthetic Elastomers and Natural Rubber).
61. Simonutti, F.M., Wilson Sporting Goods Co., Japan, "Golf ball cores containing titanate coupling agents", JP 10108925 dated 28 April 1998.
62. Kim, Hyun; Snell, Dean A., Taylor Made Golf Company, Inc.. WO 00/40306 dated 13 July 2000, "Improvement of Golf Ball Cover Using Organometallic Compounds".
63. Industrial Technology Res. Inst., Hsinchu, Taiwan, US 5,340,861, Aug. 23, 1994.
64. Monte, S.J., Kenrich Petrochemicals, Inc., "Titanate and Zirconate Coupling Agents in Foamed Polymers", RAPRA Foams Conference, March 13, 2001, Frankfurt, Germany.
65. Hilborn, Bradley L.; Harrison, Bruce L., Henkel Corporation, USA, WO 2000012571 dated 2000-03-09, "Corrosion inhibitors and corrosion-resistant structural foam".
66. Peng, Jiahui; Chen, Mingfeng; Peng, Zhihui; Lin, Changqing; Zhang, Jianxin, Chongqing University, Peop. Rep. China, Faming Zhuanli Shenqing Gongkai Shuomingshu, 11 pp., CN 1305972 dated 2001-08-01, "Preparation of thermal insulating mortar for building external wall".
67. Schut, J. "Organometallic Esters Enhance Recycled PET/PC Blends," Plastics Formulating and Compounding, Sept./Oct., 1996.
68. Neste Oy, WO 95/23183, Feb. 28, 1995.
69. Miller, N. A.; Jones, M.S.; and Stirling, C.D., Industrial Research Limited, "Waste Plastics/Cellulose Fibre Composites", Polymers & Polymer Composites, Vol.6, No. 2, 1998.
70. Monte, S.J., U.S. Patent 5,659,058 - August 19, 1997, "Thermally Stable Antistatic Agents" - Monte, S.J.
71. Monte, S.J., "Permanent, Transparent, NonBlooming and Non-Hygroscopic Antistatic Agents Based On Combined Neoalkoxy Organometallics", Addcon World 2001 Conference, 9 Oct. 2001, Berlin, Germany.