Metallosurfactants of Cu(II) and Fe(III) complexes as catalysts for the destruction of paraoxon

Journal of Surfactants and Detergents

Volumn 8, Issue 4, 2005, Pages 359-363

  Hafiz, A A ^a,b  

^a Egyptian Petroleum Research Institute   (Egypt)

^b EGYPTIAN PETROLEUM RESEARCH INSTITUTE   (Egypt)

Author keywords

Catalytic destruction; Metallosurfactants; Paraoxon; Stability constant

Indexed keywords

CATALYSTS; COMPLEXATION; COPPER; ESTERS; IRON; RATE CONSTANTS;

CATALYTIC DESTRUCTION; METALLOSURFACTANTS; PARAOXON; STABILITY CONSTANT;

SURFACE ACTIVE AGENTS;

EID: 29144497055     PISSN: 10973958     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11743-005-0369-8     Document Type: Article

References (24)

1. Menger, F.M., L.H. Gan, E. Johnson, and D.H. Durst, Phosphate Ester Hydrolysis Catalyzed by Metallomicelles, J. Am. Chem. Soc. 109:2800 (1987).
2. Scrimin, P., G. Ghirlanda, P. Tecilla, and R.A. Moss, Comparative Reactivities of Phosphate Ester Cleavages by Metallomicelles, Langmuir 12:6235 (1996).
3. Mancin, F., P. Tecilla, and U. Tonellato, Metallomicelles Made of Ni(II) and Zn(II) Complexes of 2-Pyridinealdoxime-Based Ligands as Catalyst of the Cleavage of Carboxylic Acid Esters, Langmuir 16:227 (2000).
4. Zheng, F., C.-G. Zhan, and R.L. Ornstein, Theoretical Studies of Reaction Pathways and Energy Barriers for Alkaline Hydrolysis of Phosphotriesterase Substrates Paraoxon and Related Toxic Phosphofluoridate Nerve Agents, J. Chem. Soc. Perkin. Trans. 2:2355 (2001).
5. Shaw, R.W., and M.J. Cullinane, Destruction of Military Toxic Materials, in Encyclopedia of Environmental Analysis and Remediation, edited by R.A. Myers, John Wiley & Sons, New York, 1998, Vol. 5, p. 2821.
6. Moss, R.A., and Y. Ihara, Cleavage of Phosphate Esters by Hydroxyl-Functionalized Micellar and Vesicular Reagents, J. Org. Chem. 48:588 (1983).
7. Siqing, C., Z. Xiancheng, M. Xiangguang, and Y. Xiaoqi, Metallomicellar Catalysis Hydrolysis of p-Nitrophenyl Picolinate Catalyzed by Copper(II), Nickel(II), and Zinc(II) Complexes of Long Alkyl Pyridine Ligands in Micellar Solution, J. Colloid Interface Sci. 224:333 (2000).
8. Koča, J., C.-G. Zhan, R.C. Rittenhouse, and R.L. Ornstein, Mobility of the Active Site Bound Paraoxon and Sarin in Zinc-Phosphotriesterase by Molecular Dynamics Simulation and Quantum Chemical Calculation, J. Am. Chem. Soc. 123:817 (2001).
9. Kimura, E., H. Hashimoto, and T. Koike, Hydrolysis of Lipophilic Esters Catalyzed by a Zinc(II) Complex of a Long Alkyl-Pendant Macrocyclic Tetraamine in Micellar Solution, J. Am. Chem. Soc. 118:10963 (1996).
10. Yang, Y.-C. Chemical Detoxification of Nerve Agent VX, Acc. Chem. Res. 32:109 (1999).
11. Bunton, C.A., Chemical Warfare, in Macmillan Encyclopedia of Chemistry, edited by J.J. Lagowski, Simon & Schuster/Macmillan, New York, 1997, Vol. 1, p. 343.
12. Defrank, J.J., Organophosphorous Cholinesterase Inhibitors: Detoxification by Microbial Enzymes, in Applications of Enzyme Biotechnology, edited by J.W. Kelly and T.O. Baldwin, Plenum Press, New York, 1991, p. 165.
13. Heilbronn-Wikstrom, E., Phosphorylated Cholinesterase: Their Formation Reactions and Hydrolysis, Sven. Kem. Tidskr. 77:598 (1965).
14. Moss, R.A., A.T. Kotchevar, B.D. Park, and P. Scrimin, Comparative Reactivities of Phosphotriesters Toward Iodosocarboxylates in Cationic Micelles, Langmuir 12:2200 (1996).
15. Lion, C., J.P. Boukou-Poba, and M. Hedayatullah, Nouveaux décontaminants. Action du Monoperphtalate de Magnesium (MPPM) sur Quelques insecticides et toxiques de Guerre Organo Phosphorees ou Organosulfers, Phosphorus Sulfur Silicon Relat. Elem. 56:213 (1991).
16. Lion, C., M. Hedayatullah, P. Bauer, J.P. Boukou-Poba, and C. Charvy, Nouveaux décontaminants. Destruction de Toxiques organophosphorés ou Soufres par des Peracides Mono-, Bi- et Tricycliques saturés, Bull. Soc. Chim. Belg. 101:249 (1992).
17. Moss, R.A., and H. Morales-Rojas, Kinetics of Cleavage of Thiophosphates and Phosphonothioates by Miceller Iodosocarboxylates and Copper Metallomicelles, Langmuir 16:6485 (2000).
18. 2 Complexes, Langmuir 19:292 (2003).
19. 2 Complexes, Langmuir 19:299 (2003).
20. Johnson, J.Y., Improvement in the Manufacture and Production of Wetting, Cleansing, Dispersing and Like Agents, British Patent 378, 383 (1932).
21. Badawi, A.M., A.A. Hafiz, and H.A. Ibrahim, Catalytic Destruction of Malathion by Metallomicelle Layers, J. Surfact. Deterg. 6:239 (2003).
22. Hafiz, A.A., M.Y. El Awadi, A.M. Badawi, and S.M. Mokhtar, Catalytic Destruction of Paraoxon by Metallomicelle Layers of Co(II) and Cr(III), J. Surfact. Deterg. 8:203 (2005).
23. Sawyer, D., W.E. Heineman, and J. Beebe, Chemistry Experiments for Instrumental Methods, John Wiley & Sons, New York, 1984, p. 4241.
24. Lee, J.D., Concise Inorganic Chemistry, 3rd edn., Van Nostrand Reinhold, London, 1983, p. 103.