Photolysis frequency of O3 to O(1D): Measurements and modeling during the International Photolysis Frequency Measurement and Modeling Intercomparison (IPMMI)

Journal of Geophysical Research: Atmospheres

Volumn 109, Issue 8, 2004, Pages

  Hofzumahaus, A ^a   Lefer, B L ^b   Monks, P S ^c   Hall, S R ^b   Kylling, A ^d   Mayer, B ^b   Shetter, R E ^b   Junkermann, W ^e   Bais, A ^f   Calvert, J G ^b   Cantrell, C A ^b   Madronich, S ^b   Edwards, G D ^c   Kraus, A ^a   Muller M ^a   Bohn, B ^a   Schmitt, R ^g   Johnston, P ^h   McKenzie, R ^h   Frost, G J ⁱ   Griffioen, E ^j   Krol, M ^k   Martin, T ^e,l   Pfister, G ^l   Roth E P ^a,m   Ruggaber, A ⁿ   Swartz, W H ^o   Lloyd, S A ^o   Van Weele, M ^p   more..

^a FORSCHUNGSZENTRUM JÜLICH   (Germany)

^b NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^c UNIVERSITY OF LEICESTER   (United Kingdom)

^d NORWEGIAN INSTITUTE FOR AIR RESEARCH   (Norway)

^e KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^f ARISTOTLE UNIVERSITY OF THESSALONIKI   (Greece)

^g Meteorologie Consult GmbH   (Germany)

^h NATIONAL INSTITUTE OF WATER AND ATMOSPHERIC RESEARCH   (New Zealand)

ⁱ UNIVERSITY OF COLORADO   (United States)

^j ENVIRONMENT CANADA   (Canada)

^k UTRECHT UNIVERSITY   (Netherlands)

^l UNIVERSITY OF GRAZ   (Austria)

^m UNIVERSITY OF DUISBURG ESSEN   (Germany)

ⁿ UNIVERSITY OF MUNICH   (Germany)

^o JOHNS HOPKINS UNIVERSITY   (United States)

^p ROYAL NETHERLANDS METEOROLOGICAL INSTITUTE KNMI   (Netherlands)

more..

Author keywords

Intercomparison; Measurement; Ozone; Photolysis frequency; Radiative transfer modeling

Indexed keywords

ATMOSPHERIC CHEMISTRY; NUMERICAL MODEL; OZONE; PHOTOLYSIS; RADIATIVE TRANSFER;

BOULDER; COLORADO; NORTH AMERICA; UNITED STATES;

EID: 3042706056     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2003JD004333     Document Type: Article

References (65)

