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Volumn 45, Issue 2, 2005, Pages 307-309

The total synthesis of the fungal metabolite diversonol

Author keywords

Diversonol; Domino reactions; Fungal metabolites; Natural products; Total synthesis

Indexed keywords

ALDEHYDES; CONDENSATION; FUNGI; METABOLITES; SCAFFOLDS; SYNTHESIS (CHEMICAL);

EID: 29544439528     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502913     Document Type: Article
Times cited : (71)

References (34)
  • 19
    • 37049111828 scopus 로고
    • in this publication, the question whether the isolated compound was a racemate or an enantiomerically pure compound remains unanswered; b) diversonolic esters: J. S. Holker, E. O'Brien, T. J. Simpson, J. Chem. Soc. Perkin Trans. 1 1983, 1365-1368.
    • (1983) J. Chem. Soc. Perkin Trans. 1 , pp. 1365-1368
    • Holker, J.S.1    O'Brien, E.2    Simpson, T.J.3
  • 24
    • 7044235263 scopus 로고    scopus 로고
    • For a review of domino reactions see: L. F. Tietze, Chem. Rev. 1996, 96, 115-136.
    • (1996) Chem. Rev. , vol.96 , pp. 115-136
    • Tietze, L.F.1
  • 25
    • 29544433214 scopus 로고    scopus 로고
    • note
    • Details of this synthesis can be found in the Supporting Information.
  • 34
    • 29544433829 scopus 로고    scopus 로고
    • unpublished results
    • Both of the two possible diastereoisomers could be synthesized selectively by using either meta-chloroperbenzoic acid or magnesium monoperoxophthalate as the oxidizing agent. The possibility of controlling the diastereoselectivity could be proved by X-ray structure analyses of model compounds; C. F. Nising, M. Nieger, S. Bräse, unpublished results.
    • Nising, C.F.1    Nieger, M.2    Bräse, S.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.