X-ray analysis of bond elongation in VO(acac) 2 at the excited state

Chemistry Letters

Volumn 34, Issue 9, 2005, Pages 1228-1229

  Hoshino, Manabu ^a   Sekine, Akiko ^a   Uekusa, Hidehiro ^a   Ohashi, Yuji ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 28444481410     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.1228     Document Type: Article

References (13)

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6. M. Hoshino, H. Uekusa, and Y. Ohashi, Chem. Commun., 2005, in contribution.
7. a) C. J. Ballhausen and H. B. Gray, Inorg. Chem., 1, 111 (1962).
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9. R. A. Rowe and M. M. Jones, Inorg. Synth., 5, 113 (1957).
10. 2).
11. r = 265.15; triclinic; space group P1 (No. 2); Z = 2. Each structure was solved by the direct method (SHELXS-97) and refined by the full-matrix least-squares method (SHELXL-97). All atoms were found in the difference Fourier map. All the non-hydrogen atoms were refined anisotropically and hydrogen atoms were refined isotropically. Crystallographic data reported in this manuscript have been deposited with Cambridge Crystallographic Data Centre as supplementary publication No. CCDC 278182-278191. Copies of the data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge, CB2 1EZ, UK; fax: +44 1223 336033; ordeposit@ccdc.cam.ac.uk).
12. 2 gas stream and was in the thermodynamically equilibrium state, the temperature increase caused by the radiationless transition during the data collection may be a few degree, considering from the thermal conductivity of the crystal.
13. 3, R [I > 2σ(I)] = 0.0254, Rw [I > 2σ(I)] = 0.0746, Goodness of fit = 1.065. Data collection and structure analysis were performed in the same way.