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Volumn 23, Issue 11, 2004, Pages 2568-2572

Alkyl transfer reactivity in the first octahedral isocyanide complex of nickel(II)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE COUPLED DEVICES; CHEMICAL ACTIVATION; CHEMICAL BONDS; COMPLEXATION; DIFFUSION; ESTERS; INFRARED SPECTROSCOPY; ORGANOMETALLICS; OXIDATION; REDUCTION; X RAY CRYSTALLOGRAPHY;

EID: 2942618771     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0343364     Document Type: Article
Times cited : (6)

References (26)
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    • One reviewer asked for an explanation: when isocyanides are coordinated to a monopositive or dipositive metal ion such as Cr(0) or Ni(0), little or no back-donation occurs, and the CN stretching band is shifted to a higher frequency as a result of the inductive effect of the metal. When isocyanides are coordinated to zero-valent metals, back-donation is extensive and the CN stretching band is shifted to lower frequency. See: Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997; Part B (Applications in Coordination, Organometallic, and Bioinorganic Chemistry), p 115. Cotton, F. A.; Zingales, F. J. Am. Chem. Soc. 1961, 83, 351.
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    • One reviewer asked for an explanation: when isocyanides are coordinated to a monopositive or dipositive metal ion such as Cr(0) or Ni(0), little or no back-donation occurs, and the CN stretching band is shifted to a higher frequency as a result of the inductive effect of the metal. When isocyanides are coordinated to zero-valent metals, back-donation is extensive and the CN stretching band is shifted to lower frequency. See: Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997; Part B (Applications in Coordination, Organometallic, and Bioinorganic Chemistry), p 115. Cotton, F. A.; Zingales, F. J. Am. Chem. Soc. 1961, 83, 351.
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    • One reviewer asked for an explanation: when isocyanides are coordinated to a monopositive or dipositive metal ion such as Cr(0) or Ni(0), little or no back-donation occurs, and the CN stretching band is shifted to a higher frequency as a result of the inductive effect of the metal. When isocyanides are coordinated to zero-valent metals, back-donation is extensive and the CN stretching band is shifted to lower frequency. See: Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; Wiley: New York, 1997; Part B (Applications in Coordination, Organometallic, and Bioinorganic Chemistry), p 115. Cotton, F. A.; Zingales, F. J. Am. Chem. Soc. 1961, 83, 351.
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