Polymerization of n-hexyl isocyanate with CpTiCl2(OR) (R = functional group or macromolecular chain): A route to ω-functionalized and block copolymers and terpolymers of n-hexyl isocyanate

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 43, Issue 24, 2005, Pages 6503-6514

  Mourmouris, Stylianos ^a   Kostakis, Konstantinos ^a   Pitsikalis, Marinos ^a   Hadjichristidis, Nikos ^a  

^a UNIVERSITY OF ATHENS   (Greece)

Author keywords

Anionic polymerization; Catalytic polymerization; Copolymers; Differential scanning calorimetry (DSC); N hexyl isocyanate; NMR; Size exclusion chromatography (SEC); Terpolymers

Indexed keywords

ANIONIC POLYMERIZATION; DIFFERENTIAL SCANNING CALORIMETRY; ESTERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REFRACTIVE INDEX; SIZE EXCLUSION CHROMATOGRAPHY; TERPOLYMERS;

CATALYTIC POLYMERIZATION; ISOPRENE; N-HEXYL ISOCYANATE;

BLOCK COPOLYMERS;

EID: 29144514612     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.21129     Document Type: Article

References (48)

1. (a) Wu, J.; Pearce, E. M.; Kwei, T. K.; Lefebvre, A. A.; Balsara, N. P. Macromolecules 2002, 35, 1791;
2. (b) Jenekhe, S. A.; Chen, X. L. Science 1998, 279, 1903;
3. (c) Loos, K.; Stadler, R. Macromolecules 1997, 30, 7641;
4. (d) Kukula, H.; Ziener, U.; Schöps, M.; Godt, A. Macromolecules 1998, 31, 5160;
5. (e) Cornelisen, J. J. L. M.; Fischer, M.; Somerdijk, N. A. J. M.; Nolte, R. J. M. Science 1998, 280, 1427;
6. (f) Lee, M.; Oh, N. K.; Lee, H. K.; Zin, W. C. Macromolecules 1996, 29, 5567;
7. (g) Radzilowski, L. H.; Stupp, S. I. Macromolecules 1994, 27, 7747.
8. (a) Schneider, N. S.; Furusaki, S.; Lenz, R. W. J Polym Sci Part A: Polym Chem 1965, 3, 933;
9. (b) Troxell, T. C.; Scheraga, H. A. Macromolecules 1971, 4, 519;
10. (c) Yu, H.; Bur, A. J.; Fetters, L. J. J Chem Phys 1966, 44, 2568;
11. (d) Bur, A. J.; Fetters, L. J. Macromolecules 1973, 6, 874.
12. (a) Chen, J. T.; Thomas, E. L.; Ober, C. K.; Hwang, S. S. Macromolecules 1995, 28, 1688;
13. (b) Chen, J. T.; Thomas, E. L.; Ober, C. K.; Mao, G.-P. Science 1996, 273, 343.
14. (a) Maxein, G.; Mayer, S.; Zentel, R. Macromolecules 1999, 32, 5747;
15. (b) Itou, T.; Teramoto, A. Macromolecules 1988, 21, 2225;
16. (c) Aharoni, S. M. Macromolecules 1979, 12, 94;
17. (d) Green, M. M.; Gross, R. A.; Crosby, C., III; Schilling, F. C. Macromolecules 1987, 20, 992;
18. (e) Green, M. M.; Khatri, C. A.; Reidy, M. P.; Levon, K. Macromolecules 1993, 26, 4713;
19. (f) Muller, M.; Zentel, R. Macromolecules 1993, 26, 4723;
20. (g) Maeda, K.; Okamoto, Y. Macromolecules 1998, 31, 1046.
21. Bur, A. J.; Fetters, L. J. Chem Rev 1976, 76, 727.
22. (a) Shashoua, V. E.; Sweeney, W.; Tietz, R. J. J Am Chem Soc 1960, 82, 866;
23. (b) Shashoua, V. E. J Am Chem Soc 1959, 81, 3156.
24. (a) Aharoni, S. M. J Polym Sci Polym Phys Ed 1980, 18, 1439;
25. (b) Nakatsuji, M.; Ogata, Y.; Yoshizaki, T.; Yamakawa, H. Macromolecules 2001, 31, 8512;
26. (c) Mayer, S.; Zentel, R. Macromol Chem Phys 1998, 199, 1675;
27. (d) Müler, M.; Zentel, R. Macromolecules 1996, 29, 1609.
28. (a) Natta, G.; DiPietro, J.; Cambini, M. Macromol Chem 1964, 72, 202;
29. (b) Fetters, L. J.; Yu, H. Macromolecules 1971, 4, 358;
30. (c) Maeda, K.; Okamoto, Y Macromolecules 1999, 32, 974.
31. (a) Shin, Y. D.; Kim, S. Y.; Ahn, J. H.; Lee, J. S. Macromolecules 2001, 34, 2408;
32. (b) Lee, J. S.; Ryu, S. W. Macromolecules 1999, 32, 2085;
33. (c) Ahn, J.-H.; Shin, Y.-D.; Yogendra Nath, G.; Park, S.-Y; Shahinur Rahman, M.; Samal, S.; Lee, J.-S. J Am Chem Soc 2005, 127, 4132.
34. Zorba, G.; Vazaios, A.; Pitsikalis, M.; Hadjichristidis, N. J Polym Sci Part A: Polym Chem 2005, 43, 3533.
35. Shin, Y. D.; Han, S. H.; Samal, S.; Lee, J. S. J Polym Sci Part A: Polym Chem 2005, 43, 607.
36. Vazaios, A.; Pitsikalis, M.; Hadjichristidis, N. J Polym Sci Part A: Polym Chem 2003, 41, 3094.
37. (a) Patten, T. E.; Novak, B. M. J Am Chem Soc 1996, 118, 1906;
38. (b) Patten, T. E.; Novak, B. M. J Am Chem Soc 1991, 113, 5065.
39. Wu, J.; Pearce, E. M.; Kwei, T. K. Macromolecules 2001, 34, 1828.
40. Hoff, S. M.; Novak, B. M. Macromolecules 1993, 26, 4067.
41. Hadjichristidis, N.; Iatrou, H.; Pispas, S.; Pitsikalis, M. J Polym Sci Part A: Polym Chem 2000, 38, 3211.
42. Quirk, R. P.; Ma, J. J. J Polym Sci Part A: Polym Chem 1988, 26, 2031.
43. (a) Freidzon, Y. S.; Kharitonov, A. V.; Shibaev, V. P.; Platé, N. A. Mol Cryst Liq Cryst 1982, 88, 87;
44. (b) Shannon, P. J. Macromolecules 1983, 16, 1677.
45. (a) Spier, H. L.; van Senden, K. G. Steroids 1965, 6, 871;
46. (b) van Putte, K. W.; Petroni, M. Chem Phys Lipids 1968, 2, 361;
47. (c) Loomis, C. R.; Shipley, G. G.; Small, D. M. J Lipid Res 1979, 20, 525.
48. Mano, J. F.; Corrcia, N. T.; Ramos, J. J. M. J Chem Soc Faraday Trans 1995, 91, 2003.