1. 1D) formation by ozone photolysis in the troposphere, Pure Appl. Geophys., 116, 537-544.
2. g), at ground level, Atmos. Environ., 13, 1515-1522.
3. 1D)> using a luminol detector, Geophys. Res. Lett., 19, 2047-2050.
4. Bais, A. F., et al. (2003), International Photolysis Frequency Measurement and Model Intercomparison (IPMMI): Spectral actinic solar flux measurements and modeling, J. Geophys. Res., 108(D16), 8543, doi:10.1029/2002JD002891.
5. g) from the photolysis of ozone in the wavelength range 270 nm 〈 λ 〈 329 am, Geophys. Res. Lett., 20, 2063-2066.
6. 1D) quantum yields from the photodissociation of ozone berveen 300 and 328 nm, Chem. Phys. Lett., 264, 531-538.
7. Bass, A. M., and R. J. Paur (1985), The ultraviolet cross sections of ozone: I, II, in Atmospheric Ozone, Proceedings of the Quadrennial Ozone Symposium, Greece, edited by C. S. Zerefos and A. Ghazi, pp. 606-616, D. Reidel, Norwell, Mass.
8. 3 photolysis in the near UV region between 305 and 375 nm, Phys. Chem. Chem. Phys., 2, 1421-1424.
9. Blackburn, T. E., S. T. Bairai, and D. H. Stedman (1992), Solar photolysis of ozone to singlet D oxygen atoms, J. Geophys. Res., 97, 10,109-10,117.
10. 1D) photolysis frequencies using filter radiometry, J. Geophys. Res, 109, doi:10.1029/2003JD004319, in press.
11. Brauers, T., H.-P. Dorn, H. Koch, A. B. Kraus, and C. Plass-Dülmer (1998), Meteorological aspects, ozone, and solar radiation measurements during POPCORN 1994, J. Atmos. Chem., 31, 33-52.
12. 1D) quantum yields in the fall-off region 297-325 nm, Chem. Phys., 46, 477-484.
13. 3 in the 231-794 nm range, J. Quant. Spectrosc. Radiat. Transfer, 61, 509-517.
14. Cantrell, C. A., J. G. Calvert, A. Bais, R. E. Shetter, B. L. Lefer, and G. D. Edwards (2003), Overview and conclusions of the International Photolysis Frequency Measurement and Modeling Intercomparison (IPMMI) study, J. Geophys. Res., 108(D16), 8542, doi:10.1029/2002JD002962.
15. Crawford, J., D. Davis, G. Chen, R. Shetter, M. Müller, J. Barrick, and J. Olson (1999), An assessment of cloud effiects on photolysis rate coefficients: Comparison of experimental and theoretical values, J. Geophys. Res., 104, 5725-5734.
16. Dahlback, A., and K. Stamnes (1991), A new spherical model for computing the radiation-field available for photolysis and heating at twilight, Planet. Space Sci., 39, 671-683.
17. DeMore, W. B., S. P. Sander, C. J. Howard, A. R. Ravishankara, D. M. Golden, C. E. Kolb, R. F. Hampson, M. J. Kurylo, and M. J. Molina (1994), Chemical kinetics and photochemical data for use in stratospheric modeling: Evaluation number 11, JPL Publ., 94-26.
18. DeMore, W. B., S. P. Sander, C. J. Howard, A. R. Ravishankara, D. M. Golden, C. E. Kolb, R. F. Hampson, M. J. Kurylo, and M. J. Molina (1997), Chemical kinetics and photochemical data for use in stratospheric modeling: Evaluation number 12, JPL Publ., 97-4.
19. 1D, Geophys. Res. Lett., 6, 833-836.
20. Dickerson, R. R., D. H. Stedman, and A. C. Delany (1982), Direct measurements of ozone and nitrogen dioxide photolysis rates in the troposphere, J. Geophys. Res., 87, 4933-4946.
21. Eckstein, E., D. Perner, and T. Trautmann (2002), A new actinic flux 4ν-spectrorandiometer: Instrument design and application to clear sky and broken cloud conditions, Atmos. Chem. Phys Discuss., 2, 1939-1977.
22. Edwards, G. D., and P. S. Monks (2003), Performance of a single monochromator diode array spectroradiometer for the determination of actinic flux and atmospheric photolysis frequencies, J. Geophys. Res., 108(D16), 8546, doi:10.1029/2002JD002844.
23. Ehhalt, D. H., H.-P. Dorn, and D. Poppe (1991), The chemistry of the hydroxyl radical in the troposphere, Proc. R. Soc. Edinburgh, Sect. B: Riol. Sci., 97, 17-34.
