Electron delocalisation in a trinuclear copper(II) complex: High-field EPR characterization and magnetic properties of ·Na3[Cu 3(mal)3(H2O)]·8H2O

Dalton Transactions

Volumn , Issue 23, 2005, Pages 3795-3799

  Gautier Luneau, Isabelle ^a,d   Phanon, Delphine ^a,d   Duboc, Carole ^b   Luneau, Dominique ^c   Pierre, Jean Louis ^a  

^a UNIVERSITÉ JOSEPH FOURIER   (France)

^b GRENOBLE HIGH MAGNETIC FIELD LABORATORY   (France)

^c UNIVERSITÉ CLAUDE BERNARD LYON 1   (France)

^d LABORATOIRE DE CRISTALLOGRAPHIE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; EVAPORATION; IONS; MAGNETIC ANISOTROPY; MAGNETIC SUSCEPTIBILITY; X RAY DIFFRACTION;

COPPER IONS; RHOMBIC ANISOTROPY; SPIN DENSITY; TRIANGULAR SYSTEM;

COPPER;

EID: 29144485680     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b506934c     Document Type: Article

References (40)

1. S. Ferrer, J. G. Haasnoot, J. Reedijk, E. Müller, M. Biagini Cingi, M. Lanfranchi, A. M. Manotti Lanfredi and J. Ribas, Inorg. Chem., 2000, 39, 1859.
2. M. P. Suh, M. Y. Han, J. H. Lee, K. S. Min and C. Hyeon, J. Am. Chem. Soc., 1998, 120, 3819.
3. J.-C. Liu, G.-C. Guo, J.-S. Huang and X.-Z. You, Inorg. Chem., 2003, 42, 235.
4. X. Liu, M. P. de Miranda, E. J. L. McInnes, C. A. Kilner and M. A. Halcrow, Dalton Trans., 2004, 59.
5. J. Padilla, D. Gatteschi and P. Chaudhuri, Inorg. Chim. Acta, 1997, 260, 217.
6. (a) R. Clérac, F. A. Cotton, K. R. Dunbar, E. A. Hillard, M. A. Petrukhina and B. W. Smucker, C. R. Acad. Sci. Paris, Chim./Chem., 2001, 4, 315;
7. (b) B. Cage, F. A. Cotton, N. S. Dalal, E. A. Hillard, B. Rakvin and C. M. Ramsey, J. Am. Chem. Soc., 2003, 125, 5270.
8. H. Lopez-Sandoval, R. Contreras, A. Escuer, R. Vicente, S. Bernès, H. Nöth, G. J. Leigh and N. Barba-Behrens, J. Chem. Soc., Dalton Trans., 2002, 2648.
9. Y. Elerman, E. Kavlakoglu, A. Elmali and E. Kendi, Z. Naturforsch., Teil B, 2001, 56, 1123.
10. P. Klüfers, H. Piotrowski and J. Schuhmacher, Z. Anorg. Allg. Chem., 1997, 623, 191.
11. P. V. Bernhardt and P. C. Sharpe, J. Chem. Soc., Dalton Trans., 1998, 1087.
12. A. Mukherjee, I. Rudra, S. G. Naik, S. Ramasesha, M. Nethaji and A. Chakravarty, Inorg. Chem., 2003, 42, 5660.
13. D. Luneau, H. Oshio, H. Okawa and S. Kida, J. Chem. Soc., Dalton Trans., 1990, 2283.
14. S. L. Jain, P. Bhattacharyya, H. L. Milton, A. M. Z. Slavin, J. A. Crayston and J. D. Woollins, Dalton Trans., 2004, 862.
15. G. Kolks, S. J. Lippard and J. V. Waszczak, J. Am. Chem. Soc., 1980, 102, 4832.
16. L. Gutierrez, G. Alzuct, J. A. Real, J. Cano, J. Borras and A. Castineiras, Inorg. Chem., 2000, 39, 3608.
