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Volumn 83, Issue 6-7, 2005, Pages 1006-1016

Pauson-khand reactions in water

Author keywords

Alkyne; Cycloaddition; Green chemistry; Pauson khand reaction; Water

Indexed keywords

CARBOXYLIC ACIDS; COBALT; DETERGENTS; HYDROLYSIS; SURFACE ACTIVE AGENTS; THERMAL EFFECTS; WATER;

EID: 29244443370     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v05-112     Document Type: Article
Times cited : (11)

References (54)
  • 10
    • 0003826570 scopus 로고    scopus 로고
    • Oxford University Press, Oxford
    • Development of cost-effective, safe, and environmentally benign organic processes has been an increasing research focus. (a) P. Tundo and P.T. Anastas. Green chemistry: Challenging perpectives. Oxford University Press, Oxford. 2000;
    • (2000) Green Chemistry: Challenging Perpectives
    • Tundo, P.1    Anastas, P.T.2
  • 17
    • 0008924882 scopus 로고    scopus 로고
    • Edited by M. Harmata. JAI Press Inc., Greenwich, Connecticut
    • (c) K.M. Brummond. In Advances in cycloaddition chemistry. Vol 6. Edited by M. Harmata. JAI Press Inc., Greenwich, Connecticut. 1999. p. 211.
    • (1999) Advances in Cycloaddition Chemistry , vol.6 , pp. 211
    • Brummond, K.M.1
  • 27
    • 0000316894 scopus 로고
    • Edited by E.W. Abel, F.A. Stone, and G. Wilkinson. Pergamon Press, Oxford
    • (b) R.D.W. Kemmitt and D.R. Russell. In Comprehensive organometallic chemistry. Vol 5. Edited by E.W. Abel, F.A. Stone, and G. Wilkinson. Pergamon Press, Oxford. 1982. p. 7.
    • (1982) Comprehensive Organometallic Chemistry , vol.5 , pp. 7
    • Kemmitt, R.D.W.1    Russell, D.R.2
  • 28
    • 0032556207 scopus 로고    scopus 로고
    • 3, has been exploited by the Sugihara laboratory. For Pauson-Khand reactions: (a) T. Sugihara and M. Yamaguchi. J. Am. Chem. Soc. 120, 10 782 (1998);
    • (1998) J. Am. Chem. Soc. , vol.120 , Issue.10 , pp. 782
    • Sugihara, T.1    Yamaguchi, M.2
  • 38
    • 0031936070 scopus 로고    scopus 로고
    • 12 in the PK reaction was also briefly mentioned in a reaction using supercritical fluid (3).
    • (1998) Synthesis , pp. 142
    • Kim, J.W.1    Chung, Y.K.2
  • 42
    • 4644324093 scopus 로고    scopus 로고
    • For a review of side reactions observed under the PK reaction conditions, see: (a) L.V.R. Boñaga and M.E. Krafft. Tetrahedron, 60, 9795 (2004).
    • (2004) Tetrahedron , vol.60 , pp. 9795
    • Boñaga, L.V.R.1    Krafft, M.E.2
  • 50
    • 0346461917 scopus 로고    scopus 로고
    • Cyclodextrins (CD) are cyclic oligosaccharides consisting of six (α-CD), seven (β-CD), and eight (γ-CD) glucopyranose units and possessing both hydrophilic and hydrophobic sites. The cyclodextrin cavity is slightly apolar so that when it is occupied by polar water molecules it can be energetically unfavorable. Because of this negative interaction, the water molecules can be substituted by the less polar molecules in a host-guest manner. The cyclodextrin molecule usually can trap one guest molecule so that it can theoretically improve the normally unfavorable environment that exists with a poorly soluble molecule and the aqueous solution. The reactivity of the trapped molecule can either decreased because of stabilization or be enhanced in other cases. For a background on cyclodextrins, see: J. Szejtli. Chem. Rev. 98, 1743 (1998).
    • (1998) Chem. Rev. , vol.98 , pp. 1743
    • Szejtli, J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.