24. 1D) and primary OH production rates over the Atlantic Ocean between 50°N and 30°S, J. Atmos. Chem., 15, 283-298.
25. Hofzumahaus, A., A. Kraus, and M. Müller (1999), Solar actinic flux spectroradiometry: A technique for measuring photolysis frequencies in the atmosphere, Appl. Opt., 38, 4443-4460.
26. Hofzumahaus, A., A. Kraus, A. Kylling, and C. S. Zerefos (2002), Solar actinic radiation (280-420 nm) in the cloud-free troposphere between ground and 12 km altitude: Measurements and model results, J. Geophys. Res., 107(D18), 8139, doi:10.1029/2001JD900142.
27. 1D) actinic flux within and above stratiform clouds and above snow surfaces, Geophys. Res. Lett., 21, 793-796.
28. Junkermann, W. (2001), An ultralight aircraft as platform for research in the lower troposphere: System performance and first results from radiation transfer studies in stratiform aerosol layers and broken cloud conditions, J. Atmos. Oceanic Technol., 18, 934-946.
29. Junkermann, W., U. Platt, and A. Volz-Thomas (1989), A photoelectric detector for the measurement of photolysis frequencies of ozone and other atmospheric molecules, J. Atmos. Chem., 8, 203-227.
30. Kanaya, Y., Y. Kajii, and H. Akimoto (2003), Solar actinic flux and photolysis frequency determinations by radiometers and a radiative transfer model at Rishiri Island: Comparisons, cloud effects, and detection of an aerosol plume from Russian forest fires, Atmos. Environ., 37, 2463-2475.
31. 2 and HONO by UV spectroradiometry, J. Atmos. Chem., 31, 161-180.
32. Kylling, A., K. Stamnes, and S.-C. Tsay (1995), A reliable and efficient two-stream algorithm for spherical radiative transfer: Documentation of accuracy in realistic layered media, J. Atmos. Sci., 21, 115-150.
33. Lefer, B. L., S. R. Hall, L. Cinquini, and R. E. Shetter (2001), Photolysis frequency measurements at the South Pole during ISCAT-98, Geophys. Res. Lett., 28, 3637-3640.
34. Levy, H., II (1972), Photochemistry of the lower troposphere, Planet. Space Sci., 20, 919-935.
35. Levy, H., II (1974), Photochemistry of the troposphere, Adv. Photochem., 9, 369-523.
36. Madronich, S. (1987), Photodissociation in the atmosphere: I. Actinic fluor and the effects of ground reflection and clouds, J. Geophys. Res., 92, 9740-9752.
37. Malicet, J., D. Daumont, J. Charbonnier, C. Parrisse, A. Chakir, and J. Brion (1995), Ozone UV spectroscopy. II. Absorption cross-sections and temperature dependence, J. Atmos. Chem., 21, 263-273.
38. 1D) in the ultraviolet photolysis of ozone: Recommendation based on evaluation of laboratory data, J. Geophys. Res., 107(D3), 4024, doi:10.1029/2001JD000510.
39. McElroy, C. T., C. Midwinter, D. V. Barton, and R. B. Hall (1995), A comparison of J-values from the composition and photodissociative flux measurement with model calculations, Geophys. Res. Lett., 22, 1365-1368.
40. McKenzie, R. L., P. V. Johnston, M. Kotkamp, A. Bittar, and J. D. Hamlin (1992), Solar ultraviolet spectronadiometry in New Zealand: Instrumentation and sample results from 1990, Appl. Opt., 31, 6501-6509.
41. McKenzie, R., P. Johnston, A. Hofzumahaus, A. Kraus, S. Madronich, C. A. Cantrell, J. G. Calvert, and R. E. Sherter (2002), Relationship between photolysis frequencies derived from spectroscopic measurements of actinic fluxes and irradiances during the IPMMI campaign, J. Geophys. Res., 107(D5), 4042, doi:10.1029/2001JD000601.
42. 3, Geophys Res. Lett., 21, 2227-2230.
43. Molina, L. T., and M. J. Molina (1986), Absolute absorption cross sections of ozone in the 185- to 350-nm wavelength range, J. Geophys. Res., 91, 14,501-14,508.
