Operating strategies for Fischer-Tropsch reactors: A model-directed study

Korean Journal of Chemical Engineering

Volumn 21, Issue 2, 2004, Pages 308-317

  Song, Hyun Seob ^c   Ramkrishn, Doraiswami ^a   Trinh, Sinh ^b   Wright, Harold ^b  

^a PURDUE UNIVERSITY   (United States)

^b Phillips Research Center 224GB   (United States)

^c LG Chemical Ltd   (South Korea)

Author keywords

Conversion; Fischer Tropsch (FT) Synthesis; Multiplicity; Selectivity; Stability; Start up Strategy

Indexed keywords

CARBON MONOXIDE; CATALYSTS; FISCHER-TROPSCH SYNTHESIS; HEAT TRANSFER; MASS TRANSFER; REACTION KINETICS;

CONVERSION; MULTIPLICITY; SELECTIVITY; START UP ENERGY;

CHEMICAL REACTORS;

EID: 2942670828     PISSN: 02561115     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02705414     Document Type: Article

References (16)

1. Adesina, A.A., "Hydrocarbon Synthesis via Fischer-Tropsch Reaction: Travails and Triumphs," Appl. Catal. A: General, 138, 345 (1996).
2. Adesina, A. A., Hudgins, R. R. and Silveston, P. L., "Fischer-Tropsch Synthesis Under Periodic Operation," Catal Today, 25, 127 (1995).
3. 3," Chem. Eng. Commun., 43, 39 (1986).
4. Bhattacharjee, S., Tiemey, J. W. and Shah, Y. T., "Thermal Behavior of a Slurry Reactor: Application to Synthesis Gas Conversion" Ind. Eng. Chem. Process Des. Dev., 25, 117 (1986).
5. Kirillov, V. A., Khanaev, V. M., Meshcheryakov, D., Fadeev, S. I. and Lukyanova, R. G., "Numerical Analysis of Fischer-Tropsch Processes in Reactors with a Slurried Catalyst Bed," Theor. Found. Chem. Eng., 33, 270 (1999).
6. Lox, E. S. and Froment, G. F., "Kinetics of the Fischer-Tropsch Reaction on a Precipitated Promoted Iron Catalysts. 2. Kinetic Modeling," Ind. Eng. Chem. Res., 32, 71 (1993).
7. Maretto, C. and Krishna, R., "Modelling of a Bubble Column Slurry Reactor for Fischer-Tropsch Synthesis," Catal. Today, 52, 279 (1999).
8. Russo, L. P. and Bequette, B. W., "Impact of Process Design on the Multiplicity Behavior of a Jacketed Exothermic CSTR," AIChE J., 41, 135 (1995).
9. Shah, Y. T., Dassori, C. G. and Tierney, J. W., "Multiple Steady States in Non-isothermal FT Slurry Reactor," Chem. Eng. Commun., 88, 49 (1990).
10. Sie, S. T., "Process Development and Scale Up: IV. Case History of the Development of a Fischer-Tropsch Synthesis Process," Rev. Chem. Eng., 14, 109 (1998).
11. Song, H.-S., Ramkrishna, D., Trinh, S. and Wright, H., "Diagnostic Nonlinear Analysis of Fischer-Tropsch Synthesis in Stirred Tank Slurry Reactors," AIChE J., 49, 1803 (2003a).
12. Song, H.-S., Ramkrishna, D., Trinh, S., Espinoza, R. L. and Wright, H., "Multiplicity and Sensitivity Analysis of Fischer-Tropsch Bubble Column Slurry Reactors: Plug-Flow Gas and Well-Mixed Slurry Model," Chem. Eng. Sci., 58, 2759 (2003b).
13. Stern, D., Bell, A. T. and Heinemann, H., "A Theoretical Model for the Performance of Bubble-Column Reactors Used for Fischer-Tropsch Synthesis," Chem. Eng. Sci., 40, 1665 (1985).
14. Van Der Vaan, G. P. and Beenackers, A. A. C. M., "Kinetics and Selectivity of the Fischer-Tropsch Synthesis: A Literature Review", Catal. Rev. Sci. Eng., 41, 255 (1999).
15. Withers, H. P., Eliezer, K. F. and Mitchell, J. W., "Slurry-Phase Fischer-Tropsch Synthesis and Kinetic Studies over Supported Cobalt Carbonyl Derived Catalysis," Ind. Eng. Chem. Res., 29, 1807 (1990).
16. Yermakova, A. and Anikeev, V. I., "Thermodynamic Calculations in the Modeling of Multiphase Processes and Reactors," Ind. Eng. Chem. Res., 39, 1453 (2000).