Bridged polysilsesquioxane xerogels functionalizated by amine- and thiol- Groups: Synthesis, structure, adsorption properties

Adsorption

Volumn 11, Issue 5-6, 2005, Pages 501-517

  Dabrowski A ^a   Barczak, M ^a   Stolyarchuk, N V ^b   Melnyk, I V ^b   Zub, Yu L ^b  

^a MARIA CURIE SK ODOWSKA UNIVERSITY   (Poland)

^b INSTITUTE OF SURFACE CHEMISTRY   (Ukraine)

Author keywords

Functionalized bridged; Hybrid materials; Polysilsesquioxane xerogels; Porosity; Sol gel method

Indexed keywords

AMINES; ETHANOL; GELS; HYDROLYSIS; NUCLEAR MAGNETIC RESONANCE; POLYCONDENSATION; POROSITY; SILANES; SOL-GELS; SYNTHESIS (CHEMICAL);

FUNCTIONALIZED BRIDGED; HYBRID MATERIALS; POLYSILSESQUIOXANE XEROGELS; SOL-GEL METHOD;

ADSORPTION;

EID: 29144447597     PISSN: 09295607     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10450-005-5609-0     Document Type: Article

References (31)

1. Aliev, A., D.L. Ou, B. Ormsby, and A.C. Sullivan, "Porous Silica and Polysilsesquioxane with Covalently Linked Phosphonates and Phophonic Acids," J. Mater. Chem., 10, 2758-2764 (2000).
2. Barrett, E.P., L.G. Joyner, and P.P. Halenda, "The Determination of Pore Volume and Area Distributions in Porous Substances. I. Computations from Nitrogen Isotherms," J. Am. Chem. Soc., 73, 373-380 (1951).
3. Brinker, J.C. and G.W. Scherer, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, pp. 21-616, Academic Press, San Diego, 1990.
4. Brunauer, J.S., P.H. Emmet, and E. Teller, "Adsorption of Gases in Multimolecular Layer," J. Am. Chem. Sos., 60, 309-319 (1938).
5. Cerveau, G., R.J.P. Corriu, and E. Framery, "Nanostructured Organic-Inorganic Hybrid Materials: Kinetic Control of the Texture," Chem. Mater., 13, 3373-3388 (2001a).
6. Cerveau, G., R.J.P. Corriu, and E. Framery, "Sol-Gel Process - Influence of Ageing on the Textural Properties of Organosilsesquioxane Materials," J. Mater. Chem., 11, 713-717 (2001b).
7. 2 with Amine Functional Silane Coupling Agents on Glass Fibers," Colloid. Interf. Sci., 96, 69-79 (1983).
8. Dabrowski, A., "Adsorption - From Theory to Practice," Adv. Colloid Interface Sci., 93, 135-224 (2001).
9. Finn, L.P. and I.B. Slinyakova, "Structure and Thermodestruction of Ppolyorganosiloxane Xerogels Using of IR Spectra Data," Koloid. Zh., 37, 723-729 (1975) (Rus.).
10. Gordon, A.J. and R.A. Ford, "The Chemist's Companion," pp. 437-445, Mir, Moscow, 1976.
11. Jurado-Gonzalez, M., D.L. Ou, B. Ormshy, A.C. Sullivan, and J.R.H. Wilson, "A New Solid Acid Catalyst: The First Phosphonate and Phosphonic Acid Functionalised Microporous Polysilsesquioxanes," J. Chem. Soc. Chem. Commun., 12, 67-68 (2001).
12. Lisichkin, G.V., A.Y. Fadeev, A.A. Serdan, P.N. Nesterenko, and P.G. Mingalyov, "Chemistry of Surface Grafted Compounds," G.V. Lisichkin (Ed.), pp. 68-345, Fizmatlit, Moscow, 2003.
13. Loy, D.A., J.P. Carpenter, T.M. Alam, R. Shaltout, P.K. Dorhout, J. Greaves, J.H. Small, and K.J. Shea, "Cyclization Phenomena in the Sol-Gel Polymerization of α, ω-Bis(triethoxysilyl)alkanes and Incorporation of the Cyclic Structures into Network Silsesquioxane Polymers," J. Am. Chem. Soc., 121, 5413-5425 (1999).
