Enantiospecific synthesis of tricyclo[5.2.1.04,8]decanes via acid catalysed rearrangement of isotwistanes

Tetrahedron Letters

Volumn 47, Issue 3, 2006, Pages 363-366

  Srikrishna, A ^a   Satyanarayana, G ^a   Ravi Kumar, P ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

Allopupukeanane; Isotwistanes; Molecular rearrangement; Pupukeananes

Indexed keywords

ADAMANTANE DERIVATIVE; ALKANE DERIVATIVE; ALLOPUPUKEANANE; HOMOBREXANE; ISOTWISTANE DERIVATIVE; NEOPUPUKEANANE; PUPUKEANANE; TRICYCLO[5.2.1.0 4,8 ]DECANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BIOSYNTHESIS; CATALYSIS; ENANTIOSELECTIVITY;

EID: 28944441292     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.11.008     Document Type: Article

References (14)

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13. -1. Total number of l.s. parameters = 139; R1[I > 2σ(I)] = 0.042 for 2110. Rw[I > 2σ(I)] = 0.099; GOF = 1.093. ORTEP diagram (for clarity hydrogen atoms were omitted) is depicted in Figure 1. Crystallographic data (without structure factors) have been deposited with the Cambridge Crystallographic Data Centre and the depository number is CCDC 275774.
14. The strategy has been further extended to the first enantiospecific total synthesis of allopupukeanones, Srikrishna, A.; Satyanarayana, G. Tetrahedron Lett. 2005, 46, in this issue. DOI:10.1016/j.tetlet.2005.11.009.