Nonadiabatic electron transfer at the nanoscale tin-oxide semiconductor/aqueous solution interface

Photochemical and Photobiological Sciences

Volumn 3, Issue 3, 2004, Pages 240-245

  Gaal, Dennis A ^a   McGarrah, James E ^a   Liu, Fang ^a   Cook, Jamie E ^a   Hupp, Joseph T ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; METAL COMPLEX; METHYL GROUP; NANOPARTICLE; OSMIUM; OXIDE; TIN; TRIS(2,2' BIPYRIDINE)RUTHENIUM;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOPHORE; COMPLEX FORMATION; CONTROLLED STUDY; ELECTRICITY; ELECTRON TRANSPORT; EXCITATION; PRIORITY JOURNAL; SEMICONDUCTOR;

EID: 3042589355     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/b313694a     Document Type: Article

References (34)

1. K. Kalyanasundaram M. Grätzel Applications of functionalized transition metal complexes in photonic and optoelectronic devices Coord. Chem. Rev. 1998 177 347-414.
2. 2 films Nature 1991 353 737-739.
3. C. A. Kelly G. J. Meyer Excited state processes at sensitized nanocrystalline thin film semiconductor interfaces Coord. Chem. Rev. 2001 211 295-315.
4. S. G. Yan J. S. Prieskorn Y. Kim J. T. Hupp In search of the inverted region: Chromophore-based driving force dependence of interfacial electron transfer reactivity at the nanocrystalline titanium dioxide semiconductor/solution interface J. Phys. Chem. B. 2000 104 10871-10877.
5. X. J. Dang J. T. Hupp Interfacial charge transfer pathways: Evidence for Marcus-type inverted electron transfer in metal oxide semiconductor/inorganic dye systems J. Am. Chem. Soc. 1999 121 8399-8400.
6. D. A. Gaal J. T. Hupp Thermally activated, inverted interfacial electron transfer kinetics: High driving force reactions between tin oxide nanoparticles and electrostatically-bound molecular reactants J. Am. Chem. Soc. 2000 122 10956-10963.
7. 2-water interfaces’, in Semiconductor Photochemistry and Photophysics, ed. V. Ramamurthy and K. S. Schanze, Marcel Dekker, New York, 2003, pp. 89–121.
8. R. A. Marcus On the theory of electron transfer. VI. Unified treatment for homogeneous and electrode reactions J. Chem. Phys. 1965 43 679-701.
9. N. Sutin Electron transfer reactions in solution: A historical perspective Adv. Chem. Phys. 1999 106 7-33.
10. M. Bixon J. Jortner Non-Arrhenius temperature dependence of electron-transfer rates J. Phys. Chem. 1991 95 1941-1944.
11. E. Galoppini W. Z. Guo P. Qu G. J. Meyer Long-distance electron transfer across molecule-nanocrystalline semiconductor interfaces J. Am. Chem. Soc. 2001 123 4342-4343.
12. J. Nelson S. A. Haque D. R. Klug J. R. Durrant Trap-limited recombination in dye-sensitized nanocrystalline metal oxide electrodes Phys. Rev. B. 2001 6320 205-321.
13. 2 dye-sensitized solar cells. Nonequilibrium steady-state statistics and interfacial electron transfer via surface states J. Phys. Chem. B. 2002 106 8774-8782.
14. A. V. Barzykin M. Tachiya Mechanism of charge recombination in dye-sensitized nanocrystalline semiconductors: Random flight model J. Phys. Chem. B. 2002 106 4356-4363.
15. G. L. Closs J. R. Miller Intramolecular long-distance electron transfer in organic molecules Science 1988 240 440-447.
16. N. Sutin Nuclear, electronic, and frequency factors in electron-transfer reactions Acc. Chem. Res. 1982 15 275-282.
17. 2 over the distance of 24 angstroms J. Am. Chem. Soc. 2003 125 5278-5279.
18. 2 thin films studied by femtosecond infrared spectroscopy J. Phys. Chem. B. 2000 104 11957-11964.
19. N. Garelli P. Vierling Synthesis of new amphiphilic perfluoroalkylated bipyridine J. Org. Chem. 1992 57 3046-3051.
20. P. E. Rosevear W. H. F. Sasse The synthesis of some 4,4′,4′′-trialkyl-2,2′:6′,2′′-terpyridyls J. Heterocycl. Chem. 1971 8 483-485.
21. O. Fussa-Rydel H. Zhang J. T. Hupp C. R. Leidner Electrochemical assembly of metallopolymeric films via reduction of coordinated 5-chlorophenanthroline Inorg. Chem. 1989 28 1533-1537.
22. E. M. Kober J. V. Caspar B. P. Sullivan T. J. Meyer Synthetic routes to new polypyridyl complexes of osmium(II) Inorg. Chem. 1988 27 4587-4598.
23. G. M. Hasselmann G. J. Meyer Diffusion-limited interfacial electron transfer with large apparent driving forces J. Phys. Chem. B. 1999 103 7671-7675.
24. D. Kuciauskas M. S. Freund H. B. Gray J. R. Winkler N. S. Lewis Electron transfer dynamics in nanocrystalline titanium dioxide solar cells sensitized with ruthenium or osmium polypyridyl complexes J. Phys. Chem. B. 2001 105 392-403.
25. J. M. Bolts M. S. Wrighton Correlation of photocurrent-voltage curves with flat-band potential for stable photoelectrodes for photoelectrolysis of water J. Phys. Chem. 1976 80 2641-2645.
26. R. A. Marcus Theory of electron-transfer rates across liquid/liquid interfaces. 2. Relationships and application J. Phys. Chem. B. 1991 95 2010-2013.
27. R. A. Marcus N. Sutin Electron transfers in chemistry and biology Biochim. Biophys. Acta. 1985 811 265-322.
28. S. S. Iseid A. Vassilian J. F. Wishart C. Creutz H. A. Schwarz N. Sutin The distance dependence of intramolecular electron-transfer rates: Importance of the nuclear factor J. Am. Chem. Soc. 1988 110 635-637.
29. S. G. Yan L. A. Lyon B. I. Lemon J. S. Prieskorn J. T. Hupp Energy conversion chemistry: Mechanisms of charge transfer at metal-oxide semiconductor/solution interfaces J. Chem. Educ. 1997 74 657-662.
30. 2 electrodes by polypyridine ruthenium(II) complexes J. Am. Chem. Soc. 1977 99 4676-4682.
31. 4− on colloidal titanium dioxide. A mode-by-mode description of the Franck–Condon barrier to interfacial charge transfer J. Am. Chem. Soc. 1991 113 1060-1062.
32. J. T. Hupp M. J. Weaver The frequency factor for outer-sphere electrochemical reactions J. Electroanal. Chem. Interfacial Electrochem. 1983 152 1-14.
33. G. M. Brown N. Sutin A comparison of the rates of electron exchange reactions of ammine complexes of ruthenium(II) and (III) with the predictions of adiabatic, outer-sphere electron transfer models J. Am. Chem. Soc. 1979 101 883-892.
34. N. Sutin B. S. Brunschwig Electron transfer in weakly interacting systems ACS Symp. Ser. 1982 198 105-125.