14. Loy, D.A. and K.J. Shea, "Bridged Polisilsesquioxanes. Highly Porous Hybrid Organic-Inorganic Materials," Chem. Rev., 95, 1431-1442 (1995).
15. Maciel, G.E., "NMR Characterization of Functionalized Polysiloxanes," in Solid State NMR of Polymers, I. Ando and T. Asakura (Eds.), pp. 923-984, Elsevier, Amsterdam, 1998.
16. 2 Surface Layer," Chemistry, Physics and Technology of Surface, 8, 125-133 (2002).
17. Oviatt, H.W., K.J. Shea, and J.H. Small. "Alkylene-Bridged Silsesquioxane Sol-Gel Synthesis and Xerogel Characterization. Molecular Requirements for Porosity," Chem. Mater., 5, 943-950 (1993).
18. Pilipenko, A.T., E.N. Arendaryuk, O.P. Ryabushko, and L.A. Batkovskaya, "Di-(p-sulfofenyl)-thiocarbazon - Perspective Metallochrome Indicator for Titrametric Determin Metals with a Help of Thiol," Ukr. Khim. Zh., 55, 175-179 (1989) (Ukrain.).
19. Rouquerol, F., J. Rouquerol, and K. Sing, "Adsorbtion by Powders and Porous Solids. Principles, Methodology and Application" pp. 18-20, Academic Press, London, 1999.
20. Shea, K.J. and D.A. Loy, "Bridged Polisilsesquioxanes. Molecular-Engineered Hybrid Organic-Inorganic Materials," Chem. Mater., 13, 3306-3319 (2001).
21. Shea, K.J., D.A. Loy, and O. Webster, "Arylsilsesquioxane Gels and Related Materials. New Hybrids of Organic and Inorganic Networks," J. Am. Chem. Soc., 114, 6700-6710 (1992).
22. Shea, K.J., J. Moreau, D.A. Loy, R.J.P. Corriu, and B. Boury, " Bridged Polysilsesquioxanes. Molecular-Engineering Nanostructured Hybrid Organic-Inorganic Materials," Functional Hybrid Materials, P.Gomez-Romero and C.Sanchez (Eds.), pp. 50-85, Wiley-VCH, Weinheim, 2004.
23. Shvaykovska, N.V., I.V. Melnyk, G.R. Yurchenko, O.K. Matkovskii, and Yu.L. Zub, "Synthesis and Structure-adsorption Characteristics of Bridges Polysilsesquioxanes with Aminopropyl Groups," Chemistry, Physics and Technology of Surface, 10, 80-84 (2004).
24. Slinyakova, I.B. and T.I. Denisova, "Organo-silicon Adsorbents: Synthesis, Properties, Applications," pp. 21-105, Naukova Dumka, Kiev, 1988 (Rus.).
25. Vansant, E.F., P. Van Der Voort, and K.C. Vrancken, Characterization and Chemical Modification of the Silica Surface, pp. 149-381, Elsevier, Amsterdam, 1995.
26. Voronkov, M.G., N.N. Vlasova, and Yu.N. Pozhidaev, "Organosilicon Ion-Exchange and Complexing Adsorbents," Appl. Organometal. Chem., 14, 287-303 (2000).
27. Zaitsev, V.N., "Covplexing Silicas: Synthesis, Structure of Bonded Layer and Surface Chemistry," pp. 163-231, Folio, Khar'kov, 1997 (Rus.).
28. Zaper, A.M. and J.L. Koenig, "Applications of Solid State Carbon-13 NMR Spectroscopy to Chemically Modified Surfaces," Polymer Composites, 6, 156-161 (1985).
29. Zub, Yu.L., Surface Chemistry of New Hybrid Organic-Inorganic Materials, pp. 5-7, D.Sc. Thesis, Institute of Surface Chemistry, NAS of Ukraine, Kyiv, 2002 (Ukraine.).
30. Zub, Yu.L., A.A. Chuiko, and O.V. Stechenko, "Synthesis, Structure and Structure-adsorption Characteristics of Some Polyamonosiloxanes," Reports of NAS of Ukraine, 150-155 (2002) (Ukrain.).
31. Zub, Yu.L. and R.V. Parish, "Functionalized Polysiloxane Sorbents: Preparation, Structure, Properties and Use," Stud. Surf. Sci. Catal., 99, 285-299 (1996).