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Volumn 304, Issue 5677, 2004, Pages 1639-1644

Fluctuations and bistabilities on catalyst nanoparticles

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; MOLECULAR BEAMS;

EID: 2942657818     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1097513     Document Type: Article
Times cited : (148)

References (41)
  • 2
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    • A. T. Bell, Science 299, 1688 (2003).
    • (2003) Science , vol.299 , pp. 1688
    • Bell, A.T.1
  • 5
    • 0035900417 scopus 로고    scopus 로고
    • T. W. Hansen et al., Science 294, 1508 (2001).
    • (2001) Science , vol.294 , pp. 1508
    • Hansen, T.W.1
  • 22
    • 2942641507 scopus 로고    scopus 로고
    • note
    • Both supports used, alumina and silica, interact only weakly with the Pd metal. Hence, effects due to electronic interaction with the support are expected to be weak for the three-dimensional nanoparticles under investigation. Differences in the adsorption and reaction behavior are mainly related to the intrinsically modified electronic structure of the small metal particles or to geometric effects.
  • 38
    • 2942656607 scopus 로고    scopus 로고
    • note
    • In previous angle-resolved experiments, we have shown that surface diffusion of both adsorbed O and CO is fast for model systems II (6 nm) and III (1.8 nm) (39). These findings justify the application of a pure mean-field model, in contrast to the case of reduced oxygen diffusion, which would require the application of Monte Carlo or hybrid methods (20).
  • 41
    • 2942695516 scopus 로고    scopus 로고
    • note
    • We acknowledge the support of the Deutsche Forschungsgemeinschaft and of the Competence Center for Catalysis at Chalmers, supported by the Swedish Energy Administration, Chalmers, and its member companies: AB Volvo, Johnson Matthey CSD, Saab Automobile Powertrain AB, Persorp AB, MTC AB, Eka Chemicals, and the Swedish Space Administration. C.R.H. thanks the Alexander-von-Humboldt Foundation for a senior scientist award. We thank G. Weinberg (FHI) for the SEM images of the lithographically prepared model catalyst.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.