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in this publication, the question whether the isolated compound was a racemate or an enantiomerically pure compound remains unanswered; b) diversonolic esters: J. S. Holker, E. O'Brien, T. J. Simpson, J. Chem. Soc. Perkin Trans. 1 1983, 1365-1368.
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29544433214
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note
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Details of this synthesis can be found in the Supporting Information.
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unpublished results
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Both of the two possible diastereoisomers could be synthesized selectively by using either meta-chloroperbenzoic acid or magnesium monoperoxophthalate as the oxidizing agent. The possibility of controlling the diastereoselectivity could be proved by X-ray structure analyses of model compounds; C. F. Nising, M. Nieger, S. Bräse, unpublished results.
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