Synthesis, characterization, and reactivity of the first hafnium alkyl complex stabilized by amidate ligands

Canadian Journal of Chemistry

Volumn 83, Issue 6-7, 2005, Pages 1037-1042

  Thomson, Robert K ^a   Patrick, Brian O ^a   Schafer, Laurel L ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

Amidate; Coordination chemistry; Exchange processes; Hafnium; Organometallic chemistry; Protonolysis

Indexed keywords

COMPLEXATION; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE; ORGANOMETALLICS; X RAY CRYSTALLOGRAPHY;

AMIDATE; COORDINATION CHEMISTRY; EXCHANGE PROCESS; PROTONOLYSIS;

HAFNIUM COMPOUNDS;

ALKYL GROUP; AMIDE; BENZYL DERIVATIVE; BIS(AMIDATE); COORDINATION COMPOUND; ETOMIDATE; HAFNIUM; LIGAND; N 2,6 DIMETHYLPHENYL(PHENYL)AMIDE; ORGANOMETALLIC COMPOUND; TETRAHYDROFURAN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMISTRY; COLOR; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; HIGH TEMPERATURE; HYDROLYSIS; ISOMERIZATION; LOW TEMPERATURE; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE; PHOTOCHEMISTRY; PROTON TRANSPORT; SOLID STATE; SOLVATION; SYNTHESIS; THERMOSTABILITY; X RAY CRYSTALLOGRAPHY;

EID: 29244468845     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v05-030     Document Type: Article

References (20)

1. G.J.P. Britovsek, V.C. Gibson, and D.F. Wass. Angew. Chem. Int. Ed. 38, 428 (1999).
2. C. Li, R.K. Thomson, B. Gillon, B.O. Patrick, and L.L. Schafer. Chem. Commun. 2462 (2003).
3. Z. Zhang and L.L. Schafer. Org. Lett. 5, 4733 (2003).
4. R.K. Thomson, F.E. Zahariev, Z. Zhang, B.O. Patrick, Y.A. Wang, L.L. Schafer. Inorg. Chem. In press.
5. R. Kempe. Angew. Chem. Int. Ed. 39, 468 (2000).
6. J.R. Hagadorn and J. Arnold. J. Am. Chem. Soc. 118, 893 (1996).
7. P. Bazinet, D. Wood, G.P.A. Yap, and D.S. Richeson. Inorg. Chem. 42, 6225 (2003).
8. K. Matsumoto, A. Watanabe, T. Uchida, K. Ogi, and T. Katsuki. Tetrahedron Lett. 45, 2385 (2004).
9. R.B. VonDreele, J.J. Stezowski, and R.C. Fay. J. Am. Chem. Soc. 93, 2887 (1971).
10. S.L. Hawthorne and R.C. Fay. J. Am. Chem. Soc. 101, 5268 (1979).
11. W.L. Steffen, H.K. Chun, and R.C. Fay. Inorg. Chem. 17, 3498 (1978).
12. Q.F. Mokuolu, P.A. Duckmanton, P.B. Hitchcock, C. Wilson, A.J. Blake, L. Shukla, and J.B. Love. Dalton Trans. 1960 (2004).
13. H. Friebolin. Basic one- and two-dimensional NMR spectroscopy. 2nd ed. VCH, Toronto. 1993. pp. 287-298.
14. U. Zucchini, E. Albizzati, and U. Giannini. J. Organomet. Chem. 36, 357 (1972).
15. Molecular Structure Corp. teXsan for Windows [computer program]. Molecular Structure Corp., The Woodlands, Texas. 1996.
16. A. Altomane, M.C. Burla, G. Cammali, M. Cascarano, C. Giacovazzo, A. Gagliardi, A.G.G. Moliterni, G. Polidoi, and A. Spagna. SIR-97 [computer program]. CNR-IRMEC, Universitario, Bari, Italy. 1999.
17. P.T. Beurkens, G. Admiraal, G. Baurskens, W.P. Bosman, R. de Gelder, R. Israel, and J.M.M. Smits. DIRDIF-94 [computer program]. University of Nijmegen, Nijmegen, The Netherlands. 1994.
18. International Union of Crystallography. International tables for X-ray crystallography. Kynoch Press, Birmingham, UK. 1974.
19. International Union of Crystallography. International tables for X-ray crystallography. Kluwer Academic, Boston, Mass. 1992.
20. L.J. Farrugia. J. Appl. Crystallogr. 30, 565 (1997).