Polar open-framework structure, optical properties, and electron paramagnetic resonance of the mixed-metal uranyl phosphate Cs 2[UO 2(VO 2) 2(PO 4) 2]·0.59H 2O

Chemistry of Materials

Volumn 17, Issue 25, 2005, Pages 6219-6222

  Shvareva, Tatiana Y ^a   Beitz, James V ^b   Duin, Evert C ^a   Albrecht Schmitt, Thomas E ^a  

^a AUBURN UNIVERSITY   (United States)

^b ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

URANYL PHOSPHATE; YELLOW CRYSTALS;

CESIUM COMPOUNDS; CRYSTALLINE MATERIALS; HYDROTHERMAL SYNTHESIS; MOLECULAR STRUCTURE; OPTICAL PROPERTIES; PARAMAGNETIC RESONANCE; SECOND HARMONIC GENERATION;

URANIUM COMPOUNDS;

EID: 29344476178     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm052079i     Document Type: Article

References (28)

1. Hutchings, G. J.; Heneghan, C. S.; Hudson, I. D.; Taylor, S. H. Nature 1996, 384, 341.
2. Pollington, S. D.; Lee, A. F.; Overton, T. L.; Sears, P. J.; Wells, P. B.; Hawley, S. E.; Hudson, I. D.; Lee, D. F.; Ruddock, V. Chem. Commun. 1999, 8, 725.
3. Sykora, R. E.; King, J.; Illies, A.; Albrecht-Schmitt, T. E. J. Solid State Chem. 2004, 177, 1717.
4. Sykora, R. E.; Albrecht-Schmitt, T. E. Inorg. Chem. 2003, 42, 2179.
5. Almond, P. M.; Albrecht-Schmitt, T. E. Inorg. Chem. 2002, 41, 1177.
6. Shvareva, T. Y.; Sullens, T. A.; Shehee, T. C.; Albrecht-Schmitt, T. E. Inorg. Chem. 2005, 44, 300.
7. Obbade, S.; Dion, C.; Rivenet, M.; Saadi, M.; Abraham, F. J. Solid State Chem. 2004, 177, 2058.
8. Pichot, E.; Dacheux, N.; Brandel, V.; Genet, M. New J. Chem. 2000, 24, 1017.
9. Burns, P. C.; Miller, M. L.; Ewing, R. C. Can. Mineral. 1996, 34, 845.
10. Burns, P. C. Can. Mineral. 2005, in press.
11. Sullens, T. A.; Jensen, R. A.; Shvareva, T. Y.; Albrecht-Schmitt, T. E. J. Am. Chem. Soc. 2004, 126, 2676.
12. Krivovichev, S. V.; Armbruster, Th.; Chernyshov, D. Y.; Burns, P. C.; Nazarchuk, E. V.; Depmeier, W. Micropor. Mesopor. Mater. 2005, 78, 225.
13. Krivovichev, S. V.; Cahill, C. L.; Nazarchuk, E. V.; Burns, P. C.; Armbruster, Th.; Depmeier, W. Micropor. Mesopor. Mater. 2005, 78, 209.
14. Doran, M. B.; Stuart, C. L.; Norquist, A. J.; O'Hare, D. Chem. Mater. 2004, 16, 565.
15. Krivovichev, S. V.; Burns, P. C.; Armbruster, Th.; Nazarchuk, E. V.; Depmeier, W. Micropor. Mesopor. Mater. 2005, 78, 217.
16. 2O were isolated, washed with methanol, and allowed to dry. Yield, 515 mg (quantitative yield based on U). Energy-dispersive X-ray analysis provided a Cs:U:V:P ratio of 2/1/2/2.
17. Calin, N.; Serre, C.; Sevov, S. C. J. Mater. Chem. 2003, 13, 531.
18. 2 was by full-matrix least-squares, and there were 105 parameters.
19. (b) Sheldrick, G. M. SHELXTL PC, Version 6.12; an integrated system for solving, refining, and displaying crystal structures from diffraction data; Siemens Analytical X-Ray Instruments, Inc.: Madison, WI, 2001.
20. Guesdon, A.; Charon, J.; Provost, J.; Raveau, B. J. Solid State Chem. 2002, 165, 89.
21. (a) Masse, R.; Grenier, J. C. Bull. Soc. Fr. Mineral. Cristallogr. 1971, 94, 437.
22. (b) Tordjman, I.; Masse, R.; Guitel, J. C. Z. Kristallogr., Kristallgeom., Kristallphys., Kristallchem. 1974, 139, 103.
23. Burns, P. C.; Ewing, R. C.; Hawthorne, F. C. Can. Mineral. 1997, 35, 1551.
24. Brese, N. E.; O'Keefe, M. Acta Crystallogr., Sect. B 1991, 47, 192.
25. Brown, I. D.; Altermatt, D. Acta Crystallogr., Sect. B 1985, 41, 244.
26. 2, the SHG intensity from UVP-1 was 1500 times weaker that the signal observed from a commercial rare-earth-based ceramic frequency upconverting laser beam finder (Kentek View-It).
27. EPR spectra at X-band (9.4 GHz) were obtained with a Bruker EMX-6/1 EPR spectrometer composed of the EMX-113 console, ER-041-XG bridge with built-in microwave frequency counter, ER-070 magnet, and ER-4119-HS, high-sensitivity perpendicular-mode cavity. All spectra were recorded with a field modulation frequency of 100 kHz. All samples studied were polycrystalline in nature.
28. Garces, N. Y.; Stevens, K. T.; Foundos, G. K.; Halliburton, L. E. J. Phys.: Condens. Matter. 2004, 16, 7095.