Highly selective isomerization of allyloxyalcohols to cyclic acetals or 1-propenyloxyalcohols

Synlett

Volumn , Issue 7, 2004, Pages 1203-1206

  Urbala, Magdalena ^a   Kuźnik, Nikodem ^b   Krompiec, Stanisław ^b   Rzepa, Józef ^c  

^a WEST POMERANIAN UNIVERSITY OF TECHNOLOGY   (Poland)

^b SILESIAN UNIVERSITY OF TECHNOLOGY   (Poland)

^c UNIVERSITY OF SILESIA   (Poland)

Author keywords

Acetals; Cyclization; Isomerizations; Ruthenium complexes; Vinyl ethers

Indexed keywords

ACETAL DERIVATIVE; ALCOHOL DERIVATIVE; PROPANE; RHODIUM COMPLEX; RUTHENIUM COMPLEX;

ARTICLE; CYCLIZATION; ISOMERIZATION;

EID: 2942706179     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-825597     Document Type: Article

References (24)

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20. x} (10 mg, 0.04 mmol) and tri(2,4,6-trimethoxyphenylphosphine) (19 mg, 0.04 mmol) were heated at 100°C in THF (2 mL) for 3 h, then 2-allyloxy-ethanol 1a (0.77 g, 7.6 mmol) was added and heated at 80°C for 3 h. Then, solvent was removed and the crude turned out to get the mixture of cyclic product 1c and (E)-2-(1-propenyloxy)ether 1b - NMR analysis.
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