Chemical analysis of monomers in epoxy resins based on bisphenols F and A

Contact Dermatitis

Volumn 50, Issue 5, 2004, Pages 289-297

  Ponten A ^a   Zimerson, E ^a   Sorensen O ^a   Bruze, M ^a  

^a LUND UNIVERSITY HOSPITAL   (Sweden)

Author keywords

Bisphenol F; Contact allergy; DGEBA R; DGEBF R; Epoxy resin; Epoxy resin of the bisphenol F type; High pressure liquid chromatography; HPLC; Isomer; Monomer; Thin layer chromatography; TLC

Indexed keywords

4,4' ISOPROPYLIDENEDIPHENOL; EPOXY RESIN; MONOMER;

ARTICLE; CHEMICAL ANALYSIS; EVALUATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PURIFICATION; THIN LAYER CHROMATOGRAPHY;

ALLERGENS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; DERMATITIS, ALLERGIC CONTACT; EPOXY COMPOUNDS; EPOXY RESINS; HUMANS; PATCH TESTS;

EID: 3042804070     PISSN: 01051873     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.0105-1873.2004.00319.x     Document Type: Article

References (27)

1. Jolanki R, Kanerva L, Estlander T. Epoxy resins. In: Handbook of Occupational Dermatology, Kanerva L, Elsner P, Wahlberg J E, Maibach H I, (eds). Berlin: Springer 2000: 570-590.
2. Thorgeirsson A, Fregert S, Ramnäs O. Sensitization capacity of epoxy resin oligomers in the guinea pig. Acta Derm Venereol 1978: 5: 17-21.
3. Fregert S, Thorgeirson A. Patch testing with low molecular oligomers of epoxy resins in humans. Contact Dermatitis 1977: 3: 301-303.
4. Pontén A, Bruze M. Contact allergy to epoxy resin based on diglycidyl ether of bisphenol F. Contact Dermatitis 2001: 44: 98.
5. Lee H N, Pokorny C D, Law S, Pratt M, Sasseville D, Storrs F J. Cross-reactivity among epoxy acrylates and bisphenol F epoxy resins in patients with bisphenol A epoxy resin sensitivity. Am J Contact Dermatitis 2002: 13: 108-115.
6. Bruze M, Edenholm M, Engström K, Svensson G. Occupational dermatoses in a Swedish aircraft plant. Contact Dermatitis 1996: 34: 336-340.
7. Ellis B. In: Chemistry and Technology of Epoxy Resins, Ellis B, (ed), 1st edn. Glasgow: Blackie Academic & Professional 1993.
8. Ayala F et al. The use of laboratory methods in contact dermatitis induced by composite materials. Contact Dermatitis 1990: 22: 262-266.
9. Jolanki R. Occupational skin diseases from epoxy compounds. Epoxy resin compounds, epoxy acrylates and 2,3-epoxypropyl trimethyl ammonium chloride. Acta Derm Venereol Suppl (Stockh) 1991: 159: 1-80.
10. Hansson C. Determination of monomers in epoxy resin hardened at elevated temperature. Contact Dermatitis 1994: 31: 333-334.
11. Le Coz C J et al. An epidemic of occupational contact dermatitis from an immersion oil for microscopy in laboratory personnel. Contact Dermatitis 1999: 40: 77-83.
12. Fregert S, Trulsson L. Simple methods for demonstration of epoxy resins of bisphenol A type. Contact Dermatitis 1978: 4: 69-72.
13. Jenkinson H A, Burrows D. Pitfalls in the demonstration of epoxy resins. Contact Dermatitis 1987: 16: 226-227.
14. Dorsey J G, Dorsey G F, Rutenberg A C, Green L A. Determination of epoxide equivalent weight of glycidyl ethers by proton magnetic resonance spectrometry. Anal Chem 1977: 49: 1144-1145.
15. Domke W D. 1H NMR spectroscopic determination of the isomeric ratios of bisphenol-F diglycidyl ethers. Organic Magnetic Resonance 1982: 18: 193-196.
16. Brown R M, Creaser C S. The electron impact and chemical ionization mass spectra of some glycidyl ethers. Organic Mass Spectrometry 1980: 15: 578-581.
17. Casarini D, Harris R K, Kenwright A M. Variable-temperature high-resolution carbon-13 studies of molecular motion in solid bisphenol-F diglycidyl ether. Magnetic Resonance in Chemistry 1992: 30: 434-439.
18. Cottier S, Riquet A M, Fingenbaum A, Pollet B, Lapierre C, Mortreuil P. Identification of potential migrants from a vinylic organosol varnish by gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry. J Chromatogr 1997: 771: 366-373.
19. Bruze M. Contact sensitizers in resins based on phenol and formaldehyde. Acta Derm Venereol Suppl (Stockh) 1985: 119: 1-83.
20. Zimerson E, Sörensen Ö, Bruze M. Contact allergy to trimers in p-tert-butylphenol-formaldehyde resin. Exog Dermatol 2002: 1: 207-216.
21. Henriks-Eckerman M-L, Laijoki T. Glycidyl ethers in epoxy resin products. Työterveyslaitoksen Tutkimuksia 1986: 4: 41-46. (In Finnish with English summary).
22. Pontén A, Zimerson E, Sörensen Ö, Bruze M. Sensitizing capacity and cross-reaction pattern of the isomers of diglycidyl ether of bisphenol F in the guinea pig. Contact Dermatitis 2002: 47: 293-298.
23. Bokelund F, Fregert S, Trulsson L. Sensitization from epoxy resin powder of high molecular weight. Contact Dermatitis 1980: 6: 144.
24. Commission Directive 98/98/E C of 15 December 1998 document no 31998L0098.
25. Prens E P, de Jong G, van Joost T. Sensitization to epichlorohydrin and epoxy system components. Contact Dermatitis 1986: 15: 85-90.
26. Jolanki R, Kanerva L, Estlander T, Tarvainen K, Keskinen H, Henriks-Eckerman M L. Occupational dermatoses from epoxy resin compounds. Contact Dermatitis 1990: 23: 179-180.
27. Kanerva L, Jolanki R, Alanko K, Estlander T. Patch test reactions to plastic and glue allergens. Acta Derm Venereol 1999: 79: 296-300.