The high-valent iron-oxo species of polyoxometalate, if it can be made, will be a highly potent catalyst for C-H hydroxylation and double-bond epoxidation

Journal of the American Chemical Society

Volumn 127, Issue 50, 2005, Pages 17712-17718

  Kumar, Devesh ^a   Derat, Etienne ^a   Khenkin, Alexander M ^b   Neumann, Ronny ^b   Shaik, Sason ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

^b WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; CHEMICAL BONDS; HYDROXYLATION; OXYGEN; PROBABILITY DENSITY FUNCTION; PROPYLENE;

IRON-OXO REAGENT; KEGGIN SPECIES; OXIDATIVE REACTIVITY; OXYGEN DONOR;

CATALYSTS;

CYTOCHROME P450; IRON; OXIDIZING AGENT; PROPYLENE;

ARTICLE; CATALYST; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; ENERGY; EPOXIDATION; HYDROXYLATION; OXIDATION;

EID: 29344436797     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0542340     Document Type: Article

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