Adsorption of acidic impurities from organic esters using basic ion exchange resins as functionalized polymers

Separation Science and Technology

Volumn 40, Issue 14, 2005, Pages 2947-2962

  Dharavath, Ravindar ^a   Patil, Rashmi ^a   Gaikar, Vilas ^a  

^a UNIVERSITY OF MUMBAI   (India)

Author keywords

Acetic acid; Butyl acetate; Diethyl phthalate; Hydrogen bonding; Interaction parameters; Purification; Sorption

Indexed keywords

ADSORPTION; HYDROGEN BONDS; IMPURITIES; ION EXCHANGE; POROUS MATERIALS;

ACETIC ACIDS; BUTYL ACETATE; DIETHYL PHTHALATE; HYDROGEN BONDING; INTERACTION PARAMETERS;

ESTERS;

ACID MEDIUM; ADSORPTION; ESTER; ION EXCHANGE;

EID: 29744448743     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390500333236     Document Type: Article

References (28)

1. Koinuma, Y., Anami, K., and Ikebe, H. (1988) Purification of aromatic carboxylic acid esters. Jpn. Kokai Tokkyo Koho JP 63 174, 951 [88, 174, 951] (Cl. C07C67/56). c.f. Chem. Abstracts, 110: 7867.
2. Hosangadi, B.D. and Dave, R.H. (1996) An efficient general method for esterification of aromatic carboxylic acids. Tetra. Letters, 37 (35): 6375.
3. Gillios, J., Guillerm, G., Savignac, M., and Vo-Quang, L. (1986) Producing plastics in the laboratory. J. Chem. Edu., 63 (9): 811.
4. Matsushita, Y. (1991) Removal of tetraalkyltitanium catalysts from ester product mixture by complexation with polyhydric alcohols. Eur. Pat. Appl. EP 405,332 (Cl. C07C69/80), c.f. Chem. Abstracts, 114: 81250.
5. Hasegava, R. and Asano, H. (1988) Preparation of esters for use as plasticizers. Jpn. Kokai Tokkyo Koho JP 62,267, 341 [87, 267, 341] (Cl. C08 K5/10), c.f. Chem. Abstracts, 108, 132873.
6. Tretinnik, V.Y., Batyuk, V.P., Avilov, V.O., Kokta, O.D., and Sedlova, L.N. (1990) Purification of dioctyl phthalate with natural sorbents. Khim. Tekhnol., 3: 96,
7. (c.f. Chem. Abstracts, 113: 99799.
8. Stern, R. and Hillion, G. (1990) Purification of esters. Eur. Pat. Appl. EP 356, 317 (Cl. C07C67/56), c.f. Chem. Abstracts, 113: 58504.
9. Trzmielewska, H., Sadlowski, Z., Slugocki, E., Masal, C., Lewicki, M., Budzynski, K. and Fuks, S. (1997) Preparation and purification of phthalate esters. POL Pl 142, 971 (Cl. C07C69/80), c.f. Chem. Abstracts, 111: 9238.
10. Sven, S. and Gmehling, J. (2002) n-Butyl acetate synthesis vis reactive distillation: thermodynamic aspects, reaction kinetics, pilot plant experiments and simulation studies. Ind. Eng. Chem. Res., 41 (21): 5483.
11. Loning, S., Horst, C., and Hoffmann, V. (2000) Theoretical investigation on the quaternary system: n-Butanol, butyl acetate, acetic acid and water. Chem. Eng. Technol, 23: 789.
12. Hanika, J., Kolena, J., and Quido, S. (1999) Butyl acetate via distillation: Modeling and experiments. Chem. Eng. Sci., 54 (21): 5205.
13. Brune, B.J., Payne, G.F., Koehler, J.A., and Smith, P.J. (1999) Correlation between adsorption and small molecule hydrogen bonding. Langmuir, 15: 3987.
14. Maity, N., Payne, G.F., and Chipchosky, J.L. (1991) Adsorptive separations based on the differences in solute-sorbent hydrogen bonding strengths. Ind. Eng. Chem. Res., 30: 2456.
15. Payne, G.F. and Ninomiya, Y. (1990) Selective adsorption of solutes based on hydrogen bonding. Sep. Sci. Tech., 25 (11&12): 1117.
16. Maity, N. and Payne, G.F. (1991) Adsorption from aqueous solutions based on a combination of hydrogen bonding and hydrophobic interactions. Langmuir, 7: 1247.
17. Gaikar, V.G. and Anasthas, H.M. (2001) Separation of o-/p- Hydroxyacetophenones by selective solubilization and sorption on weak base ion exchange resin. Ind. Eng. Chem. Res., 41: 1335.
18. Prausnitz, J.M. (1969) Molecular Thermodynamic of Fluid Phase Equilibria; Prentice-Hall, Inc.: New Jersey.
19. Walas, S.M. (1985) Phase Equilibria in Chemical Engineering; Butterworth Publishers: Boston.
20. Anasthas, H.M. and Gaikar, V.G. (2001) Adsorption of acetic acid on ion exchange resin s in non-aqueous conditions. React. Funct. Poly., 47: 23.
21. Helfferich, F.G. (1962) Ion Exchange; McGraw-Hill Co. Inc.: New York.
22. Gusler, G.M., Browne, T.E., and Cohen, V. (1993) Sorption of organics from aqueous solutions onto polymeric resin. Ind. Eng. Chem. Res., 32: 2727.
23. Mazzotti, M., Neri, B., Gesola, D., Kruglow, A., and Morbidelli, M. (1996) A continuous Chromatographic reactor: SMBR. Chem. Eng. Sci., 51 (10): 1827.
24. Flory, P.J. (1942) Thermodynamics of high polymer solutions. J. Chem. Phys., 10: 51.
25. Flory, P.J. (1953) Principles of Polymer Chemistry; Cornell University Press: Ithica, New York.
26. Semmens, M. and Gregory, J. (1974) Selectivity of strongly basic anion exchange resins for organic anions. Environ. Sci. Technol., 8 (9): 834.
27. Treybal, R.E. (1981) Mass Transfer Operations, 3rd ed.; McGraw-Hill Inc.: New York.
28. Anasthas, H.M. and Gaikar, V.G. (2001) Removal of acetic acid impurities from ethyl acetate by adsorption on ion exchange resins. Sep. Sci. Technol., 36 (12): 2623.