Extraction of U(VI), Th(IV), Sc(III), and rare-earth elements from nitric acid solutions by selected bifunctional neutral organophosphorus compounds

Solvent Extraction and Ion Exchange

Volumn 22, Issue 3, 2004, Pages 391-413

  Turanov, A N ^a   Karandashev, V K ^b   Yarkevich, A N ^c   Safronova, Z V ^c  

^a INSTITUTE OF SOLID STATE PHYSICS   (Russian Federation)

^b RUSSIAN ACADEMY OF SCIENCES   (Russian Federation)

^c INSTITUTE OF PHYSIOLOGICALLY ACTIVE COMPOUNDS   (Russian Federation)

Author keywords

Extractant; Nitric acid solution; Organophosphorus compounds; Rare earth elements

Indexed keywords

ION EXCHANGE; SOLVENT EXTRACTION; STOICHIOMETRY; SUBSTITUTION REACTIONS;

METAL IONS; PHENYL RADICALS;

ORGANOMETALLICS;

SOLVENT;

EID: 3042631549     PISSN: 07366299     EISSN: None     Source Type: Journal    
DOI: 10.1081/SEI-120030397     Document Type: Article

References (33)

1. Siddall, T.H., III. Bidentate organophosphorus compound as extractants-I. Extraction of cerium, promethium, and americium nitrates. J. Inorg. Nucl. Chem. 1963, 25, 883-892.
2. Mrochek, J.E.; Banks, C.V. bis-(Disubstitutedphosphinyl)-alkanes-IV. Extraction of mineral acids, uranium (VI), and some lanthanides. J. Inorg. Nucl. Chem. 1965, 27, 589-601.
3. Rozen, A.M.; Nikolotova, Z.I.; Kartasheva, N.A.; Yudina, K.S. An anomalous dependence of Am(III) complexes stability upon the structure of diphosphine dioxides. Dokl. Akad. Nauk SSSR 1975, 222, 1151-1154.
4. Rozen, A.M.; Nikolotova, Z.I.; Kartasheva, N.A.; Yudina, K.S. Complexation of Am, Cm, and lanthanides with organic dioxides. Radiokhimiya 1977, 19, 709-719.
5. Turanov, A.N.; Karandashev, V.K.; Yarkevich, A.N. Extraction of rare-earth elements and yttrium from nitric acid solutions by butyl(diphenylphosphinylmethyl)phenylphosphinate. Solv. Extr. Ion Exch. 2002, 20 (1), 1-19.
6. Turanov, A.N.; Karandashev, V.K.; Yarkevich, A.N.; Ushakova, A.P. Extraction of Am (III) and rare-earth elements by dibutyl(diphenylphosphinylmethyl)phosphonate from nitric acid solution. Radiokhimiya 2002, 44 (2), 130-134.
7. Tsvetkov, E.N.; Bondarenko, N.A.; Malakhova, I.G.; Kabachnik, M.I. A simple synthetic method of phosphide- and phosphinite-substituted anions and synthesis on their basis. Zh. Obshch. Khim. 1985, 55, 11-26.
8. Yarkevich, A.N.; Tsvetkov, E.N. Chloromethylphosphoryl compounds in the Arbuzov reaction. Zh. Obshch. Khim. 2002, 72 (3), 521-522.
9. Turanov, A.N.; Karandashev, V.K.; Yarkevich, A.N.; Safronova, Z.V. Extraction of Am(III) and Eu(III) from nitric acid solutions by bidentate neutral organophosphorus compounds. Radiokhimiya, in press.
10. Patsanovskii, I.I.; Ishmaeva, E.A.; Sundukova, E.N.; Yarkevich, A.N.; Tsvetkov, E.N. Regularities of rotatory isomery in the methylsubstituted oxides of dialkyl- and diarylmethylphosphines. Zh. Obshch. Khim. 1986, 56 (3), 567-576.
11. Chauzov, V.A.; Studnev, Yu.M.; Iznoskova, M.G.; Fokin, A.V. Preparation of methylenediphosphine oxides and carbamoylmethylphosphine oxides from O-trimethylsilyl phosphinites. Zh. Obshch. Khim. 1987, 57 (1), 54-56.
12. Turanov, A.N.; Karandashev, V.K.; Baulin, V.E. Extraction of metal chloride complexes by phosphoryl-containing podands. Solv. Extr. Ion Exch. 1996, 14, 227-245.
13. Chiarizia, R.; Horwitz, E.P.; Dietz, M.L. Acid dependency of the extraction of selected metal ions by a strontium-selective extraction chromatographic resin: calculated vs. experimental curves. Solv. Extr. Ion Exch. 1992, 10, 337-361.
14. Rozen, A.M.; Berkman, Z.A.; Bertina, L.E.; Denisov, D.A.; Zarubin, A.I.; Kossih, V.G.; Nikolotova, Z.I.; Pisareva, S.A.; Yudina, K.S. Extraction of nitric acid by alkylenediphosphine dioxides. Radiokhimiya 1976, 18, 493-501.