44. Monks, P. S., L. J. Carpenter, S. A. Penkett, G. P. Ayers, R. W. Gillet, I. E. Galbally, and C. P. Meyer (1998), Fundamental ozone photochemistry in the remote marine boundary layer: The SOAPEX experiment, measurement and theory, Atmos. Environ., 32, 3647-3664.
45. Müller, M. (1994), Messung der aktinischen ultravioletten Strahlung und der Ozon-Photolysefrequenz in der Atmosphäre mittels Filterradiometrie und Spektralradiometrie, Ph.D. thesis, Univ. of Bonn, Bonn, Germany.
46. 1D) photolysis frequencies determined from spectroradiometric measurements of solar actinic UV-radiation: Comparison with chemical actinometer measurements, Geophys. Res. Lett., 22, 679-682.
47. Olson, J., et al. (1997), Results from the Intergovernmental Panel on Climatic Change Photochemical Model Intercomparison (PhotoComp), J. Geophys. Res., 102, 5979-5991.
48. Pfister, G., D. Baumgartner, R. Maderbacher, and E. Putz (2000), Aircraft measurements of photolysis rate coefficients for ozone and nitrogen dioxide under cloudy conditions, Atmos. Environ., 34, 4019-4029.
49. Sander, S. P., et al. (2000), Chemical kinetics and photochemical data for use in stratospheric modeling, supplement to evaluation number 12: Update of key reactions, evaluation number 13, JPL Publ., 00-3.
50. Sander, S. R, et al. (2003), Chemical kinetics and photochemical data for use in atmospheric studies: Evaluation number 14, JPL Publ., 02-25.
51. Shetter, R. E., and M. Müller (1999), Photolysis frequency measurements using actinic flux spectroradiometry during the PEM-Tropics mission: Instrumentation description and some results, J. Geophys. Res., 104, 5647-5661.
52. 1D) during the Mauna Loa Observatory Photochemistry Experiment 2, J. Geophys. Res., 101, 14,631-14,642.
53. Shetter, R. E., L. Cinquini, B. L. Lefer, S. R. Hall, and S. Madronich (2002), Comparison of airborne measured and calculated spectral actinic flux and derived photolysis frequencies during the PEM Tropics B mission, J. Geophys. Res., 107, 8234, doi:10.1029/2001JD001320. [printed 108(D2), 2003]
54. 2: Measurement and modeling during the International Photolysis Frequency Measurement and Modeling Intercomparison (IPMMI), J. Geophys. Res., 108(D16), 8544, doi:10.1029/2002JD002932.
55. 1D) quantum yields from the photolysis of ozone between 295 and 338 nm, J. Phys. Chem., 104, 8916-8921.
56. Stamnes, K., S.-C. Tsay, W. Wiscombe, and K. Jayaweera (1988), Numerical stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media, Appl. Opt., 27, 2502-2509.
57. Stockwell, W. R., P. Middleton, J. S. Chang, and X. Tang (1990), The second generation regional acid deposition model: Chemical mechanism for regional air quality modelling, J. Geophys. Res., 95, 16,343-16,367.
58. Swartz, W. H. (2002), Quantifying photolysis rates in the troposphere and stratosphere, Ph.D. thesis, Univ. of Md., College Park.
59. 3P,) products, J. Phys. Chem., 100, 4084-4089.
60. 1D) yield from the 305-329 nm photodissociation of ozone, J. Chem. Phys., 108, 7161-7172.
61. 1D) as a function of temperature, Geophys. Res. Lett., 24, 1091-1094.
62. 1D) in the photolysis of ozone between 289 and 329 nm as a function of temperature, Geophys. Res. Lett., 25, 143-146.
63. 2) following ozone photolysis between 275 and 325 nm, J. Geophys. Res., 93, 7119-7124.
64. WMO Global Ozone Research and Monitoring Project (1985), Atmospheric ozone 1985: Assessment of our understanding of the processes controlling its present distribution and change, vol. 1, Tech. Rep. 16, World Meteorol. Organ., Geneva.
65. Woods, T. N., et al. (1996), Validation of the UARS solar ultraviolet irradiances: Comparison with the Atlas 1 and 2 measurements, J. Geophys. Res., 101, 9541-9569.