η2-palladium and platinum(II) complexes of a λ4-phosphinine anion: Syntheses, X-ray crystal structures, and DFT calculations

Organometallics

Volumn 23, Issue 12, 2004, Pages 2870-2875

  Moores, Audrey ^a   Mézailles, Nicolas ^a   Ricard, Louis ^a   Jean, Yves ^a   Le Floch, Pascal ^a  

^a LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CHEMICAL BONDS; COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM; PLATINUM; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

BONDING MODES; COORDINATION CHEMISTRY; KINETIC STABILITY; NUCLEOPHILES;

REACTION KINETICS;

EID: 2942731523     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049871y     Document Type: Article

References (35)

1. (a) Ashe, A. J. I.; Smith, T. W. Tetrahedron Lett. 1977, 407-410.
2. (b) Märkl, G.; Merz, A. Tetrahedron Lett. 1968, 3611-3614.
3. (c) Märkl, G.; Merz, A. Tetrahedron Lett. 1971, 1215-1218.
4. (d) Märkl, G.; Martin, C.; Weber, W. Tetrahedron Lett. 1981, 22, 1207-1210.
5. (e) Dimroth, K. Acc. Chem. Res. 1982, 15, 58-64.
6. (a) Markl, G.; Martin, C. Angew. Chem., Int. Ed. Engl. 1974, 13, 408-409.
7. (b) Dave, T.; Berger, S.; Bilger, E.; Kaletach, H.; Pebler, J.; Knecht, J.; Dimroth, K. Organometallics 1985, 4, 1565-1572.
8. (c) Baum, G.; Massa, W. Organometallics 1985, 4, 1572-1574.
9. (d) Nief, F.; Fischer, J. Organometallics 1986, 5, 877-883.
10. Moores, A.; Ricard, L.; Le Floch, P.; Mézailles, N. Organometallics 2003, 22, 1960-1966.
11. Doux, M.; Mézailles, N.; Ricard, L.; Le Floch, P. Organometallics 2003, 22, 4624-4626.
12. (a) Doux, M.; Bouet, C.; Mézailles, N.; Ricard, L.; Le Floch, P. Organometallics 2002, 21, 2785-2788.
13. (b) Doux, M.; Mézailles, N.; Ricard, L.; Le Floch, P. Eur. J. Inorg. Chem. 2003, 3878-3894.
14. Doux, M.; Mézailles, N.; Melaimi, M.; Ricard, L.; Le Floch, P. Chem. Commun. 2002, 1566-1567.
15. (a) Karsch, H. H.; Grauvogl, G.; Kawecki, M.; Bissinger, P.; Kumberger, O.; Schier, A.; Muller, G. Organometallics 1994, 13, 610-618.
16. (b) Karsch, H. H.; Grauvogl, G.; Deubelly, B.; Muller, G. Organometallics 1992, 11, 4238-4245.
17. van der Sluis, M.; Beverwijk, V.; Termaten, A.; Bickelhaupt, F.; Kooijman, H.; Spek, A. L. Organometallics 1999, 18, 1402-1407.
18. Carrano, C. J.; Cowley, A. H.; Nunn, C. M.; Pakulski, M.; Quashie, S. J. Chem. Soc., Chem. Commun. 1988, 170-171.
19. ‡ formula see Supporting Information and Günther, H. NMR Spectroscopy; Wiley: New York, 1980.
20. Maseras, F.; Morokuma, K. J. Comput. Chem. 1995, 16, 1170-1179.
21. Harvey, J. N.; Heslop, K. M.; Orpen, A. G.; Pringle, P. G. Chem. Commun. 2003, 278-279.
22. (a) Avarvari, N.; LeFloch, P.; Mathey, F. J. Am. Chem. Soc. 1998, 118, 11978-11979.
23. (b) Avarvari, N.; LeFloch, P.; Ricard, L.; Mathey, F. Organometallics 1997, 16, 4089-4098.
24. Parr, R. G.; Yang, W. Density Functional Theory of Atoms and Molecules; Oxford University Press: Oxford, U.K., 1989.
25. Ziegler, T. Chem. Rev. 1991, 91, 651-667.
26. (a) Becke, A. D. Phys. Rev. A 1988, 38, 3098-3108.
27. (b) Perdew, J. P. Phys. Rev. B 1986, 33, 8822-8832.
28. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. J. A.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Baboul, A. G.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Challacombe, M.; Gill, P. M. W.; Johnson, B.; Chen, W.; Wong, M. W.; Andres, J. L.; Gonzalez, C.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. In Gaussian 98, revision A-11; Gaussian, Inc.: Pittsburgh, PA, 1998.
29. Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299-310.
30. (a) Hehre, W. J.; Ditchfield, R.; Pople, J. A. J. Chem. Phys. 1972, 56, 2257.
31. (b) Harihara, P.; Pople, J. A. Theor. Chim. Acta 1973, 28, 213-222.
32. (c) Francl, M. M.; Pietro, W. J.; Hehre, W. J.; Binkley, J. S.; Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654-3665.
33. Altomare, A.; Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A.; Moliterni, A. G. G.; Polidori, G.; Spagna, R. SIR97, an integrated package of computer programs for the solution and refinement of crystal structures using single-crystal data.
34. Sheldrick, G. M. SHELXL-97; Universität Göttingen: Göttingen, Germany, 1997.
35. Farrugia, L. J. ORTEP-3; Department of Chemistry: University of Glasgow.