15. P constants in the chemistry of organophosphorus compounds. Uspechi Khimii. 1969, 38, 1751-1782.
16. Shvedov, V.P.; Orlov, Yu.F. Nitric acid extraction by phosphate and phosphonate derivatives. Zh. Neorg. Khim. 1965, 10 (12), 2774-2779.
17. Rozen, A.M.; Krupnov, B.V. Dependence of the extraction ability of organic compounds on their structure. Uspechi Khimii. 1996, 65, 1052-1079.
18. Rozen, A.M.; Nikolotova, Z.I.; Kartasheva, N.A.; Yudina, K.S. Complexation of Am, Cm, and lanthanides with organic dioxides. Radiokhimiya 1977, 19, 709-719.
19. Sasaki, Y.; Tachimori, S. Extraction of actinides (III), (IV), (V), (VI), and lanthanides (III) by structurally tailored diamides. Solv. Extr. Ion Exch. 2002, 20 (1), 21-34.
20. Horwitz, E.P.; Martin, K.A.; Diamond, H.; Kaplan, L. Extraction of Am from nitric acid by carbamoyl-phosphoryl extractants: the influence of substituents on the selectivity of Am over Fe and selected fission products. Solv. Extr. Ion Exch. 1986, 4, 449-494.
21. Mowafy, E.A.; Aly, H.F. Extraction of actinides and selected fission products from nitric acid medium using long chain monoamides. Solv. Extr. Ion Exch. 2001, 19 (4), 629-641.
22. Turanov, A.N.; Karandashev, V.K.; Kharitonov, A.V.; Safronova, Z.V.; Yarkevich, A.N. Extraction of U, Th, Sc and Zr by tetraphenylalkylenediphosphine dioxides from nitric acid solutions. Radiokhimiya 2000, 42 (4), 349-353.
23. Turanov, A.N.; Karandashev, V.K.; Baulin, V.E. Extraction of rare-earth elements from nitric acid solutions with bidentate phosphoryl-containing compounds and their mixtures. Radiokhimiya 2001, 43, 72-78.
24. Turanov, A.N.; Karandashev, V.K.; Kharitonov, A.V.; Yarkevich, A.N.; Safronova, Z.V. Extraction of scandium, rare-earth elements, and yttrium from nitric acid solutions by selected diphosphine dioxides. Solv. Extr. Ion Exch. 2000, 18 (6), 1109-1134.
25. Vlasov, V.S.; Rozen, A.M. The activity coefficients of lanthanides and actinides in nitric acid solutions. Radiokhimiya 1988, 30, 146-147.
26. Litvina, M.N.; Chmutova, M.K.; Myasoedov, B.F.; Kabachnik, M.I. Extraction of rare-earth elements and americium and their separation factor in nitric acid-diaryl(dialkyl)[dialkylcarbamoylmethyl]phosphine oxide systems. Radiokhimiya 1996, 38 (6), 526-530.
27. Chiarizia, R.; Horwitz, E.P. Diluent effects in the extraction of Am(III) from nitric acid solutions by selected carbamoyl-phosphoryl extractants and related monofunctional compounds. Solv. Extr. Ion Exch. 1992, 10, 101-118.
28. Kabachnik, M.I.; Myasoedov, B.F.; Mastryukova, T.A.; Polikarpov, Yu.M.; Chmutova, M.K.; Nesterova, N.P. Correlation analysis of "aryl strengthening" for extraction ability of bidentate organophosphorus extractant. Izvestiya A.N. Seriya Khim. 1996, 2624-2629.
29. Tsvetkov, E.N.; Evreinov, V.I.; Bondarenko, N.A.; Safronova, Z.V. Effect of alkyl substituents at the phosphorus atom on complexability of neutral monopodands. Zh. Obshch. Khim. 1996, 66, 1081-1092.
30. Rozen, A.M.; Nikolotova, Z.I.; Kartasheva, N.A.; Bolshakova, A.S. Anomalous aryl strengthening effect americium and europium extraction by alkylenediphosphine dioxides from perchlorate medium. Radiokhimiya 1978, 20 (5), 725-734.
31. Sc, Y, La-Lu rare earth elements, Part D6. Ion exchange and solvent extraction reactions, organometallic compounds. In Gmelin Handbook of Inorganic Chemistry, 8th Ed.; Springer-Verlag: Berlin, 1983; 1-136.
32. Nash, K. Aqueous complexes in separations of f-elements: options and strategies for future development. Sep. Sci. Technol. 1999, 34 (6&7), 911-929.
33. Suresh, G.; Murali, M.S.; Mathur, J.N. Effect of anions on thermodynamics of extraction of Am(III) and Eu(III) with octyl(phenyl)-N,N-diisobutyl-carbamoylmethylphosphine Oxide. Solv. Extr. Ion Exch. 2001, 19 (6), 947-964.