17. M. Gonzalez-Alvarez, G. Alzuet, J. Borras, B. Macias and A. Castineiras, Inorg. Chem., 2003, 42, 2992.
18. J. F. Berry, A. Cotton, P. Lei and C. A. Murillo, Inorg. Chem., 2003, 42, 377.
19. P. de Meester and A. C. Skapski, J. Chem. Soc., Dalton Trans., 1972, 2400.
20. S. P. Yang, Y. Hong, H. M. Chen, F. Zhang, Q.-Q. Chen and X.-B. Yu, Acta Crystallogr., Sect. E, 2004, 60, m582.
21. (a) A. Messerschmidt, A. Rossi, R. Ladenstein, R. Huber, M. Bolognesi, G. Gatti, A. Marchesini, R. Petruzzelli and A. Finazzi-Agro, J. Mol. Biol., 1989, 206, 513;
22. (b) A. Messerschmidt, R. Ladenstein, R. Huber, M. Bolognesi, L. Avigliano, R. Petruzzelli, A. Rossi and A. Finazzi-Agro, J. Mol. Biol., 1992, 224, 179;
23. (c) A. Messerschmidt, H. Luecke and R. Huber. J. Mol. Biol., 1993, 230, 997.
24. (a) E. I. Solomon, M. J. Baldwin and M. D. Lowery, Chem. Rev., 1992, 92, 521;
25. (b) H. R. Holm, P. Kennepohl and E. I. Solomon, Chem. Rev., 1996, 96, 2239;
26. (c) E. I. Solomon, U. M. Sundaran and T. E. Machokin, Chem. Rev., 1996, 96, 2564.
27. D. A. Fenton and H. Okawa, J. Chem. Soc., Dalton Trans., 1993, 1349.
28. T. M. Polyanskaya, V. V. Bakakin and I. I. Zviedre, Zh. Strukt. Khim., 1982, 23, 117.
29. (a) J.-L. Pierre and I. Gautier-Luneau, Biometals, 2000, 13, 91;
30. (b) I. Gautier-Luneau, C. Fouquard, C. Merle, D. Luneau; and J.-L. Pierre, J. Chem. Soc., Dalton Trans., 2001, 2127;
31. I. Gautier-Luneau, C. Merle, D. Phanon, C. Lebrun, F. Biaso, G. Serratrice and J.-L. Pierre, Chem.-Eur. 7, 2005, 11, 2207.
32. B. N. Figgis and D. J. Martin, J. Chem. Soc., Dalton Trans., 1972, 2174.
33. V. H. Crawford, H. W. Richardson, J. R. Wasson, D. J. Hodgson and W. E. Hatfield, Inorg. Chem., 1976, 15, 2107.
34. E. Ruiz, S. Alvarez, A. Rodriguez-Fortea, P. Alemany, Y. Pouillon and C. Massobrio, Magnetism: Molecules to Materials II, ed. J. Miller and M. Drillon, Wiley-VCH Verlag GmbH, Weinheim, Germany, 2001, pp. 227-279.
35. G. Christou, S. P. Perlepes, E. Libby, K. Folting, J. C. Huffman, R. Webb and D. N. Hendrickson, Inorg. Chem., 1990, 29, 3657.
36. O. Kahn, Molecular Magnetism, VCH Publishers, New York, 1993.
37. A. Bencini, C. Benelli, A. Dei and D. Gatteschi, Inorg. Chem., 1985, 24, 695.
38. W. Van Havere and A. T. H. Lenstra, Bull. Soc. Chim. Belg., 1978, 87, 419.
39. TEXSAN, Single crystal Structure Analysis Software, version 1.8, 3200 Research Forest Drive, The Woodlands, TX 77381, 1995.
40. A.-L. Barra, L.-C. Brunel and J.-B. Robert, Chem. Phys. Lett., 1990, 165, 107.