Chemistry of silanes: Interfaces in dental polymers and composites

Journal of Research of the National Institute of Standards and Technology

Volumn 110, Issue 5, 2005, Pages 541-558

  Antonucci, Joseph M ^a,c   Dickens, Sabine H ^b,c,d   Fowler, Bruce O ^a,c   Xu, Hockin H K ^b,c,d   McDonough, Walter G ^a,e  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b American Dental Association Foundation   (United States)

^c NIST Materials Science and Engineering Laboratory   (United States)

^d AMERICAN DENTAL ASSOCIATION   (United States)

^e THE MEASUREMENT GROUP   (United States)

Author keywords

Adhesion; Interfacial adhesion; Interphases; Silanes; Silanization; Silsesquioxanes

Indexed keywords

ADHESION; CERAMIC MATERIALS; DENTAL COMPOSITES; FILLERS; ORGANIC POLYMERS; POLYMERIZATION; RESINS;

INTERFACIAL ADHESION; INTERPHASES; SILANIZATION; SILSESQUIOXANES;

SILANES;

EID: 30444455480     PISSN: 1044677X     EISSN: 1044677X     Source Type: Journal    
DOI: 10.6028/jres.110.081     Document Type: Article

References (47)

1. L. H. Sharpe, The Interphase in Adhesion. J. Adhes. 4, 51-64 (1972).
2. L. H. Sharpe, Recent Advances in Adhesion, L.H. Lee, Ed., Gordon and Breach, NY (1992).
3. J. D. Miller, H. Ishida, Adhesive-adherend interface and interphase, in Fundamentals of Adhesion, L. H. Lee, ed., Plenum Press, NY (1991) pp. 291-324.
4. H. Ishida, Structural gradient in the silane coupling agent layers and its influence on mechanical and physical properties of composites, in Molecular Characterization of Composite Interfaces, H. Ishida, ed., Plenum Press, NY (1983).
5. J. L. Kardos, The role of the interface in polymer composites - some myths, mechanisms, and modifications, in Molecular Characterization of Composites Interfaces, H. Ishida, ed., Plenum Press, NY (1983).
6. M. W. Raney, S. E. Berger, J. G. Marsden, Silane coupling agents in paniculate mineral filled composites, in Interfaces in polymer matrix composites, Composite Materials 6, E. P. Plueddemann, ed., Academic Press, NY (1974).
7. R. H. Halvorson, R. L. Erickson, C. L. Davidson, The effect of filler and silane content on conversion of resin-based composite, Dent. Mater. 19, 327-333. (2003).
8. E. P. Plueddemann, Adhesion through silane coupling agents, in Fundamentals of Adhesion, L. H. Lee, ed., Plenum Press, NY (1991) pp. 279-290.
9. E. R. Pohl and F. D. Osterholtz, Kinetics and mechanism of aqueous hydrolysis and condensation of alkyltrialkoxysilanes, in Molecular characterization of composite interfaces, H. Ishida, ed., Plenum Press, NY (1983).
10. R. L. Bowen, Use of epoxy resins in restorative materials, J. Dent. Res. 35, 360-369 (1956).
11. R. L. Bowen, Dental filling materials comprising vinyl silane treated fused silica and a binder consisting of the reaction products of bisphenol and glycidyl methacrylate, U.S. Patent 3,066,012 (1962).
12. R. L. Bowen, Properties of a silica-reinforced polymer for dental restorations, J. Am. Dent. Assoc. 66, 57-64 (1963).
13. T. M. Chen and G. M. Brauer, Solvent effects on bonding organosilane to silica surfaces, J. Dent. Res. 61 (12), 1439-1443 (1982).
14. K. J. M. Söderholm, Degradation of glass filler in experimental composites, J. Dent. Res. 60, 1867-1875 (1981).
15. K. J. M. Söderholm, M. Zigan, M. Ragan, W. Fischlschweiger, M. Bergman, Hydrolytic degradation of dental composites, J. Dent. Res. 63, 1248-1254 (1984).
16. K. J. M. Söderholm, Filler systems and resin interface, in Posterior Composite Resins Dental Restorative Materials, G. Vannerle and D. C. Smith, eds., Peter Szulc Publishing Co, Ultrecht, 139-159 (1985).
17. S. Venz and J. M. Antonucci, Silanization and modification of fillers for dental composites, J. Dent. Res. 65, 191, Abst. No. 191 (1986).
18. K. J. M. Söderholm and S-W. Shang, Molecular Orientation of Silane at the Surface of Colloidal Silica, J. Dent. Res. 72, 1050-1054 (1993).
19. N. Nishiyama, T. Ishizaki, K. Horie, M. Tomari, and M. Someya, Novel polyfunctional silanes for improved hydrolytic stability at the polymer-silica interface, J. Biomed. Mater. Res. 25, 213-221 (1991).
20. N. M. Mohsen and R. G. Craig, Effect of silanation of fillers on their dispersability by monomer systems, J. Oral Rehab. 22, 183-189 (1995).
21. N. M. Mohsen and R. G. Craig, Hydrolytic stability of silanated zirconia-silica-urethane dimethacrylate composites, J. Oral Rehab. 22, 213-220 (1995).
22. J. M. Antonucci, W. J. McDonough, C. L. Schutte, and C. K. Moon, Shear strength measurements of dental polymer/glass fiber interfaces via the microbond test, Polymer Preprints 36(1), 821-822 (1995).
