Self-organized nanotubular oxide layers on Ti-6Al-7Nb and Ti-6Al-4V formed by anodization in NH4F solutions

Journal of Biomedical Materials Research - Part A

Volumn 75, Issue 4, 2005, Pages 928-933

  Macak, Jan M ^a   Tsuchiya, Hiroaki ^a   Taveira, Luciano ^a   Ghicov, Andrei ^a   Schmuki, Patrik ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Bioactivity; Electrochemistry; Nanotube; Titanium alloy; Titanium dioxide

Indexed keywords

ELECTROCHEMISTRY; ELECTROLYTES; NANOTUBES; POROUS MATERIALS; SCANNING ELECTRON MICROSCOPY; STOICHIOMETRY; TITANIUM ALLOYS; TITANIUM DIOXIDE; X RAY PHOTOELECTRON SPECTROSCOPY;

BIOACTIVITY; ELECTROCHEMICAL TREATMENT; PORE FORMATION;

BIOMATERIALS;

ALLOY; ALUMINUM; AMMONIUM FLUORIDE; BIOMATERIAL; NANOTUBE; NIOBIUM; TITANIUM; TITANIUM DIOXIDE;

ARTICLE; CHANNEL GATING; CRYSTAL STRUCTURE; DISSOLUTION; DRUG ACTIVITY; ELECTROCHEMISTRY; HIP PROSTHESIS; POROSITY; PROSTHESIS MATERIAL; SCANNING ELECTRON MICROSCOPY; STOICHIOMETRY; STRUCTURE ANALYSIS; SURFACE PROPERTY; THICKNESS; TOOTH PROSTHESIS;

FLUORIDES; MICROSCOPY, ELECTRON, SCANNING; NANOTUBES; OXIDES; QUATERNARY AMMONIUM COMPOUNDS; TITANIUM;

EID: 28844508635     PISSN: 00219304     EISSN: None     Source Type: Journal    
DOI: 10.1002/jbm.a.30501     Document Type: Article

References (29)

1. Brunette DM, Tengvall P, Textor M, Thomsen P. Titanium in medicine. Berlin, Germany: Springer; 2001.
2. Luckley HA, Kubli F. Titanium alloys in surgical implants. PhiladelphiaPA: ASTM; 1981. p 7.
3. Young L. Anodic oxide films. London, UK: Academic; 1961.
4. Schultze JW, Lohrengel MM. Nucleation and growth of anodic oxide films. Electrochim Acta 1983;28:973-984.
5. Delplancke JL, Winand R. Galvanostatic anodization of titanium. II. Reaction efficiencies and electrochemical behaviour model. Electrochim Acta 33;1988:1551-1559.
6. Zwilling V, Aucouturier M, Darque-Ceretti E, Boutry-Forveille A. Anodic oxidation of titanium and TiAl6V alloy in chromic media. An electrochemical approach. Electrochim Acta 1999; 45:921-929.
7. Zwilling V, Darque-Ceretti E, Boutry-Forveille A, David D, Perrin MY, Aucouturier M. Structure and physicochemistry of anodic oxide films on titanium and TA6V alloy. Surf Interface Anal 1997;27:629-637.
8. Simpson JP. Biological and biomechanical performance of biomaterials. Amsterdam: Elsevier; 1986. p 63.
9. Sul YT, Johansson CB, Petronis S, Krozer A, Jeong Y, Wennerberg A, Albrektsson T. Characteristics of the surface oxides on turned and electrochemically oxidized pure titanium implants up to dielectric breakdown: the oxide thickness, micropore configurations, surface roughness, crystal structure and chemical composition. Biomaterials 2002;23:491-501.
10. Yang B, Uchida M, Kim HM, Zhang X, Kokubo T. Preparation of bioactive titanium metal via anodic oxidation treatment Biomaterials 2004;25:1003-1010.
11. Othsuka T, Guo J, Sato N. Raman spectra of the anodic oxide film on titanium in acidic sulfate and neutral phosphate solutions. J Electrochem Soc 1986;133:2473-2476.
12. Shibata T, Zhu YC. The effect of film formation conditions on the structure and composition of anodic oxide films on titanium. Corr Sci 1995;37:253-270.
13. Marchenoir JJC, Loup JP, Masson J. Étude des couches poreuses formées par oxydation anodique du titane sous fortes tensions. Thin Solid Films 1980;66:357-369.
14. Dyer CK, Leach JSL. Breakdown and efficiency of anodic oxide growth on titanium. J Electrochem Soc 1978;125:1032-1038.
15. Mueller Y, Virtanen S. Stages of anodic oxide growth on titanium, pits and pores. II. In: Schmuki P, Lockwood DJ, Ogata YH, Isaacs HS, editors. PV 2000-25, The Electrochemical Society Proceedings Series. Pennington, NJ: Electrochemical Society; 2000. p 294-305.
16. Gong D, Grimes CA, Varghese OK, Chen Z, Dickey EC. Titanium oxide nanotube arrays prepared by anodic oxidation. J Mater Res 2001;16:3331-3334.
17. Mor GK, Varghese OK, Grimes CA. Fabrication of tapered, conical-shaped titania nanotubes. J Mater Res 2003;18:2588-2591.
18. 4/HF electrolytes. Electrochem Solid State Lett 2003;6:B12-B14.
19. 2 nanotubes by anodization of titanium. Angew Chem Int Ed 2005;44:2100-2102.
20. Ghicov A, Tsuchiya H, Macak JM, Schmuki P. Titanium oxide nanotubes prepared in phosphate electrolytes. Electrochem Commun 2005;7:505-509.
21. 4/NaF electrolytes. Electrochim Acta 2005;50:3679-3684.
22. 4F electrolytes. Electrochem Commun 2004;6:1131-1134.
23. Tsuchiya H, Schmuki P. Self-organized high aspect ratio porous hafnium oxide prepared by electrochemical anodization. Electrochem Commun 2005;7:49-52.
24. 3 formed in NaF electrolytes. Electrochem Commun 2005;7:295-298.
25. 4/HF electrolytes. Electrochem Solid-State Lett 2005;8:J10-J13.
26. Sieber I, Hildebrand H, Friedrich A, Schmuki P. Formation of self-organized niobium porous oxide on niobium. Electrochem Commun 2005;7:97-100.
27. Brooks CHR. Heat treatment, structure and properties of non-ferrous alloys. Metals Park, OH: ASM; 1986. p 361.
28. 4-electrolytes. J Electrochem Soc. Forthcoming.
29. 2 films. Z Phys Chem. Forthcoming.