Solvation properties of N-substituted cis and trans amides are not identical: Significant enthalpy and entropy changes are revealed by the use of variable temperature1H NMR in aqueous and chloroform solutions and ab initio calculations

Journal of Physical Chemistry A

Volumn 109, Issue 51, 2005, Pages 11878-11884

  Troganis, Anastassios N ^c   Sicilia, Emilia ^b   Barbarossou, Klimentini ^a   Gerothanassis, Ioannis P ^a   Russo, Nino ^a  

^a UNIVERSITY OF IOANNINA   (Greece)

^b UNIVERSITY OF CALABRIA   (Italy)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

DIELECTRIC PROPERTIES; ENTROPY; ISOMERS; MATHEMATICAL MODELS; SOLVENTS; THERMOANALYSIS;

AQUEOUS AND CHLOROFORM SOLUTIONS; N-METHYL FORMAMIDE (NMF); N-SUBSTITUTED CIS AND TRANS AMIDES; SOLVATION PROPERTIES;

ENTHALPY;

AMIDE; CHLOROFORM; FORMAMIDE DERIVATIVE; N METHYLFORMAMIDE; PEPTIDE; SOLVENT; WATER;

ALGORITHM; ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; COMPARATIVE STUDY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUTION AND SOLUBILITY; STEREOISOMERISM; TEMPERATURE; THERMODYNAMICS;

ALGORITHMS; AMIDES; CHLOROFORM; FORMAMIDES; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; PEPTIDES; SOLUTIONS; SOLVENTS; STEREOISOMERISM; TEMPERATURE; THERMODYNAMICS; WATER;

EID: 30344452303     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0537557     Document Type: Article

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