23. W. G. McDonough, J. M. Antonucci, and J. P. Dunkers, A study of dental adhesion by means of the microbond test, Polymer Preprints 38 (2):112-113 (1997).
24. W. G. McDonough, J. M. Antonucci, and J. P. Dunkers, Interfacial shear strengths of dental resin-glass fibers by the microbond test, Dent. Mater. 17, 492-498 (2001).
25. H. Kikuchi, M. Nishiyama, and J. M. Antonucci, Assessing strength and durability of composites using the uniaxial tensile test, J. Dent. Res.71, 72, Abst. No. 1636 (1992).
26. H. Takahashi, J. M. Antonucci, J. W. Stansbury, and F. Wang, Relationship between the Tensile and Flexural Strength of Composite Resins, Polymer Preprints 38(2), 163-164 (1997).
27. H. Takahashi, J. M. Antonucci, and J. W. Stansbury, Effect of silane coupling agent and filler on composite durability, J. Dent. Res. 78, 549, Abst. No. 3547 (1999).
28. C. L. Schutte, Environmental durability of glass-filler composites, Mater. Sci. Eng. Rept., Vol. R13, No. 7, 265-323 (1994).
29. R. Guggenberger and W. Weinmann, Exploring beyond methacrylates, Am. J. Dent. 13, 82D-84D (2000).
30. B. A. Venhoven, A. J. de Gee, A. Werner, and C. L. Davidson, Silane treatment of filler and composite blending in a one-step procedure for dental restoratives, Biomaterials 15, 1152-1156 (1994).
31. J. M. Antonucci, J. W. Stansbury, and S. I. Kim, Effect of a long-chain silane coupling agent on composite strength, J. Dent. Res. 74, Abst. No. 461 (1995).
32. W. H. Douglas, R. G. Craig, and C. J. Chen, A new composite restorative based on a hydrophobic matrix, J. Dent. Res. 58, 1981-1986 (1979).
33. J. M. Antonucci, New monomers for use in dentistry, in Biomedical and Dental Applications of Polymers, C.G. Gebelein and F. F. Koblitz, eds., Plenum Press, New York (1981) pp. 357-371.
34. J. M. Antonucci, J. W. Stansbury, and S. Venz, Synthesis and properties of a polyfluorinated prepolymer multifunctional urethane methacrylate, in Progress in Biomedical and Dental Polymers, C. G. Gebelein and R. L. Dunn, eds., Plenum Press, New York (1990) pp. 121-131.
35. J. M. Antonucci and J. W. Stansbury, Synthesis of novel polyfluorinated acrylic monomers and oligomers, Polymer Preprints 34(1), 403-404 (1993).
36. J. M. Antonucci, J. W. Stansbury, and G. W. Cheng, Synthesis of novel hydrophilic and hydrophobic multifunctional acrylic monomers, in Polymers of Biological and Biomedical Significance 540, S. W. Shalaby, Y. Ikada, R. Langer, and J. Williams, eds., American Chemical Society, Washington, pp. 191-201.
37. T. Li and R. G. Craig, Synthesis of fluorinated Bis-GMA and its use with other fluorinated monomers to formulate hydrophobic composites, J. Oral Rehabil. 23, 158-162 (1996).
38. J. W. Stansbury and J. M. Antonucci, Dimethacrylate monomers with varied fluorine contents and distributors, Dent. Mater. 15, 166-173 (1999).
39. B. S. Lim, J. L. Ferracane, J. R. Condon, and J. D. Adey, Effect of filler fraction and filler surface treatment on wear of micro-filled composites, Dent. Mater. 18, 1-11 (2002).
40. H. H. Xu, T. A. Martin, J. M. Antonucci, and F. C. Eichmiller, Ceramic whisker reinforcement of dental resin composites, J. Dent. Res. 78, 706-712 (1999).
41. H. H. Xu, J. B. Quinn, D. T. Smith, J. M. Antonucci, G. E. Schumacher, and F. C. Eichmiller, Dental resin composites containing silica-fused whiskers - effects of whisker-to-silica ratio on fracture toughness and indentation properties, Biomaterials 23, 735-742 (2002).
42. J. M. Antonucc , B. O. Fowler, and J. W. Stansbury, Facile syntheses of acrylic organosilsesquioxanes. Polymer Preprints 38(2), 118-119 (1997).
43. J. M. Antonucci, B. O. Fowler, and J. W. Stansbury, Facile synthesis of oligomeric organofluorosilsesquioxanes, Polymer Preprints 39(2), 810-811 (1998).
44. W. E. Wallace, C. M. Guttman, and J. M. Antonucci, Molecular structure of silsesquioxanes determined by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, J. Am. Soc. Mass Spectrom. 10, 224-230 (1999).
45. S. H. Dickens, J. M. Antonucci, and B. O. Fowler, Novel dental resins from trialkoxysilanes and dental monomers by Insitu formation of oligomeric silsesquioxanes, Polymer Preprints 43(2), 747-748 (2002).
46. J. M. Antonucci, B. O. Fowler, S. H. Dickens, and N. D. Richards, Novel dental resins from trialkoxysilanes and dental monomers by in-situ formation of oligomeric silsesquioxanes, Polymer Preprints 43(2), 633-634 (2002).
47. J. M. Antonucci, B. O. Fowler, J. H. Stansbury, and H. Takahashi, Synthesis and evaluation of an acrylic organosilsesquioxane, Transactions of the Third International Congress on Dental Materials 314, Hawaii (1997).