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In previous angle-resolved experiments, we have shown that surface diffusion of both adsorbed O and CO is fast for model systems II (6 nm) and III (1.8 nm) (39). These findings justify the application of a pure mean-field model, in contrast to the case of reduced oxygen diffusion, which would require the application of Monte Carlo or hybrid methods (20).
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We acknowledge the support of the Deutsche Forschungsgemeinschaft and of the Competence Center for Catalysis at Chalmers, supported by the Swedish Energy Administration, Chalmers, and its member companies: AB Volvo, Johnson Matthey CSD, Saab Automobile Powertrain AB, Persorp AB, MTC AB, Eka Chemicals, and the Swedish Space Administration. C.R.H. thanks the Alexander-von-Humboldt Foundation for a senior scientist award. We thank G. Weinberg (FHI) for the SEM images of the lithographically prepared model catalyst.
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