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Volumn 37, Issue 11, 2004, Pages 4283-4295

Phase diagram of random copolymer melts: A computer simulation study

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; CONFORMATIONS; CORRELATION METHODS; MARKOV PROCESSES; MICROEMULSIONS; MONOMERS; MONTE CARLO METHODS; ORDER DISORDER TRANSITIONS; PHASE DIAGRAMS; POLYMERIZATION; RELAXATION PROCESSES;

EID: 2942532496     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma035814p     Document Type: Article
Times cited : (49)

References (45)
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    • Ginzburg, V. L. Sov. Phys. Solid State 1960, 1, 1824. de Gennes, P. G. J. Phys. Lett. (Paris) 1977, 38, L-441. Joanny, J. F. J. Phys. A1978, 11, L-117. Binder, K Phys. Rev. A 1984, 29, 341.
    • (1978) J. Phys. A , vol.11
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    • note
    • Q) that even experimental samples might not be large enough to contain each species in a large number. Of course, this hold a fortiori for finite size simulation cells (cf. section III.C).
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    • Carmesin, I.1    Kremer, K.2
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    • note
    • 33 End a small minimum in the binding potential at finite D over the entire range of incompatibility, leading to a three-phase coexistence between a lamellar phase and two homopolymer-rich phases. The minimum is, however, so weak that thermal fluctuations can easily overcome this minimum, and therefore, it is immaterial for our Monte Carlo results.


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