Development of calibration models for estimation of monomer concentration by Raman spectroscopy during emulsion polymerization: Facing the medium heterogeneity

Journal of Applied Polymer Science

Volumn 93, Issue 3, 2004, Pages 1136-1150

  Reis, Marlon M ^a   Araújo, Pedro H H ^a   Sayer, Claudia ^a   Giudici, Reinaldo ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Copolymerization; Emulsion polymerization; Partial least squares; Process monitoring; Raman spectroscopy; Sensors

Indexed keywords

CALIBRATION; DATA ACQUISITION; DECISION MAKING; DISPERSIONS; EMULSION POLYMERIZATION; FREE RADICAL POLYMERIZATION; LEAST SQUARES APPROXIMATIONS; POLYACRYLATES; RAMAN SPECTROSCOPY;

PARTIAL LEAST SQUARES; PROCESS MONITORING;

MONOMERS;

POLYMER SCIENCE;

EID: 3042517027     PISSN: 00218995     EISSN: None     Source Type: Journal    
DOI: 10.1002/app.20474     Document Type: Article

References (17)

1. Kiparissides, C. Chem Eng Sci 1996, 51, 1637.
2. Dimitratos, J.; Eliçabe, G.; Georgakis, C. AIChE J 1994, 40 1993.
3. Laserna, J. J. Modern Techniques in Raman Spectroscopy; ohn Wiley & Sons: New York, 1996.
4. Hendra, P.; Jones, C.; Warnes, G. Fourier Transform Raman Spectroscopy, Instrumentation and Chemical Application; Ellis Horwood: Chichester, England 1991; p. 127.
5. Wang, C.; Vickers, T. J.; Mann, C. K. Appl Spectrosc 1993, 47, 928.
6. Al-Khanbashi, A.; Hansen, M. G.; Wachter, E. A. Appl Spectrosc 1996, 50, 1089.
7. Özpozan, T.; Schrader, B.; Keller, S. Spectrochim Acta 1997, 53, 1.
8. Bauer, C.; Amram, B.; Agnely, M.; Charmot, D.; Sawatzki, J.; Dupuy, N.; Huvenne, J.-P. Appl Spectrosc 2000, 54, 528.
9. Charmot, D.; Amram, B.; Drochon, B.; Agnely, M.; Armitage, P.; Pere, E. Patent EP1163504, 2000.
10. van den Brink, M. On-Line Monitoring of Polymerization Reactions by Raman Spectroscopy: Application to Control of Emulsion Copolymerizations and Copolymerizations Kinetics; Ph. D. Thesis, Eindhoven University of Technology, Eindhoven, The Netherlands, 2000.
11. Van den Brink, M.; Pepers, M.; van Herk, A. M.; German, A. L. Polym React Eng 2001, 9, 101.
12. Reis, M. M.; Araújo, P. H. H.; Sayer, C.; Giudici, R. Macromolecular Symposia 2004, 206, 165.
13. Jackson, J. E. A User's Guide to Principal Component; John Wiley & Sons: New York, 1991.
14. Geladi, P.; Kowalski, B. R. Anal Chim Acta 1986, 185, 1.
15. de Jong, S. Chemom Intell Lab Syst 1993, 18, 251.
16. Lin-Vien, D.; Colthup, N. B.; Fateley, W. G.; Grasselli, J. G. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press: San Diego, CA, 1991.
17. Ellis, G.; Claybourn, M.; Richards, S. E. Spectrochim Acta 1990, 46A, 227.